• Title/Summary/Keyword: GLASS

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Physical properties of EAF dust-loaded glass-ceramics (EAF dust가 첨가된 결정화 유리의 물리적 특성)

  • Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.6
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    • pp.242-247
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    • 2008
  • The glass and glass-ceramics containing EAF dust $30{\sim}70\;wt%$ were fabricated and the dependance of physical properties upon crystal phases and microstructure formed was studied. The crystallization behavior of glass and glass-ceramics containing various contents of EAF dust composing of mainly $Fe_2O_3$ and ZnO was analyzed by crystal identification and microstructure observation. The glass specimen with EAF dust 30 wt% showed a typical amorphous pattern in XRD results and the specimen with above 30 wt% EAF dust had some un-dissolved crystals which was originated from EAF dust. The all glass-ceramics had franklinite, willemite and augite crystal phases. The density of glass-ceramics was higher than that of same composition glass, and it increased with EAF dust contents. In addition, the thermal and mechanical properties of glass-ceramics were always higher than those of glasses. In other words, the thermal expansion coefficient of glass increased with EAF dust contents while it decreased for the glass-ceramics. The vickers hardness for the glass and glass-ceramics increased with EAF dust content, the glass-ceramics always being higher those of glass of same composition.

Effect of softening point of glass frit on the sintering behavior of low-temperature cofitrable glass/ceramic composites (유리 프릿트의 연화점이 저온소성용 글라스/세라믹 복합체의 소결거동에 미치는 영향)

  • 구기덕;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.619-625
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    • 1998
  • The effect of softening point and glass amount of glass frit on the sintering behavior of low temperature cofirable glass/ceramic composites was studied and according to these results, glass/ceramic composites with high sintered density was fabricated. The density of composites was increased as the glass amount was increased. In case of using the glass with low softening point, the deformation of specimen was occurred though the ratio of the glass amount in the specimen was low. But, in case of using the glass with high softening point, the sintered density of composites was increased in accordance with glass amount. With the specimen of high softening point, the deformation was not happened. Therefore, it was found that the densification was progressed continuously in high glass amount. From the study on the effect of softening point of glass on sintering behavior, the suitable softening point and glass amount for fabrication of glass/ceramic composites can be anticipated. When glass frit with softening point of $790^{\circ}C$ was chosen according to this result, low temperature cofirable glass/ceramic composites with high density (97%) at $900^{\circ}C$ was fabricated.

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DCPD Formation and Conversion to HAp in Glass and Glass-ceramic Bone Cement (유리 및 결정화 유리 골 시멘트에서 DCPD의 형성 및 수산화 아파타이트로의 전환)

  • Lim, Hyung-Bong;Kim, Cheol-Young
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.26-33
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    • 2011
  • The glass in the system of CaO-$SiO_2-P_2O_5$ and the corresponding glass-ceramics are prepared for bone cements and the behaviors of the hardening and hydroxyapatite formation were studied for the glass and glass-ceramic powders. The glass crystallized into apatite, $\alpha$-wollastonite and $\beta$-wollastonite depending on the glass composition when they were heat-treated at $950^{\circ}C$ for 4 h. A DCPD (dicalcium phosphate dihydrate : $CaHPO_4{\cdot}2H_2O$) was developed when the prepared glass and glass-ceramic powders were mixed with 3M-$H_3PO_4$ solution. The DCPD (Ca/P=1.0) transformed to HAp (Ca/P=1.67) when the bone cement was soaked in simulated body fluid (SBF), and this HAp formation strongly depended on the releasing capacity of $Ca^{2+}$ ions from the glass and glass-ceramic cements. The glass-ceramic bone cement containing $\alpha$-wollastonite crystals showed faster transformation of DCPD to HAp than other glass-ceramics containing $\alpha$- and $\beta$-wollastonite crystals. No hydroxyapatite was observed when the glass-ceramic bone cement containing apatite crystals (36P6C) was soaked in SBF even for 1 month, because no $Ca^{2+}$ ion can be released from the stable apatite crystals.

