• Title/Summary/Keyword: Functional resin

Search Result 231, Processing Time 0.057 seconds

Development of Eco-Friendly High-Solids Paints for Automotive Coatings (환경친화형 고고형분 자동차용 도료의 개발)

  • Park, Chan-Nam;Lee, Won-Ki;Jang, Sung-Ho
    • Journal of Environmental Science International
    • /
    • v.17 no.8
    • /
    • pp.925-932
    • /
    • 2008
  • Manufactures of automotive repair finishes are tending to reduce more and more the level of volatile organic compounds (VOCs) in their paint processes in order to comply with increasingly strict environmental legislation. The production of high solids paints is a way to solve this problem. However, the application of high-solids paints is limited primarily by the viscosity of resin which is strongly related to painting ability: the higher solid content, the lower desired property. In this study, alkyl copolymer with low viscosity was synthesized by the introduction of the monomers with long-side chains and functional groups which improve flexibility and cross-linking density, respectively. The solid content of the paint prepared with the synthesized resin was 80wt% and its VOCs was reduced by 20%, compared to the commercialized paint. Also, the physical and mechanical properties of coatings on steel sheets were similar to commercialized one.

Preferential face coating of knitted PET fabrics via UV curing for water- and oil-repellent finish (자외선 경화에 의한 PET 니트직물의 편면 발수발유 가공)

  • Jeong, Yong-Kyun;Jeong, Yongjin;Jang, Jinho
    • Textile Coloration and Finishing
    • /
    • v.17 no.6 s.85
    • /
    • pp.27-35
    • /
    • 2005
  • Conventional pad- dry-cure(thermo-fixation) process usually produces functional performance on both sides of a fabric. UV curing technique was applied to impart water- and oil-repellent finish effective only on the face of a PET knitted fabric. The preferential one-side coating, by virtue of the limited penetration of UV light, was achieved by W curing after padding of a fluorocarbon agent without special coating or printing equipments. The difference in the functional property of face and back sides was examined by measuring water and oil repellency at each side of the treated fabric. The influence of pre/post-irradiation dose and agent concentration on the performance of the finished fabrics were investigated. While increase in both resin concentration and post-irradiation did not have significant effect on the finish, UV pre-irradiation of PET fabrics caused remarkable influence presumably due to appropriate surface modification of PET fabrics required for facile wetting of the resin. The dimensional stability and color change of the UV cured fabrics measured by FAST and reflectance spectrophotometry showed significantly decreased color difference and increased percent extension compared with the samples pre-irradiated without agent application.

Characterization of Porous Asphalt Concrete Coated with MMA Resin (아크릴 수지로 코팅한 배수성 아스팔트 콘크리트의 특성 평가)

  • Choi, Tae-Jun;Lee, Hyun-Jong;Kim, Tae-Woo;Song, Jae-Hyok
    • International Journal of Highway Engineering
    • /
    • v.11 no.2
    • /
    • pp.111-120
    • /
    • 2009
  • This paper presents a fundamental findings of the functional and structural performance of the porous asphalt concrete coated with MMA resin. To evaluate the structural performance, cantabro, wheel tracking, moisture sensitivity and indirect tensile fatigue tests are performed. The tests results show that the cantabro loss is reduced three times and fatigue resistance is significantly increased after the specimens are coated with MMA resin. However there are little changes in the rutting and moisture damage resistances before and after the coating. Air voids, permeability and BPT(British Pendulum Test) tests are conducted to study the functional performance. It is observed form the tests that the air voids and permeability are slightly decreased after the coating. However, the changes in the air voids and permeability are negligible. The skid resistance of the coated specimens is lower than reference specimens. However, the skid resistance is maintained beyond the level of the reference specimens when silica sands are chipped on top of the coated surface.

