• Title/Summary/Keyword: Functional Layer

Search Result 683, Processing Time 0.028 seconds

Structural Study of Interface Layers in Tetragonal-HfO2/Si using Density Functional Theory (범 밀도함수론을 이용한 정방정계-HfO2/Si의 계면 층 구조 연구)

  • Kim, D.H.;Seo, H.I.;Kim, Y.C.
    • Journal of the Korean Vacuum Society
    • /
    • v.18 no.1
    • /
    • pp.9-14
    • /
    • 2009
  • We calculated tetragonal-$HfO_2$/Si superstructures using density functional theory. When a and b-axes of cubic-$HfO_2$ were increased to be matched with those of Si for epitaxy contact, c-axis was decreased by 2%. Eight models of interface layers were produced by choosing different terminating layers of tetragonal-$HfO_2$ and Si substrate at the interface. It was found that tetragonal-$HfO_2$ $(004)_{1/4}$/Si $(004)_{3/4}$ superstructure was the most favorable and tetragonal-$HfO_2$ (004)$_{1/4}$/Si (002) superstructure was the most unfavorable. In tetragonal-$HfO_2$ $(004)_{1/4}$/Si (002) superstructure, there were two oxygen vacancies in tetragonal-$HfO_2$ as two oxygen atoms were moved to Si substrate located at the interface.

Vertical Distribution and Composition of Dissolved Free Amino Acids in the Northeast Pacific Ocean (북동태평양 해역의 용존 자유아미노산 분포 및 조성 연구)

  • Son, Seung-Kyu;Park, Yong-Chul;Lee, Kyeong-Yong;Kim, Ki-Hyune;Lee, Hyo-Jin
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
    • /
    • v.4 no.4
    • /
    • pp.289-297
    • /
    • 1999
  • Concentrations of total dissolved free amino acids (DFAAs) in the northeast Pacific Ocean $9^{\circ}54'-10^{\circ}27'N$, $131^{\circ}43'-131^{\circ}53'W$) ranged from 15.9 to 1778.2 17M, and the average was 407.2 nM. Concentrations of DFAAs in surface mixed layers, ranged from 60.1 to 1411.9 nM, and the average was 535.2 nM. Seasonal thermoclines with maxima were formed between the depth of 50 to 150 m. DFAAs in this layer were varied in concentrations from 91.7 to 1778.2 nM, and the average was 588.5 nM. DFAAs below the seasonal thermoclines fluctuated from 15.9 to 384.2 nM, and the average was 175.1 nM. Consequently, in average relatively abundant DFAAs were observed in the subsurface layer than the deeper layer. DFAA vertical profiles and compositions of station A showed similar to station Band C. Glycine, alanine, glutamic acid, serine and valine were predominant accounting for more than 60% of total amino acids. Isoleucine, tyrosine, methionine and phenylalanine comprised only few percents of total DFAAs in the study area. In mole % of amino acid, according to characteristics of functional group of amino acid, aliphatic neutral accounted for 59% and aliphatic hydroxy 16%, acidic 12%, respectively. Although differences in DFAA concentrations with depth were observed, the amino acid composition and mole % of deeper layers in all stations were similar to those of subsurface layers. The results indicate that individual DtAAs remains invariably in water columns relative to the compositions and distributions of DFAAs in the study area, which may be the result of close coupling between microbial activity and their water solubility.

  • PDF

Performance Characteristics of Organic Electroluminescence Diode Using a Carbon Nanotube-Doped Hole Injection Layer (탄소 나노튜브가 도입된 정공 주입층에 의한 유기발광다이오드의 성능 특성 연구)

  • Kang, Hak-Su;Park, Dae-Won;Choe, Youngson
    • Korean Chemical Engineering Research
    • /
    • v.47 no.4
    • /
    • pp.418-423
    • /
    • 2009
  • MWCNT(multi-wall carbon nanotube)-doped PEDOT:PSS(poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)), used as a HIL(hole injection layer) material in OLEDs(organic light emitting diodes), was spin-coated on to the ITO glass to form PEDOT:PSS-MWCNT nano composite thin film. Morphology and transparency characteristics of nano composite thin films with respect to the loading percent of MWCNT have been investigated using FT-IR, UV-Vis and SEM. Furthermore, ITO/PEDOT:PSS-MWCNT/NPD/$Alq_3$/Al devices were fabricated, and then J-V and L-V characteristics were investigated. Functional group-incorporated MWCNT was prepared by acid treatment and showed good dispersion property in PEDOT:PSS solution. PEDOT:PSS-MWCNT thin films possessed good transparency property. For multi-layered devices, it was shown that as the loading percent of MWCNT increased, the current density increased but the luminance dramatically decreased. It might be conclusively suggested that the enhanced charge mobility by MWCNT could increase the current density but the hole trapping property of MWCNT could dramatically decrease the hole mobility in the current devices.