A Study on the Glass passivation film by electrophoretic method (전기영동법을 이용한 Glass Passivation막에 관한 연구)

  • 박인배;허창수
    • Electrical & Electronic Materials
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    • v.10 no.5
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    • pp.473-480
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    • 1997
  • Surface passivation using glass powders results in good reliability for high voltage silicon power devices. In this paper Zinc borosilicate glass and Lead borosilicate glass were prepared for the purpose of passivating, and a deposition technique of glass films on the silicon surface by electrophoresis in which acetone is used as a suspension medium has been investigated. Their physical properties were compared using DTA, SEM, XRD, as a function of firing temperature, I can get the fine films of 22${\mu}{\textrm}{m}$ thickness with Lead borosilicate glass under 300 volts applied, 3 minutes and $700^{\circ}C$ firing temperature. Also I can get the fine films of 17${\mu}{\textrm}{m}$ thickness with Zinc borosilicate glass under same conditions. As a result of investigation of glass films from which glass layer was removed by placing it in HCl, it has been found that pre-firing and annealing play an important role to achieve uniform and fine glass deposition films. And also it was found that relative dielectric constant is independence of frequency.

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The Preparation of Glass Beads (Glass beads 제조에 관하여)

  • Jin Il Kim
    • Journal of the Korean Chemical Society
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    • v.17 no.3
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    • pp.198-206
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    • 1973
  • We produced the glass beads using a spherical vessel which is rotable with the mix ture of releasing agent and glass powder in a electric furnace (apparatus 1), a tubing apparatus of electric furnace which can be gravitated a cullet (apparatus 2) and a tubing apparatus which is dispersible glass powders with the flame of propane gas (apparatus 3). The substrates which are Korean sodium silicates glass 1, 2, boro silicates glass and lead silicates glass are used and the size of cullets is 60-300 mesh. In the results of experimental apparatus, the preferable temperature of apparatus 1 is 880$^{\circ}C$, apparatus 2 is 980$^{\circ}C$ and apparatus 3 is 1100$^{\circ}C$. However, the method of apparatus 3 is more effective than the methods of apparatus 1 and 2 in view of treating time and rate of adhesion.

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Experimental Study on the Surface Defects of Scribed Glass Sheets (절단 유리판의 표면결함에 관한 실험적 연구)

  • Kim, Chung-Kyun
    • Tribology and Lubricants
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    • v.24 no.6
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    • pp.332-337
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    • 2008
  • This paper presents the surface defect analysis based on the experimental investigation of scribed glasses. The scribing process by a diamond wheel cutter is widely used as a reliable and inexpensive method for sizing of glass sheets. The wheel cutter generates a small median crack on the glass surface, which is then propagated through the glass thickness for complete separation. The surface contour patterns in which are formed during a scribing process are strongly related to wheel cutter parameters such as wheel tip surface finish, tip angle and wheel diameter, and cutting process parameters such as scribing pressure, speed and tooling technique. The scribed surface of a glass sheet provides normal Wallner lines, which represent regular median cracks and crack propagation in glass thickness, and abnormal surface roughness patterns. In this experimental study, normal and abnormal surface topographic patterns are classified based on the surface defect profiles of scribed glass sheets. A normal surface of a scribed glass sheet shows regular Wallner lines with deep median cracks. But some specimens of scribed glass sheets show that abnormal surface profiles of glass sheets in two pieces are represented by a chipping, irregular surface cracks in depth, edge cracks, and combined crack defects. These surface crack patterns are strongly related to easy breakage of the scribed glass imposed by external forces. Thus the scribed glass with abnormal crack patterns should be removed during a quality control process based on the surface defect classification method as demonstrated in this study.

A Study of Static Fatigue of Domestic Soda-Lime Glass (국산 Soda-석탄유리의 피노현상에 관한 연구)

  • 이희수;현상훈;이형복
    • Journal of the Korean Ceramic Society
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    • v.12 no.1
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    • pp.16-22
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    • 1975
  • The network structure of a glass is known to be cracked by a chemical reaction, diffusion, and ion exchange of alkali ion, formed at the crack tip of the glass surface, when water is present on the glass surface. Since the durability of glass is reduced, due to the fatigue phenomenon mentioned above, pollution problem of glass goods, especially bottle glass, is becoming acute gradually. A static fatigue phenomenon was studied thermodynamically in this paper, and a mechanism of static fatigue, a quality control, and a method of preventing pollution for the main local glass goods were also investigated. The PH of reacted solution and the quantity of extracted alkali were measured at different conditions such as temperature, reacting time, particle size of a crushed glass sample, and the nature of reacting solution. The enthalpy change was calculated from the Arrhenius equation. The results are given below; 1) The absolute value of enthalpy change for the bottle glass was found to be higher than the for the flat glass. 2) The fatigue phenomenon of a glass was more sensitive to the temperature than to the reacting time. 3) The durability of glass in acid solution is stronger than in alkaline solution. 4) The substance which cracks the network structure of glas is considered the hydroxyl ion.

