• Title/Summary/Keyword: GF/PP Composites

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A Study on the Ternary GF/PA/PP Composites Manufactured by Using Pre-impregnated Glass Fiber (유리섬유를 미리 함침시켜 제조한 GF/PA/PP 삼성분 복합재료에 관한 연구)

  • 윤병선;우동진;서문호;이석현
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.701-712
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    • 2000
  • The continuous fiber reinforced composites of GF/PA were fabricated using a pultrusion resin impregnation apparatus and cut into pellets of 6 mm length. GF/PA pellets were then melt-mixed with PP resin to prepare new types of ternary composites, GF/PA/PP. Mechanical and rheological properties of such composites revealed to be better than conventional ternary composites due to the longer average glass fibers. Measurements also showed that the mechanical properties of the composites prepared by direct injection molding were higher than those of the composites prepared by injection molding followed by extrusion. To improve adhesions of fiber surfaces and polymer matrix, PP-MAH (maleic anhydride) has been introduced in the GF/PA/PP composites as a compatibilizer. It was found that PP-MAH did indeed improve surface adhesion between fibers and polymer matrix and that, as a result, various mechanical properties were markedly enhanced. Visualization of the phase structure in the samples was done by means of SEM. The surfaces of glass fibers in GF/PA/PP composites revealed that the fibers remained to be encapsulated by PA resin. However, pre-encapsulation did not persist in GF/PA/PP/PP-MAH composites due to the improvement of surface adhesion between fibers and polymer matrix, although resin sticking to the fiber was observed.

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Evaluation of Impregnation and Mechanical Properties of Thermoplastic Composites with Different GF Content of GF/PP Commingled Fiber (유리섬유/폴리프로필렌 복합원사의 유리섬유 함량 변화에 따른 열가소성 복합재료의 함침 및 기계적 특성 평가)

  • Jang, Yeong-Jin;Kim, Neul-Sae-Rom;Kwon, Dong-Jun;Yang, Seong Baek;Yeum, Jeong Hyun
    • Composites Research
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    • v.33 no.6
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    • pp.346-352
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    • 2020
  • In mobility industries, the use of thermoplastic composites increased dynamically. In this study, the mechanical and impregnation properties of continuous glass fiber (GF)/polypropylene (PP) composite were evaluated with different GF contents. The GF/PP commingled fiber was manufactured with different GF contents and continuous GF/PP composite was manufactured using continuous compression molding process. Tensile, flexural, and impact test of specimens were evaluated with different GF contents. The fracture behavior of specimens was proved using field emission-scanning electron microscope images of fracture area and impregnation property was evaluated using dynamic mechanical analyzer and interlaminar shear strength. Finally, the GF/PP composite was the optimized mechanical and impregnation properties using 50 wt.% GF/PP commingled fiber.

Measurement of Degree of Hydrolysis of a PA66/GF Composite using a py-GC/MS analysis

  • Lee, Jong-Young;Kim, Kwang-Jea
    • Elastomers and Composites
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    • v.52 no.1
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    • pp.59-68
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    • 2017
  • The effect on the hydrolysis resistance properties by the addition of maleic anhydride grafted EMDM (MA-g-EPDM) and PP (MA-g-PP) to a PA66/GF composite was investigated with respect to the mechanical properties, thermal properties, and morphology. The degree of hydrolysis of the PA66/GF composite was measured using py-GC/MS analysis. When compared to the PA66/GFcomposite in MEG/water solution, the composites where MA-g-EPDM and MA-g-PP were added to PA66/GF showed a higher degree of hydrolysis resistance, impact strength, and thermal properties, whereas their tensile strength, tensile modulus, flexural strength and flexural modulus decreased. As immersion time in the solution increases, the rate of tensile strength drop of the MA-g-PP added composite appeared lower than that of the PA66/MA-g-EPDM/GF and PA66/GF composites. The py-GC/MS analysis confirmed the formation of PA66 hydrolysis reaction by products such as carboxylic acid and alkylamine with increasing immersion time.

Effect of Temperature on Tensile Fracture Behavior of Glass Fiber Polypropylene Composites (온도변화에 따른 GF/PP복합재료의 인장파괴거동)

  • 고성위;엄윤성;허경환;김엄기;김형진
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.37 no.3
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    • pp.240-245
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    • 2001
  • The tensile strength and failure mechanisms of glass fiber polypropylene (GF/PP) composites are investigated in the temperature range from ambient to 8$0^{\circ}C$. The tensile strength increases as fiber volume fraction ratio increase. The tensile strength shows a maximum at ambient temperature, and it tens to decrease as temperature goes up. Major failure mechanisms of GF/PP composites can be classified as fiber matrix debonding, fiber pull-out, delamination and matrix deformation.

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Temperature Effect on Impact Fracture Behavior of GF/PP Composites (GF/PP 복합재료의 충격파괴거동에 대한 온도효과)

  • Koh, Sung-Wi;Um, Yoon-Sung
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.41 no.1
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    • pp.78-84
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    • 2005
  • The main goal of this work is to study the effects of temperature and volume fraction of fiber on the Charpy impact test with GF/PP composites. The critical fracture energy and failure mechanisms of GF/PP composites are investigated in the temperature range of 60^{\circ}C$ to -50^{\circ}C$ by impact test. The critical fracture energy increased as the fiber volume fraction ratio increased. The critical fracture energy shows a maximum at ambient temperature and it tends to decreases as temperature goes up or goes down. Major failure mechanisms can be classified such as fiber matrix debonding, fiber pull-out and/or delamination and matrix deformation.