A Performance Comparison of Spatial Scalable Encoders with the Constrained Coding Modes for T-DMB/AT-DMB Services (T-DMB/AT-DMB 서비스를 위한 부호화 모드 제한을 갖는 공간 확장성 부호기의 성능 비교)

  • Kim, Jin-Soo;Park, Jong-Kab;Kim, Kyu-Seok;Choi, Sung-Jin;Seo, Kwang-Deok;Kim, Jae-Gon
    • Journal of Broadcast Engineering
    • /
    • v.13 no.4
    • /
    • pp.501-515
    • /
    • 2008
  • Recently, as users' requests for high quality mobile multimedia services are rapidly increasing and additional bandwidth can be provided by adopting the hierarchical modulation transmission technology, the research on the Advanced Terrestrial DMB (AT-DMB) service using the SVC (Scalable Video Coding) scheme is being actively studied. But, in order to realize a compatible video service and to accelerate the successful standardization and commercialization, it is necessary to simplify the compatible encoder structure. In this parer, we propose a fast mode decision method by constraining the redundant coding modes in the spatial scalable encoder that keeps the current T-DMB video in base layer. The proposed method is based on the statistical characteristics of each coding mode at both base and enhancement layers, inter-layer predictions, which are derived by investigating macroblock-layer coding modes of the spatial scalable encoder's functional structure. Through computer simulations, it is shown that a simplified encoder model that reduces the heavy computational burden can be found, while keeping the objective visual quality very high.

Hydrophobic Coating on Fish Feed Using Dielectric Barrier Discharge Plasma Polymerization (유전체장벽방전 플라즈마 중합을 이용한 양어 사료의 소수성 코팅)

  • Lee, Sang Baek;Hung, Trinhquang;Jo, Jin Oh;Jung, Jun Bum;Im, Tae Heon;Mok, Young Sun
    • Applied Chemistry for Engineering
    • /
    • v.25 no.2
    • /
    • pp.174-180
    • /
    • 2014
  • A plasma hydrophobic coating on commercial fish feed was conducted to prolong the floating time of feed, thereby enhancing the feed consumption rate and reducing the contamination of water in fish farms. The hydrophobic coating on the fish feed was prepared using an atmospheric-pressure dielectric barrier discharge (DBD) plasma with hexamethyldisiloxane (HMDSO), toluene and n-hexane as the precursors. The effect of the parameters such as input power, precursor type and coating time on the coating performance were examined. The physicochemical properties of the coating layer were analyzed using a Fourier transform infrared (FTIR) spectrometer and a contact angle (CA) analyzer. The water CA increased after the coating preparation, indicating that the surface changed from hydrophilic to hydrophobic. The FTIR characterization revealed that the hydrophobic layer was comprised of functional groups such as $CH_3$, Si-O-Si and Si-C. As a result of the hydrophobic coating, the floating time of the fish feed increased from several seconds to 3 minutes, which suggested that the plasma coating method could be a viable means for practical applications. Compared to the water CA measured as soon as the coating layer was prepared, the 6-day aged sample exhibited a substantial CA increase, confirming the aging effect on the improvement of the hydrophobicity.

The Design of Polynomial Network Pattern Classifier based on Fuzzy Inference Mechanism and Its Optimization (퍼지 추론 메커니즘에 기반 한 다항식 네트워크 패턴 분류기의 설계와 이의 최적화)

  • Kim, Gil-Sung;Park, Byoung-Jun;Oh, Sung-Kwun
    • Journal of the Korean Institute of Intelligent Systems
    • /
    • v.17 no.7
    • /
    • pp.970-976
    • /
    • 2007
  • In this study, Polynomial Network Pattern Classifier(PNC) based on Fuzzy Inference Mechanism is designed and its parameters such as learning rate, momentum coefficient and fuzzification coefficient are optimized by means of Particle Swarm Optimization. The proposed PNC employes a partition function created by Fuzzy C-means(FCM) clustering as an activation function in hidden layer and polynomials weights between hidden layer and output layer. Using polynomials weights can help to improve the characteristic of the linear classification of basic neural networks classifier. In the viewpoint of linguistic analysis, the proposed classifier is expressed as a collection of "If-then" fuzzy rules. Namely, architecture of networks is constructed by three functional modules that are condition part, conclusion part and inference part. The condition part relates to the partition function of input space using FCM clustering. In the conclusion part, a polynomial function caries out the presentation of a partitioned local space. Lastly, the output of networks is gotten by fuzzy inference in the inference part. The proposed PNC generates a nonlinear discernment function in the output space and has the better performance of pattern classification as a classifier, because of the characteristic of polynomial based fuzzy inference of PNC.