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A Study on the Expressional Characteristic of Glass outer Skin in Contemporary Space Design - Focusing on the case after 2000 - (현대 공간디자인에 있어서 유리외피의 표현특성에 관한 연구 - 2000년 이후의 사례를 중심으로 -)

  • Kim, Eun-Jung;Hong, Kwan-Seon
    • Korean Institute of Interior Design Journal
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    • v.17 no.3
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    • pp.123-130
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    • 2008
  • This study is about the Characteristic of glass outer skin expressions in space designs of contemporary society, due to the rapid development of information and digital technology. These days, the glass outer skin show the various images and space expressions which symbolize the informations and the society. The contemporary space designers focus on the glass as the structure materials, and purposely use the glass to achieve the structure concept which satisfies the needs of contemporary society. Therefore, it is a valuable work to analyze the meaning of glass, which has been used for the structure. Throughout the work which has been experienced by glass outer skin, theoretical studies have been achieved and recently the 14 examples were chosen as the glass structures based on the experimental research and frequency featured in magazines after year 2000, which we have analyzed in detail. Glass outer skin reflect the phrases of time in modern society, and throughout the meaning of it, we could see that the glass outer skin serve the roles in informations, interface, imaginary modernization, and as a landmark position. Therefore, in this study, we can make a definition of glass outer skin expression based on the situations of modem times by analyzing the symbolic meaning of glass outer skin in contemporary space designs.

Study on the Aspheric Glass Lens Forming Simulation in the Progressive GMP process (순차이송 GMP 공정에서의 비구면 유리렌즈 성형 해석에 관한 연구)

  • Chang, S.H.;Gang, J.J.;Shin, K.H.;Jung, W.C.;Heo, Y.M.;Jung, T.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.539-542
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    • 2008
  • Recently, GMP(Glass Molding Press) process is mainly used to produce aspheric glass lenses. Because glass lens is heated at high temperature above Ty (yielding point) for forming glass, the quality of aspheric glass lens is deteriorated by residual stresses which are generated in a aspheric glass lens after forming. Before this study, as a fundamental study to develop forming conditions for progressive GMP process, compression, strain relaxation and thermal conductivity tests were carried out to obtain the visco-rigid plastic, the visco-elastic and thermal properties of K-PBK40 which is newly developed and applied for precision molding glass material, In this study, using the experimental results we obtained, a glass lens forming simulation in progressive GMP process was carried out and we could forecast the shape of deformed glass lenses and residual stresses contribution in the structure of deformed glass lenses after forming.

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A Low-Cost Lidar Sensor based Glass Feature Extraction Method for an Accurate Map Representation using Statistical Moments (통계적 모멘트를 이용한 정확한 환경 지도 표현을 위한 저가 라이다 센서 기반 유리 특징점 추출 기법)

  • An, Ye Chan;Lee, Seung Hwan
    • The Journal of Korea Robotics Society
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    • v.16 no.2
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    • pp.103-111
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    • 2021
  • This study addresses a low-cost lidar sensor-based glass feature extraction method for an accurate map representation using statistical moments, i.e. the mean and variance. Since the low-cost lidar sensor produces range-only data without intensity and multi-echo data, there are some difficulties in detecting glass-like objects. In this study, a principle that an incidence angle of a ray emitted from the lidar with respect to a glass surface is close to zero degrees is concerned for glass detection. Besides, all sensor data are preprocessed and clustered, which is represented using statistical moments as glass feature candidates. Glass features are selected among the candidates according to several conditions based on the principle and geometric relation in the global coordinate system. The accumulated glass features are classified according to the distance, which is lastly represented on the map. Several experiments were conducted in glass environments. The results showed that the proposed method accurately extracted and represented glass windows using proper parameters. The parameters were empirically designed and carefully analyzed. In future work, we will implement and perform the conventional SLAM algorithms combined with our glass feature extraction method in glass environments.