• Nuclear Engineering and Technology
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• v.56 no.2
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• pp.477-484
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• 2024

Experimental investigations on gamma - rays attenuation parameters and dielectric spectroscopic properties were done on a polymeric mixture with chemical composition (100-x) polyethylene + x basalt, where x = 0, 1, 3, 5, 10, and 20 wt%. Using the melting blending technique,six nanocomposite polymeric samples were prepared. The linear attenuation coefficient µ of each prepared set of samples was measured using a gamma-ray spectrometer including High Purity Germanium detector (HPGe) at energies 662.5, 1173.24, and 1332.51 keV. Based on the measured values of (µ) and sample density, the other effective shielding parameters were calculated. The values of µ showed an increase with increasing the dopant ratios from 0.0 up to 20.0 wt%. In addition, the µ values decreased with the photon's energy. The µ values were found 0.0847 up to 0.1175 cm^-1, 0.0571 up to 0.0855 cm^-1, and 0.0543 up to 0.075 cm^-1 at 662.5, 1173.24, and 1332.51 keV. for B0 up to B20, respectively. The ATR spectroscopy was done on the prepared samples, and a good evidence of adding the filler to the pure polyethylene (HDPE) was obtained. Besides, an enhancement in dielectric constant by insertion of basalt NPs also recorded and can be attributed to the large dielectric constant of basalt compared to pure HDPE.

• Journal of the Korean association of regional geographers
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• v.11 no.4
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• pp.440-452
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• 2005

The granites in the Gyeongju area are represented by the Namsan granites and the Tohamsan granodiorites. In this study I examined the geomorphological and geological characteristics of the granite landforms in the Gyeongju area. Joint, tor and corestones are most identifiable geomorphological and geological structure in the study areas. Tor in the Namsan granites is well developed and mainly composed of cubic corestones. Petrographical features of the stones used for the stone-built cultural properties are compared with those of the granites cropped out nearby. Additionally radiogenic element contents (K, Th, U) were acquired for comparison by gamma-ray spectrometer analysis. Most stones from the stone-built cultural properties in the Bulguksa Temple are very similar to the Namsan granites in terms of petrography, radiogenic elements. On the contrary almost all stones from the Seokguram Grotto share common petrographical, physical and chemical characteristics with the Tohamsan granodiorites. Therefore it can be suggested that the stones in the Bulguksa Temple were supplied from Namsan, and that the stones in the Seokgurarn Grotto were collected at nearby Tohamsan.

• Journal of the Korean Society of Radiology
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• v.7 no.1
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• pp.31-36
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• 2013

The radioactive gas radon ($^{222}Rn$), which is generated from the decay process of uranium ($^{238}U$) originating from the soil of more than 85 percent higher the porosity of the soil, the soil can radiate out the possibility that many isotopes. In order to protect the human body from radon, above all, the development of accurate measurement techniques to formulate appropriate measures should be followed. This study Gamma-ray spectrometry using a high purity germanium (HPGe) detector, if you want to measure radon unstable the nature radiation of the background problems can be reduced, radium and radon daughter nuclides after radioactive equilibrium leads to Radon concentration was measured, the soil samples from the Gamma-ray emitting nuclides, and the energy spectrum is analyzed.

• Korean Journal of Food Science and Technology
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• v.35 no.6
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• pp.1060-1063
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• 2003

Electron spin resonance (ESR) spectroscopy was used to investigate the effects of irradiation doses and storage times on three spices. Three imported spices (Brassica juncea, Origanum vulgare, Laurus nobilis) were irradiated with doss of 0, 1, 5 and 10 kGy using a Co-60 irradiator at room temperature. ESR signals were measured from each sample by a Bruker-EPR spectrometer. The gamma-irradiated Brassica and Laurus nobilis exhibited characteristic signals, which were different from those of the non-irradiated ones. Non-irradiated and irradiated Origanum vulgare exhibited single lines, with higher ESR signals in irradiated sample than in non-irradiated sample. The ESR signals increased linearly with increasing irradiation doses $(1{\sim}10kGy)$. A strong positive correlation coefficient $(R^2=0.9939{\sim}0.9993)$ was obtained between the irradiation doses and the corresponding ESR signal intensities. Although the ESR signal intensities decreased with storage time, signals from the three irradiated spices were observed even after 12 weeks of storage at room temperature.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.12 no.2
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• pp.97-105
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• 2014

