• Title/Summary/Keyword: Galvanic corrosion

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A Study on the Measurement of Foreign Material in Dissimilar Metal Contact Using Pulse Laser and Confocal Fabry-Perot Interferometer (펄스 레이저와 CFPI를 이용한 이종금속 접촉부의 이물질 측정에 관한 연구)

  • Hong, Kyung-Min;Kang, Young-June;Park, Nak-Kyu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.2
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    • pp.160-164
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    • 2013
  • A laser ultrasonic inspection system is a non-contact inspection device which generates and measures ultrasonics by using laser beam. A laser ultrasonic inspection system provides a high measurement resolution because the ultrasonic signal generated by a pulse laser beam has a wide-band spectrum and the ultrasonic signal is measured from a small focused spot of a measuring laser beam. In this study, galvanic corrosion phenomenon was measured by non-destructive and non-contact method using the laser. The case of mixed foreign material on the part of corrosion was assumed and laser ultrasonic experiment was conducted. Ultrasonic was generated by pulse laser from the back side of the specimen and ultrasonic signal was acquired from the same location of the front side using continuous wave laser and Confocal Fabry-Perot Interferometer(CFPI). The characteristic of the ultrasonic signal of exist foreign material part was analyzed and the location and size of foreign material was measured.

Evaluation of the corrosion property on the welded zone of seawater pipe by A.C shielded metal arc welding (교류 피복아크 용접에 의한 해수 배관 용접부위의 부식 특성 평가)

  • Jeong, Jae-Hyun;Kim, Yun-Hae;Moon, Kyung-Man;Lee, Myeong-Hoon;Kim, Jin-Gyeong
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.8
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    • pp.877-885
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    • 2013
  • A seawater pipe of the engine room in the ships is being surrounded with severely corrosive environments caused by fast flowing of the seawater, containing aggressive chloride ion and high conductivity etc.. Therefore, the leakage of the seawater from its pipe have been often occurred due to its local corrosion by aggressive chloride ions. Subsequently, its leakage area is usually welded by AC shielded metal arc welding with various electrodes. In this study, when the sea water pipe is welded with several types of electrodes such as E4301, E4311, E4313 and E4316, a difference of the corrosion resistance on the welding metal zones was investigated using an electrochemical method, observing microstructure, measuring polarization behaviors and hardness. The weld metal zone welded with E4313 electrode exhibited the lowest value of hardness compared to other weld metal zones. In addition, its zone indicated also the best corrosion resistance than those of other weld metal zones. Furthermore, all of the weld metal zones revealed a relatively better corrosion resistance than those of the base metal zones. and also showed higher hardness than the base metal zones.

Material Characteristic of POFA Concrete and Its Application to Corrosion Resistance Evaluation (POFA 콘크리트의 재료특성 및 부식 저항성 평가로의 적용)

  • Lee, Chang-Hong;Song, Ha-Won;Ann, Ki-Yong;Ismail, Mohamed Abdel
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.565-572
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    • 2009
  • In this study, corrosion resistance of palm oil fuel ash (POFA) concrete as a blended concrete is evaluated by using electrochemical technique. The POFA is an industrial byproduct obtained from fuel ash after extracting palm oil from palm-tree. In order to obtain basic material characteristics of the POFA concrete, tests on compressive strength, slump, weight loss, bleeding and expansion ratio were carried out the early-aged POFA concrete. On the other hand, durability characteristics, both chloride penetration and carbonation depth test, were also conducted. Finally, corrosion resistance were evaluated by applying electro-chemical artificial crack healing technique, and the tests on the impressed voltage characteristic, galvanic current and linear polarization resistance. From the experimental results, it was found that long-term strength, bleeding, lower slump ratio, expansion ratio, chloride penetration, carbonation and corrosion resistance were improved by using the POFA due to activated pozzolanic reaction. It can be also mentioned that POFA concrete has a potential to be used as a cementitious binder for green-recycling resources.

Effect of Circumferential Tool Path Control on Friction Stir Spot Welding of Al/Fe Dissimilar Metal Joint (툴 경로제어를 이용한 Al/Fe 이종금속 마찰교반점용접 공정특성 평가)

  • Yoon, Jin Young;Kim, Cheolhee;Rhee, Sehun
    • Journal of Welding and Joining
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    • v.34 no.3
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    • pp.6-11
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    • 2016
  • Joining Al/Fe dissimilar metals is becoming a subject of special interest in the assembly of automotive parts as a trade-off between the weight lightening and the cost reduction. Although various studies have been introduced to join Al alloy with the steel sheet by fusion welding, weak joint strength and galvanic corrosion still remained as problems to be solved. As a solid state welding, friction stir welding has been preferred to fusion welding processes in the dissimilar metal joints. This study investigated friction stir spot welding (FSSW) of Al alloy to the thin steel sheet with a thickness of 0.65 mm. The conventional FSSW is a stationary spot welding process but new approach adopted an additional circumferential movement in company with high speed tool rotation. A full factorial experimental design was implemented, and the main and interaction effects of parameters were analysed on the failure load in the tensile shear test. The direction and radius of rotation were statistically significant parameters and these two parameters affected the joint width and the shape of the hook.

