• Title/Summary/Keyword: Gas Composition

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Combustion Characteristics of the SOFC Products for SOFC/Gas Turbine Hybrid Power Generation System (SOFC/가스터빈 혼합발전을 위한 SOFC 생성물의 연소특성)

  • Lee, Byeong Jun;Bae, Chul Han
    • Journal of the Korean Society of Combustion
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    • v.19 no.3
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    • pp.44-52
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    • 2014
  • Solid oxide fuel cell(SOFC) makes electric power using hydrogen or reformed from methane and emits high temperature products that contain flammable species like hydrogen, carbon monoxide and methane which varies with operation condition. SOFC/gas turbine integrated system which uses thermal and chemical energy of the discharges is more efficient than SOFC itself. Burning character of the SOFC products will affect the efficiency and stability of the system. Experiments were conducted to know the characteristics of the flame for two typical composition of SOFC products, i.e. start-up and steady state composition. When coflowing air temperature was higher than $600^{\circ}C$, auto-ignitin occurred for both fuels. Though start-up fuel has higher contents of hydrogen, it makes longer flame than steady state composition. It was inferred that the amount of oxidizer necessary to burn makes this phenomenon. Steady state composition fuel was unstable since it contains lots of water. Nozzle that had 6 holes, distance between each hole was 16.7 times of hole diameter, improved the stability of the flame.

A Conversion Rate Prediction Study of Exhaust Gas by Catalyst Simulation in Heavy Duty Natural Gas Vehicle (대형천연가스차량에서 촉매시뮬레이션에 의한 배출가스의 변환율 예측 연구)

  • 한영출;오용석;강호인
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.3
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    • pp.257-264
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    • 2000
  • An aftertreatment device which reduce exhaust gas of natural gas vehicle(NGV), NGV catalyst has important meaning as to reduce the exhaust emission. In this study, the characteristics of NGV catalyst were investigated and the effect parameters of NGV catalyst were analyzed and were predicted by changing the various parameters such as temperature, and gas concentration. The conversion efficiency of NGV catalyst converter was also predicted by Pd-loading, mass flow rate and gas composition.

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Evaluation of Some Aquatic Plants from Bangladesh through Mineral Composition, In Vitro Gas Production and In Situ Degradation Measurements

  • Khan, M.J.;Steingass, H.;Drochner, W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.4
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    • pp.537-542
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    • 2002
  • A study was conducted to evaluate the nutritive potential value of different aquatic plants: duckweed (Lemna trisulaca), duckweed (Lemna perpusila), azolla (Azolla pinnata) and water-hyacinth (Eichhornia crassipes) from Bangladesh. A wide variability in protein, mineral composition, gas production, microbial protein synthesis, rumen degradable nitrogen and in situ dry matter and crude protein degradability were recorded among species. Crude protein content ranged from 139 to 330 g/kg dry matter (DM). All species were relatively high in Ca, P, Na, content and very rich in K, Fe, Mg, Mn, Cu and Zn concentration. The rate of gas production was highest in azolla and lowest in water-hyacinth. A similar trend was observed with in situ DM degradability. Crude protein degradability was highest in duckweed. Microbial protein formation at 24 h incubation ranged from 38.6-47.2 mg and in vitro rumen degradable nitrogen between 31.5 and 48.4%. Based on the present findings it is concluded that aquatic species have potential as supplementary diet to livestock.

Analysis of lipopolysaccharides of Pasteurella multocida and several Gram-negative bacteria by gas chromatography on a capillary column (Gas chromatography의 capillary column을 이용한 Pasteurella multocida 및 기타 그람음성 세균의 lipopolysaccharide 분석)