  • PDF

A study on the removal of As, Sb, Bi from the copper sulfate solutions by Ion exchange resin containing Aminophosphosphonic acid as a functional group (황산동용액(黃酸銅溶液)에서 Aminophosphosphonic acid 관능기를 가진 이온교환수지에 의한 As, Sb, Bi 제거(除去)에 관한 연구(硏究))

  • Ahn, Jae-Woo;Seo, Jae-Seong
    • Resources Recycling
    • /
    • v.21 no.5
    • /
    • pp.50-57
    • /
    • 2012
  • A comparative study has been carried out on the removal of impurities such As, Sb, Bi from the copper sulfate solution by ion exchange resin containing aminophosphosphonic acid as functional group. The various parameters which affect the removal of impurities; such as the reaction temperature, the reaction time, the amount of ion-exchange resins, the concentration of sulfuric acid in electrolyte, were studied. The basic experimental results showed that about 88% of Sb & 94% of Bi can be adsorbed in these chelate resins and removed from the copper sulfate solutions but As was removed below 10% from the solutions. And the selective elution of Bi and Sb from the adsorbed ion exchange resin also can be achieved by $H_2SO_4$ or HCl solutions. The results also showed that 98.1% of Sb and 96.6% of Bi can be adsorbed from the copper sulfate solutions after 2 Bed-volume of continuous ion exchange column test.

3D Weaving Process : Development of Near Net Shape Preforms and Verification of Mechanical Properties

  • Klapper, Vinzenz;Jo, Kwang-Hoon;Byun, Joon-Hyung;Song, Jung-Il;Joe, Chee-Ryong
    • Composites Research
    • /
    • v.34 no.2
    • /
    • pp.96-100
    • /
    • 2021
  • The lightweight industry continuously demands reliable near-net-shape fabrication where the preform just out-of-machine is close to the final shape. In this study, different half-finished preforms are made π-beams. Then the preforms are unfolded to make a 3D shape with integrated structure of fibers, providing easier handling in the further processing of composites. Several 3D textile preforms are made using weaving technique and are examined after resin infusion for mechanical properties such as inter-laminar shear strength, compressive strength and tensile strength. Considering that the time and labor are important parameters in modern production, 3D weaving technique reduces the manufacturing steps and therefore the costs, such as hand-lay up of textile layers, cutting, and converting into preform shape. Hence this 3D weaving technique offers many possibilities for new applications with efficient composite production.

Improvement of Wrinkle Recovery and Functional Properties in Linen Fabrics (아마직물의 방추성과 복합기능성 향상을 위한 연구)

  • Kang, Mi-Jung;Kwon, Young-Ah
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.34 no.11
    • /
    • pp.1859-1869
    • /
    • 2010
  • This study provides improved wrinkle recovery and UV protection capabilities as well as an antibacterial and deodorizing function to linen fabrics for summer shirts. The results obtained from this study are as follows. By setting catalyst concentration to 1.2% and DMDHEU concentration to 6% respectively and applying a heat treatment to them at $160^{\circ}C$ for 5 minutes, the decrease of fabric strength could be minimized and the crease resistance of linen fabrics improved. Compared to the treatment with DMDHEU only, the crease resistance of linen fabrics could be maintained and degradation of their properties could be more effectively prevented by applying the mixture of the UV absorber and the nano silver to the DMDHEU resin. The UV protection of fabrics could be improved by adding the UV absorber. Although the separate treatment of resin or the nano silver had no effect on the improvement of the UV protection properties for treated fabrics, they could increase the UV protection capability when they were combined with the UV absorber. Linen fabrics could possess an antibiosis and deodorizing capability by applying the mixture of the UV absorber, the nano silver, and the resin. The UV protection, crease resistance and flexibility of finished fabrics were maintained even after laundering. Washed treated fabrics maintained excellent antibiosis and odor free capabilities compared to untreated fabrics.

A study on color characteristics of Multi-color functional Rapid Prototypes Using laser stereolithography (광조형을 이용한 다색 기능성 시작품의 색상특성에 관한 연구)

  • 조진구;정해도;손재혁;임용관
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2000.05a
    • /
    • pp.824-828
    • /
    • 2000
  • As production cycle has become more and more shorter, the demand of rapid prototyping technology has increased largely. There are many methods for rapid prototyping technology, such as SLA. SLS, FDM. INK JET, LOM and so on. Of all methods, SLA has been most widely used for fabricating precision parts. But products manufactured by this method have limitation of single color and single material. So the principal purpose of this study is to overcome the limit of single color product. If the internal structure of manufactured product is visible with multi-color characteristic, it is possible to check easily the designed model with reality. In order to give multi-color characteristic to the product, photocurable resin mixed with pigment is used in this study. First, transparency of photocurable resin without pigment is evaluated, and then color characteristic and curing characteristic of the mixture is evaluated changing mixing ratio. Through the basic experiments, it becomes possible to fabricate multi-color 3D prototype without assembly.