Performances of Metallic (sole, composite) and Non-Metallic Anodes to Harness Power in Sediment Microbial Fuel Cells

  • Haque, Niamul;Cho, Daechul;Kwon, Sunghyun
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.363-367
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    • 2014
  • One chambered sediment microbial fuel cell (SMFC) was equipped with Fe, brass (Cu/Zn), Fe/Zn, Cu, Cu/carbon cloth and graphite felt anode. Graphite felt was used as common cathode. The SMFC was membrane-less and mediator-less as well. Order of anodic performance on the basis of power density was Fe/Zn ($6.90Wm^{-2}$) > Fe ($6.03Wm^{-2}$) > Cu/carbon cloth ($2.13Wm^{-2}$) > Cu ($1.13Wm^{-2}$) > brass ($Cu/Zn=0.24Wm^{-2}$) > graphite felt ($0.10Wm^{-2}$). Fe/Zn composite anode have twisted 6.73% more power than Fe alone, Cu/carbon cloth boosted power production by 65%, and brass (Cu/Zn) produced 65% less power than Cu alone. Graphite felt have shown the lowest electricity generation because of its poor galvanic potential. The estuarine sediment served as supplier of oxidants or electron producing microbial flora, which evoked electrons via a complicated direct microbial electron transfer mechanism or making biofilm, respectively. Oxidation reduction was kept to be stationary over time except at the very initial period (mostly for sediment positioning) at anodes. Based on these findings, cost effective and efficient anodic material can be suggested for better SMFC configurations and stimulate towards practical value and application.

An Application of Solenoid Eddy Current Sensor for Nondestructively Inspecting Deterioration of Overhead Transmission Lines due to Forest Fires (산불에 의한 가공송전선의 열화특성을 비파괴적으로 검출하기 위한 솔레노이드 와류센서의 응용)

  • Kim, Sung-Duck;Kim, Young-Dal;Jeong, Dong-Hwa
    • Journal of Sensor Science and Technology
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    • v.9 no.6
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    • pp.404-415
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    • 2000
  • This paper describes several performances and nondestructive inspection for deterioration due to forest fires in overhead transmission lines. After discussing corrosion mechanism such as atmospheric and galvanic corrosion for aged ACSR conductors and its detection for them are presented. Through impedance analysis of a solenoid coil, it is shown that the eddy current sensor may be available to inspect severe fault or local corrosion. As the solenoid coil changes its impedance when the test conductor is inserted into the coil, it can be possible to measure deterioration degree caused by forest fires. Tensile strength, extension rate and sensor impedance are tested for some samples degraded by artificial fire. As increasing blazed period to some extent, the strength of aluminum strand begins to be reduced remarkably, while galvanized steel strand holds the similar strength to the initial value, despite of appearing a little loss of zinc layer. In general, it is shown that the sensor impedance would be increased while the tension load of conductor is reduced and the extension rate is contrarily increased. Therefore, the sensor output could exhibit the changes of mechanical performances, and would be used to detect such deterioration caused by forest fire in ACSR conductors built on the ridge of mountains. Finally, it was verified that the solenoid coil could be applicable to obtain any crucial inform for serious deterioration due to forest fires.

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A Study on the Electrode Characteristics of Hypo-Stoichiometric Zr-based Hydrogen Storage Alloys

  • Lee, Sang-Min;Kim, Seoung-Hoe;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.4
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    • pp.197-210
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    • 1999
  • The hydrogen storage performance and electrochemical properties of $Zr_{1-X}Ti_X(Mn_{0.2}V_{0.2}Ni_{0.6})_{1.8}$(X=0.0, 0.2, 0.4, 0.6) alloys are investigated. The relationship between discharge performance and alloy characteristics such as P-C-T characteristics and crystallographic parameters is also discussed. All of these alloys are found to have mainly a C14-type Laves phase structure by X-ray diffraction analysis. As the mole fraction of Ti in the alloy increases, the reversible hydrogen storage capacity decreases while the equilibrium hydrogen pressure of alloy increases. Furthermore, the discharge capacity shows a maxima behavior and the rate-capability is increased, but the cycling durability is rapidly degraded with increasing Ti content in the alloy. In order to analyze the above phenomena, the phase distribution, surface composition, and dissolution amount of alloy constituting elements are examined by S.E.M., A.E.S. and I.C.P. respectively. The decrease of secondary phase amount with increasing Ti content in the alloy explains that the micro-galvanic corrosion by multiphase formation is little related with the degradation of the alloys. The analysis of surface composition shows that the rapid degradation of Ti-substituted Zr base alloy electrode is due to the growth of oxygen penetration layer. After comparing the radii of atoms and ions in the electrolyte, it is clear that the electrode surface becomes more porous, and that is the source of growth of oxygen penetration layer while accelerating the dissolution of alloy constituting elements with increasing Ti content. Consequently, the rapid degradation (fast growth of the oxygen-penetrated layer) with increasing Ti substitution in Zr-based alloy is ascribed to the formation of porous surface oxide through which the oxygen atom and hydroxyl ion with relatively large radius can easily transport into the electrode surface.