In the case of the direct measurement of $^{226}Ra$ using a HPGe gamma-ray spectrometer, the interference between gammarays with 186.21 keV of $^{226}Ra$ and 185.7 keV of $^{235}U$ should be corrected to calculate the net peak area in the energy spectrum. In general, it is very difficult to conduct peaks stripping with difference of about 0.5 keV, although a HPGe with the superior resolution is applied and the maximum channels is applied to the spectrometer. In this study, several interference correction techniques in the direct measurement were surveyed to evaluate the feasibility for the measurement of $^{226}Ra$ using the gamma-ray spectrometery. Applying the interference corrections to the analysis of raw materials and by-products, the method validation for the direct measurement of $^{226}Ra$ was conducted by evaluating the measurement uncertainty, linearity, and range. As a result, the optimum method of the interference correction was selected by comparing with the indirect measurement of which progenies of $^{226}Ra$, such as $^{214}Pb$ and $^{214}Bi$, were analyzed in the secular equilibrium state.

• Journal of the Korean Society for Precision Engineering
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• v.14 no.11
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• pp.42-49
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• 1997

The extent of absorption and transmitance of the light that passes through some material is changed as the wavelength of the light varies, and which makdes it possible to estimate characteristics of the material. Spectrometer is a measurement system that can analyze the characteristics of material by using this principle. Its application field is so wide that it can be applied to all the arease that are concerned with analyzing materials : biological, environmental, medical and chemical area etc. This study is focused on developing precision sine drive mechanism for grating monochromator which is the most important part of the spectrometers. It is designed to be simple in struicture. It is achieved to derive basic principles to manipu- late precision sine drive mechanism : it should be aligned with a condition that .beta. , the angle between grat- ing normal and grating rod should be the same as .gamma. , the one between moving nut's normal and sliding guide. And also, it's found that the mis-alignments of the grating and mirrors are not the main factor in guaranteeing the linearity of sine drive mechanism. Performance evaluation is achieved by a standard sample by comparing experimental results with standard values. It results in wavelength accuracy of .+-. 0.5nm and resolution of 1nm. Conclusively, it can be verified that the sine drive mechanism developed in this study is not only simple in structure, but also stable and excellent in performanes.

• Textile Coloration and Finishing
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• v.21 no.5
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• pp.51-57
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• 2009

Since heavy metal pollution is a significant global environmental problem and very dangerous to human health, the improved methods for detecting heavy metals are required recently. Colorimetric chemosensors are now considered as one of the most effective analytical method used in the environment monitoring. New direct dyes having the function of colorimetric chemosensors were synthesized. When metal ions such as $Al^{3+}$, $Ca^{2+}$, $Cd^{2+}$, $Cr^{3+}$, $Cu^{2+}$, $Fe^{2+}$, $Fe^{3+}$, $Hg^{2+}$, $Li^+$, $Mg^{2+}$, $Na^+$, $Ni^{2+}$, $Pb^{2+}$ and $Zn^{2+}$ were added each solution of new direct dyes, the color of solution was changed and can be easily detected with naked eyes without expensive experimental equipment such as atomic absorption spectrometer (AAS) or inductively coupled plasma?mass spectrometer (ICP-MS). The new benzidine analogues were diazotized and reacted with couplers such as H-acid, J-acid, Chromotropic acid, Nevill-winther acid and gamma acid to synthesize new direct dyes. The structures of the new direct dyes were confirmed by high resolution mass spectrometer (FAB ionization) and evaluated with UV-Vis spectroscopy. The UV-VIS spectroscopy was measured for the dye solutions by adding various concentrations of metal ions. It was observed that the absorbance in UV-Vis spectra was changed as the heavy metal ions were added.