  • Ryu, Hyo-ik;Kim, Chul-joong
    • Korean Journal of Veterinary Research
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    • v.40 no.1
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    • pp.72-80
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    • 2000
  • Lipopolysaccharides (LPS) of Pasteurella multocida (P multocida) and several Gram-negative bacterial pathogens were analyzed by methanolysis, trifluoroacetylation and gas chromatography (GC) on a fused-silica capillary column. The GC analysis indicated that LPS prepared from a strain of P multocida by phenol-water (PW) or trichloroacetic acid (TCA) extraction were quite different in chemical composition. However, LPS prepared from Salmonella enteritidis by the two extraction methods were very similar. PW-LPS extracts from different Pasteurella strains of a serotype had essentially identical GC patterns. Endotoxic LPS extracted from 16 different serotypes of P multocida by PW or by phenol-chloroform-petroleum ether procedures yielded chromatograms indicating similar composition of the fatty acid moieties but minor differences in carbohydrate content. When the chemical composition of endotoxic LPS extracted from several Gram-negative bacteria (P multocida, Pasteurella hacmolytica, Haemophilus somnus, Actinobacillus ligniersii, Brucella abortus, Treponema hyodysenteriae, Escherichia coli, Bacteriodes fragilis, Salmonella abortus equi and Salmonella enteritidis) were examined, each bacteria showed a unique GC pattern. The carbohydrate constituents in LPS of various Gram-negative bacteria were quite variable not only in the O-specific polysaccharides but also in the core polysaccharides. The LPS of closely related bacteria shared more fatty acid constituents with each other than with unrelated bacteria.

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Characterization of Nanostructure and Electronic Properties of Catalytically Grown Carbon Nanofiber (촉매법으로 제조한 나노탄소섬유의 미세구조 및 전기적 특성 제어 연구)

  • 김명수;우원준;송희석;임연수;이재춘
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.345-353
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    • 2000
  • Carbon nanofibers were prepared from the decomposition of various carbon-containing gases over pure Ni, pure Fe and their alloys with Cu. They yields, properties, and structure of carbon nanofibers obtained from the various reaction conditions were analyzed. Type of reacting gas, reaction temperature and catalyst composition were changed as the reaction variable. With Ni-Cu catalysts, the maximum yields of carbon nanofibers were obtained at temperatures between 550 and 650$^{\circ}C$ according to the reacting gas mixtures of C2H2-H2, C2H4-H2 and C3H8-H2, and the surface areas of the carbon nanofibers produced were 20∼350㎡/g. In the case of CO-H2 mixture, the rapid deposition of carbon nanofibers occurred with Fe-Cu catalyst and the maximum yield were obtained around 550$^{\circ}C$ with the range of surface areas of 140∼170㎡/g. The electrical resistivity of carbon nanofiber regarded as the key property of filler for the application of electromagnetic interference shielding was very sensitive to the type of reactant gas and the catalyst composition ranging 0.07∼1.5Ωcm at a pressure of 10000 psi, and the resistivity of carbon nanofibers produced over pure nickel catalyst were lower than those over alloy catalysts. SEM observation showed that the carbon nanofibers produced had the diameters ranging 20∼300 nm and the straight structure of carbon nanofibers changed into the twisted or helical conformation by the variation of reacting gas and catalyst composition.

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INDUCTION PLASMA DEPOSITION TECHNOLOGY FOR NUCLEAR FUEL FABRICATION

  • I. H. Jung;K. K. Bae;Lee, J. W.;Kim, T. K.;M. S. Yang
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.216-221
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    • 1998
  • A study on induction plasma deposition with ceramic materials, yttria-stabilized-zirconia ZrO$_2$-Y$_2$O$_3$ (m.p 264O $^{\circ}C$), was conducted with a view developing a new method for nuclear fuel fabrication Before making dense pellets more than 96%TD., the spraying condition was optimized through the process parameters, such as chamber pressure, plasma plate power powder spraying distance, sheath gas composition, probe position, particle size and powders different morphology. The results with a 5mm thick deposit on rectangular planar graphite substrates showed a 97.11% theoretical density when the sheath gas flow rate was Ar/H$_2$120/20 l/min, probe position 8cm, particle size -75 ${\mu}{\textrm}{m}$ and spraying distance 22cm by AMDRY146 powder. The degree of influence of the main effects on density were powder morphology. particle size, sheath gas composition, plate power and spraying distance, in that order. Among the two parameter interactions, the sheath gas composition and chamber pressure affects density greatly. By using the multi-pellets mold wheel type, the pellet density did not exceed 94%T.D., owing to the spraying angle.

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Taxonomical Study by the Major Fatty Acid of Genus Rhus(anacardiaceae) in Korean (주요 지방산에 의한 한국산 옻나무屬의 분류학적 연구)

  • 정재민
    • Korean Journal of Plant Resources
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    • v.11 no.2
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    • pp.202-209
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    • 1998
  • Through total fatty acid analysis by the Gas chromatography, 17 different fatty acids were identified from the sap extracted from bark of Korean Rhus(Anacardiaceae), six species. Linoleic acid(C18 :2) and oleic acid(C18 : 1) were identified as major fatty acids for the species investigated, but except in R. chinensis.In the fatty acid composition for the species, one or two specific-fatty acid was detected, and its could be utilized as a useful taxonomic character.The result of cluster analysis by the 22 reliable characters in the fatty acid composition suggested first group was R.trichocarpa and R. succedanea, the second group, R.verniciflua, R.ambgua and R. sylvestris, but R.chinensis was a greatly independent species. The possible chemotaxonomic application of the fatty acid composition of bark in the genus Rhus was discussed.