  • PDF

Analysis for Filling Stage of Injection Molding Considering Compressibility and Phase Change (압축성과 상변화를 고려한 사출성형의 충전과정 해석)

  • Lee, Sang-Chan;Park, Chang-Eon;Yang, Dong-Yeol
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.18 no.12
    • /
    • pp.60-65
    • /
    • 2001
  • To simulate the real molding conditions, the effects of phase change and compressibility of the resin were considered in the present investigation. A modified Cross model with either an Arrhenius-type or WLF-type functional form was used for modeling viscosity of the resin. A double-domain Tait equation of state was employed to describe the compressibility of the resin during molding. The energy balance equation including latent-heat dissipation fur semi-crystalline materials was solved in order to predict the solidified layer and temperature profile. Injection molding experiments were carried out using polypropylene(PP) in the present study. Based on the comparison between experiments and simulations, it was found out the predicted pressure distributions and melt front propagations were accurate. Thus it was concluded that the program developed in this study was proved to be useful in simulations of injection molding process.

  • PDF

Ethylene Gas Adsorption of Clay-Woodceramics from 3 layers-clay-woodparticleboard

  • Lee, Hwa Hyoung;Kang, Seog-Goo
    • Journal of the Korean Wood Science and Technology
    • /
    • v.31 no.6
    • /
    • pp.83-88
    • /
    • 2003
  • The woodceramics are porous amorphous carbon and glassy carbon composite materials. Woodceramics attracted a lot of attention in recent years because they are environmentally friendly and because of their unique functional characteristics such as catalysis, moisture absorption, deodorization, purification, carrier for microbial activity, specific stiffness, corrosion and friction resistance, and their electromagnetic shielding capacity. In this paper, we made new products of clay-woodceramics to investigate the industrial analysis and ethylene gas adsorption for basic data of building- and packging- materials keeping fruit fresh for a long time. Clay-woodceramics were carbonized for 3 h of heating in a special furnace under a gas flow of nitrogen(15 ml/min.) from 3 layers-clay-woodparticleboard made from pallet waste wood, phenol- formaldehyde resin(hereafter PF, Non volatile content:52%, resin content 30%), and clay(10%, 20% and 30%). Carbonization temperature was 400℃, 600℃ and 800℃. Experimental results shows that the higher the carbonization temperature, the higher the fixed carbon and the lower the volatile contents. The higher the clay content, the more the ash content. The higher the carbonization temperature, the more the ethylene gas adsorption. Carbonization temperature of 800℃ gave the best reslts as same as that of white charcoal and activated carbon.(800℃-clay-woodceramic: 5.36 ppm, white charcoal: 5.66 ppm, activated carbon: 5.79 ppm) The clay contents did not make difference of ethylene gas adsoption.

Plasma Etching and Polymerization of Carbon Fiber (플라즈마 에칭과 중합에 의한 탄소섬유의 표면 개질)

  • H. M. Kang;Kim, N. I.;T. H. Yoon
    • Proceedings of the Korean Society For Composite Materials Conference
    • /
    • 2002.05a
    • /
    • pp.143-146
    • /
    • 2002
  • Unsized AS-4 carbon fibers were etched by RF plasma and then coated via plasma polymerization in order to enhance adhesion to vinyl ester resin. The gases utilized for the plasma etching were Ar, $N_2 and O_2$, while the monomers used for the plasma polymerization coating were acetylene, butadiene and acrylonitrile. The conditions for the plasma etching and the plasma polymerization were optimized by measuring interfacial adhesion with vinyl ester resin via micro-droplet tests. Among the treatment conditions, the combination of Ar plasma etching and acetylene plasma polymerization provided greatly improved interfacial shear strength (IFSS) of 69MPa compared to 43MPa with as-received carbon fiber. Based on the SEM analysis of failure surface and load-displacement curve, it was assume that the failure might be occurred at the carbon fiber and plasma polymer coating. The plasma etched and plasma polymer coated carbon fibers were subjected to analysis with SEM, XPS, FT-IR or Alpha-Step, and dynamic contact angles and tensile strengths were also evaluated. Plasma polymer coatings did not change tensile strength and surface roughness of fibers, but decreased water contact angle except butadiene plasma polymer coating, possibly owing to the functional groups introduced, as evidenced by FT-IR and XPS.

  • PDF