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.144-152
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• 1993

Immobilized polyethylene glycols onto metal oxides such as ${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$, $SiO_2$ and $TiO_2$ were used as phase transfer catalysts for the room temperature synthesis of aniline from nitrobenzene and ironpentacarbonyl. The amount of attached PEG molecules increased with specific surface area of metal oxides. Among the immobilized catalysts tested PEG/${\gamma}-Al_2O_3$ showed the highest activity. The reaction rate increased with the chain length of PEG mole-cules and the aqueous NaOH concentration. Mechanistic study carried out using infrared spectrometer revealed that the role of PEG was to increase the formation of $HFe(CO)_4{^-}$ ion, which is known as active species, and its movement from aqueous to organic phase.

• Nuclear Engineering and Technology
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• v.50 no.6
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• pp.957-962
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• 2018

The gamma radiation shielding capability (GRSC) of two clay-materials (Ball clay and Kaolin)of Southwestern Nigeria ($7.49^{\circ}N$, $4.55^{\circ}E$) have been investigated by determine theoretically and experimentally the mass attenuation coefficient, ${\mu}/{\rho}(cm^2g^{-1})$ of the clay materials at photon energies of 609.31, 1120.29, 1173.20, 1238.11, 1332.50 and 1764.49 keV emitted from $^{214}Bi$ ore and $^{60}Co$ point source. The mass attenuation coefficients were theoretically evaluated using the elemental compositions of the clay-materials obtained by Particle-Induced X-ray Emission (PIXE) elemental analysis technique as input data for WinXCom software. While gamma ray transmission experiment using Hyper Pure Germanium (HPGe) spectrometer detector to experimentally determine the mass attenuation coefficients, ${\mu}/{\rho}(cm^2g^{-1})$ of the samples. The experimental results are in good agreement with the theoretical calculations of WinXCom software. Linear attenuation coefficient (${\mu}$), half value layer (HVL) and mean free path (MFP) were also evaluated using the obtained ${\mu}/{\rho}$ values for the investigated samples. The GRSC of the selected clay-materials have been compared with other studied shielding materials. The cognizance of various factors such as availability, thermo-chemical stability and water retaining ability by the clay-samples can be analyzed for efficacy of the material for their GRSC.

• Nuclear Engineering and Technology
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• v.54 no.10
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• pp.3795-3802
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• 2022

NaI(Tl) scintillation materials are considered to be one of many materials that are used exclusively for γ-ray detection and spectroscopy. The gamma-ray spectrometer is not an easy-to-use device, and the accuracy of the numerical values must be carefully checked based on the rules of the calibration technique. Therefore, accurate information about the detection system and its effectiveness is of greater importance. The purpose of this study is to estimate, using an analytical-numerical formula (ANF), the purely geometric solid angle, geometric efficiency, and total efficiency of a cylindrical NaI(Tl) γ-ray detector with a side-through hole. This type of detector is ideal for scanning fuel rods and pipelines, as well as for performing radio-immunoassays. The study included the calculation of the complex solid angle, in combination with the use of various points like gamma sources, located axially and non-axially inside the through detector side hole, which can be applied in a hypothetical method for calibrating the facility. An extended γ-ray energy range, the detector, source dimensions, "source-to-detector" geometry inside the side-through hole, path lengths of γ-quanta photons crossing the facility, besides the photon average path length inside the detector medium itself, were studied and considered. This study is very important for an expanded future article where the radioactive point source can be replaced by a volume source located inside the side-trough hole of the detector, or by a radioactive pipeline passing through the well. The results provide a good and useful approach to a new generation of detectors that can be used for low-level radiation that needs to be measured efficiently.