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Effects of Ensiling Alfalfa with Whole-crop Maize on the Chemical Composition and Nutritive Value of Silage Mixtures

  • Ozturk, Durmus;Kizilsimsek, Mustafa;Kamalak, Adem;Canbolat, Onder;Ozkan, Cagri Ozgur
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.4
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    • pp.526-532
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    • 2006
  • The aim of this study was to evaluate the chemical composition, in vitro DM degradability, ME and OMD of alfalfa-maize silage mixtures in comparison to pure maize and alfalfa silages, and to test the existence of associative effects of ensiling alfalfa forage with whole-crop maize using the in vitro gas production technique. Ensiling alfalfa with whole-crop maize had a significant (p<0.001) effect on chemical composition, pH, in vitro DM degradability, OMD and estimated ME values of mixtures. DM content of the resultant silages significantly increased with increasing proportion of whole-crop maize in the mixtures, whereas the pH value, crude protein (CP), acid detergent fibre (ADF) and ash contents of mixtures decreased due to the dilution effect of whole-crop maize which was low in CP, ADF and ash. The pH values of all alfalfa-maize silage mixtures were at the desired level for quality silage. Gas production of alfalfa-maize silage mixtures at all incubation times except 12 h increased with increasing proportion of whole-crop maize. When alfalfa was mixed with whole-crop maize in the ratio 40:60, ME and OMD values were significantly (p<0.001) higher than other silages. Maximum gas production ($A_{gas}$) ranged from 65.7 to 78.1 with alfalfa silage showing the lowest maximum gas production. The results obtained in this study clearly showed that maximum gas production increased with increased percentage of whole-crop maize in the silage mixtures (r = 0.940, p<0.001). It was concluded that ensiling alfalfa with whole-crop maize improved the pH, OMD and ME values. However, trials with animals are required to see how these differences in silage mixtures affect animal performance.

Effects on the Gas Dispersion by Changed Gas Composition (가스의 성분변화가 확산에 미치는 영향)

  • Min, Dongchul;Gye, Hyeri;Kim, Sungtae;Kim, JongMin;Kwon, Jeong-Rock;Kim, Byung-Duk
    • Journal of Energy Engineering
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    • v.24 no.4
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    • pp.117-123
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    • 2015
  • Recetly, Many industry have used unknown composition gases and no information gases. These gases were used increasing. As use increases, The more important software that can predict dispersion region and speed. It is very difficult to predict the dispersion of new gases. Because, it is predict from existing database. In this study, we propose to esimate dispersion region and speed of some gases, using a FLACS software and equivalent gas.

Effect of Anodic Gas Compositions on the Overpotential in a Molten Carbonate Fuel Cell

  • Lee C.G.;Kim D.H.;Hong S.W.;Park S.H.;Lim H.C.
    • Journal of the Korean Electrochemical Society
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    • v.9 no.2
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    • pp.77-83
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    • 2006
  • Anodic overpotential has been investigated with gas composition changes in a $100cm^2$ class molten carbonate fuel cell. The overpotential was measured with steady state polarization, reactant gas addition (RA), inert gas step addition (ISA), and electrochemical impedance spectroscopy (EIS) methods at different anodic inlet gas compositions, i.e., $H_2:CO_2:H_2O=0.69:0.17:0.14\;atm\;and\;H_2:CO_2:H_2O=0.33:0.33:0.33\;atm$, at a fixed $H_2$ flow rate. The results demonstrate that the anodic overpotential decreases with increasing $CO_2\;and\;H_2O$ flow rates, indicating the anode reaction is a gas-phase mass-transfer control process of the reactant species, $H_2,\;CO_2,\;and\;H_2O$. It was also found that the mass-transfer resistance due to the $H_2$ species slightly increases at higher $CO_2\;and\;H_2O$ flow rates. EIS showed reduction of the lower frequency semi-circle with increasing $H_2O\;and\;CO_2$ flow rate without affecting the high frequency semi-circle.