Temperature Effects on Impact Fracture Mechanisms of Glass Fiber/Polypropylene Campsites (유리섬유/폴리프로필렌 복합재료의 충격파괴기구에 대한 온도효과)

  • KOH S. W.;Um Y. S.
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.314-319
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    • 2004
  • Many of researches regarding mechanical properties of composite materials are associated with humid environment and temperature. Especially the temperature is a very important factor influencing the design of thermoplastic composites. However, the effect of temperature on impact behavior of reinforced composites have not yet been fully explored. An approach which predicts critical fracture toughness GIC was performed by the impact test in this work The main goal of this work is to study effects of temperature in the impact test with glass fiber/polypropylene(GF/pp) composites. The critical fracture energy and failure mechanisms of GF/PP composites are investigated in the temperature range of $60^{\circ}C\;to\;-50^{\circ}C$ by impact test. The critical fracture energy shows a maximum at ambient temperature and it tends to decrease as temperature goes up or goes down. Major failure mechanisms can be classified such as fiber matrix debonding, fiber pull-out and/or delamination and matrix deformation.

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Surface Modified Glass-Fiber Effect on the Mechanical Properties of Glass-Fiber Reinforced Polypropylene Composites

  • Park, Sanghoo;Kim, Su-Jong;Shin, Eun Seob;Lee, Seung Jun;Kang, Beom Mo;Park, Kyu-Hwan;Hong, Seheum;Hwang, Seok-Ho
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.182-187
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    • 2019
  • To improve the mechanical properties of glass-fiber-reinforced polypropylene (PP) composites through interfacial adhesion control between the PP matrix and glass fiber, the surface of the glass fiber was modified with PP-graft-maleic anhydride (MAPP). Surface modification of the glass fiber was carried out through the well-known hydrolysis-condensation reaction using 3-aminopropyltriethoxy silane, and then subsequently treated with MAPP to produce the desired MAPP-anchored glass fiber (MAPP-a-GF). The glass-fiber-reinforced PP composites were prepared by typical melt-mixing technique. The effect of chemical modification of the glass fiber surface on the mechanical properties of composites was investigated. The resulting mechanical and morphological properties showed improved interfacial adhesion between the MAPP-a-GF and PP matrix in the composites.

Tensile Fracture Behavior of Glass Fiber/Polypropylene Composites for Various Fiber Volume Fraction (섬유함유율에 따른 GF/PP 복합재료의 인장파괴거동)

  • Koh, Sung-Wi;Um, Yoon-Sung
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.40 no.2
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    • pp.161-165
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    • 2004
  • The main goal of this work is to study the effect of glass fiber volume fraction on the result of tensile test with respect to glass fiber/polypropylene(GF/PP) composites. The tensile test and failure mechanisms of GF/PP composites were investigated in the fiber volume fraction range from 10% to 30%. The tensile strength and the fracture strength increased with the increasing of the fiber volume fraction in the tested range. Fiber pull-out and debonding of this composites increased with the fiber volume fraction in thc tested range. The major failure mechanisms were classified into the debonding, the fiber pull out, the delamination and the matrix deformation.

Mechanical and thermal properties of Homo-PP/GF/CaCO3 hybrid nanocomposites

  • Parhizkar, Mehran;Shelesh-Nezhad, Karim;Rezaei, Abbas
    • Advances in materials Research
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    • v.5 no.2
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    • pp.121-130
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    • 2016
  • In an attempt to reach a balance of performances in homo-polypropylene based system, the effects of single and hybrid reinforcements inclusions comprising calcium carbonate nanoparticles (2, 4 and 6 phc) and glass fibers (10 wt.%) on the mechanical and thermal properties were investigated. Different samples were prepared by employing twin-screw extruder and injection molding machine. In morphological studies, the uniform distribution of glass fibers in PP matrix, relative adhesion between glass fibers and polymer, and existence of nanoparticles in polymer matrix were observed. $PP/CaCO_3$ (6 phc) as compared to pure PP and PP/GF had superior tensile and flexural strengths, impact resistance and deformation temperature under load (DTUL). $PP/GF/CaCO_3$ (6 phc) composite displayed comparable tensile and flexural strengths and impact resistance to neat PP, while its tensile and flexural moduli and deformation temperature under load (DTUL) were 436%, 99% and $26^{\circ}C$greater respectively. The maximum impact resistance was observed in $PP/CaCO_3$(6 phc). The highest DTUL was perceived in PP hybrid nanocomposite containing 10 wt.% glass fiber and 4 phc $CaCO_3$ nanoparticle.

A Study on the Impact Fracture Behavior of Glass Fiber Polypropylene Composites (GF/PP 복합재료의 충격파괴거동에 관한 연구)

  • 엄윤성
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.35 no.4
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    • pp.421-427
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    • 1999
  • The critical fracture energy and failure mechanisms of GF/PP composites are investigated in the temperatures range of the ambient temperature to $-50^{\circ}C$ The critical fracture energy increase as fiber volume fraction ratio increased The critical fracture energy shows a maximum at ambient temperature and it tends to decrease as temperature goes up. Major failure mechanisms can be classfied such as fiber matrix debonding, fiber pull-out and/or delamination and matrix deformation.

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