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A Study on Prediction Technique for Underwater Electric Field Signature Characteristic using Dipole Modelling Method (다이폴 모델링 기법을 이용한 수중 전기장 신호 특성 예측 기법 연구)

  • Yang, Chang-Seob;Chung, Hyun-Ju;Lee, Jong-Ju;Jeon, Jae-Jin
    • Journal of the Korean Magnetics Society
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    • v.18 no.6
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    • pp.221-224
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    • 2008
  • This paper describes the equivalent dipole modeling method utilizing a singular value decomposition technique from analysis data by the FNREMUS Detailled Modeller software based on BEM which can predict the underwater electric field signal due to a galvanic corrosion phenomenon on a naval vessel. The proposed dipole modeling method was successfully verified in good agreement with predicted BEM data at 30 m depths through the comparison of average differences. The proposed dipole modelling method can be effectively used in the prediction and analysis of static electric field signature distributions generated from a naval vessel at any different depths.

Material Degradation of Ancient Iron Pot by Repeated Heating for One Thousand Years (고대 철확(철솥)의 1천년 반복 가열 및 열화현상)

  • Go, Hyeong;Han, Min Su;Choe, Byung Hak;Min, Doo Sik;Shim, Yun Im;Jeong, Hyo Tae;Cho, Nam Chul
    • Korean Journal of Metals and Materials
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    • v.50 no.4
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    • pp.324-330
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    • 2012
  • The microstructural changes of three pieces from an ancient iron pot were studied in order to identify present the material degradation due to repeated heating for one-thousand years. The microstructures of the pieces were divided into the areas of ferrite/graphite, ferrite/pearlite, and corroded oxidation. The area of ferrite/graphite was undergone by severe Galvanic corrosion, but that of ferrite/pearlite was not even during a thousand years' using. The shape of the graphites was coexisted with types of A, B, and C of as modern graphite classification. In the ferrite/pearlite area, abnormal acicula precipitates with a high aspect ratio of $0.2{\mu}m$ thickness and several hundreds ${\mu}m$ length were presented. They might be a kind of carbide in the ferrite matrix with its special precipitate plane.

A Study on the Effect of Metallic Fillers and Plastic for Ionic Migration (이온마이그레이션에 대한 플라스틱과 금속첨가제의 영향 연구)

  • Jeon, Sang Soo;Kim, Ji Jung;Lee, Ho Seung
    • Journal of Auto-vehicle Safety Association
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    • v.13 no.2
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    • pp.30-34
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    • 2021
  • Electrical failures and reliability problems of electronic components by ionic migration between adjacent device terminals have become an issue in automotive electronics. Especially unlike galvanic corrosion, ionic migration is occurred at high temperature and high humidity under applied electric field condition. Until now, although extensive studies of the ionic migrations dealing with PCBs, electrodes, and solders were reported, there is no study on the effect of insulation polymers and metallic fillers for ionic migration. In this research, therefore, ionic migration induced by the types and contents of polymers and metallic fillers, and variety conditions of temperature, humidity, and applied voltage was studied in detail. Ester and amide types of liquid crystal polymer (LCP) and poly (phthalamide) (PPA) were used as base polymers, respectively and compounded with the metallic fillers of Copper iodide (CuI), Zinc stearate (Zn-st), or Calcium stearate (Ca-st) in various compositions. The compounding polymers were fabricated in IPC-B-24 of SIR test coupon according to ISO 9455-17 with Cu electrodes for ionic migration test. While there is no change in LCP-based samples, ionic migration in PPA compounding sample with a high water absorption property was accelerated in the presence of 0.25 wt% or above of CuI at the environmental conditions of 85℃, 85% RH and 48V. The dendritic short-circuit growth of Cu caused by ionic migration between the electrodes on the surface of compounded polymers was systematically observed and analyzed by using optical microscopy and SEM (EDX).