NO Reduction Performance of V2O5-WO3/TiO2 Catalyst Supported on a Ceramic Sheet Filter (세라믹 시트 필터에 부착된 V2O5-WO3/TiO2 촉매의 NO 환원 성능)

  • Choi, Joo Hong
    • Clean Technology
    • /
    • v.24 no.1
    • /
    • pp.27-34
    • /
    • 2018
  • Catalytic filter has many advantages for the industrial application owing to its bi-functional ability to treat nitrogen oxides and particulate simultaneously. The technical feasibility of using the catalytic filter in the flue gas treatment process will be more promoted if the high porous ceramic sheet filter is utilized. However, it is not easy to prepare the effective catalytic filter using sheet filter as it has less room for catalyst support due to its thin layer. In this study, catalytic filter using a domestic ceramic sheet filter element has been prepared and conducted the experimental evaluation for NO reduction performance. The current sheet filter element shows the low catalytic activity less than 92% conversion for NO concentration 700 ppm at the face velocity $0.02m\;s^{-1}$. This unexpected low catalytic activity seems to be caused by the present of extraordinary large pores from the lack of uniformity in the pore size distribution of the sheet filter. The large pore size of the sheet filter is reduced by composing the smaller powder as its raw material, which presents improvement in NO conversion more than 96%. More improvement is observed showing 98% NO conversion which is applicable to a commercial plant when the catalyst coating layer is expanded by adding the large $TiO_2$ particles during the catalyst preparation. Both of above two methods is regarded as that the broad gates of the larger pores in the coating layer are effectively filled with the proper catalyst. So these results encourage the utilization of sheet filter as a good catalytic filter material with its potential merit of high permeability.

Preparation of TiO2-SiO2 Organic-Inorganic Hybrid Coating Material by Sol-gel Method and Evaluation of Corrosion Characteristics (졸-겔법에 의한 유·무기 TiO2-SiO2 혼성(Hybrid)코팅재료의 제조 및 부식 특성 평가)

  • Noh, J.J.;Maeng, W.Y.
    • Corrosion Science and Technology
    • /
    • v.14 no.2
    • /
    • pp.64-75
    • /
    • 2015
  • Single $TiO_2$ coating prepared by sol-gel process usually experiences cracks in coating layer. In order to prevent cracks, an inorganic-organic hybrid $TiO_2-SiO_2$ coating was synthesized by combining precursors with an organic functional group. Five different coatings with various ratios of (1:8, 1:4, 1:1, 1:0.25 and 1:0.125) titanium alkoxide (TBOT, Tetrabutylorthotitanate) to organo-alkoxysilane (MAPTS, ${\gamma}$-Methacryloxy propyltrimethoxysilane) on carbon steel substrate were made by sol-gel dip coating. The prepared coatings were analyzed to study the coating properties (surface crack, thickness, composition) by scanning electron microscope (SEM), focused ion beam (FIB), and Fourier transform infrared spectroscopy (FT-IR). Potentiodynamic polarization tests and electrochemical impedance spectroscopy (EIS) were also performed to evaluate the corrosion characteristics of the coatings. Crack free $TiO_2-SiO_2$ hybrid coatings were prepared with the optimization of the ratio of TBOT to MAPTS. The corrosion rates were significantly decreased in the coatings for the optimized precursor ratio without cracks.

Simulation of Grape Downy Mildew Development Across Geographic Areas Based on Mesoscale Weather Data Using Supercomputer

  • Kim, Kyu-Rang;Seem, Robert C.;Park, Eun-Woo;Zack, John W.;Magarey, Roger D.
    • The Plant Pathology Journal
    • /
    • v.21 no.2
    • /
    • pp.111-118
    • /
    • 2005
  • Weather data for disease forecasts are usually derived from automated weather stations (AWS) that may be dispersed across a region in an irregular pattern. We have developed an alternative method to simulate local scale, high-resolution weather and plant disease in a grid pattern. The system incorporates a simplified mesoscale boundary layer model, LAWSS, for estimating local conditions such as air temperature and relative humidity. It also integrates special models for estimating of surface wetness duration and disease forecasts, such as the grapevine downy mildew forecast model, DMCast. The system can recreate weather forecasts utilizing the NCEP/NCAR reanalysis database, which contains over 57 years of archived and corrected global upper air conditions. The highest horizontal resolution of 0.150 km was achieved by running 5-step nested child grids inside coarse mother grids. Over the Finger Lakes and Chautauqua Lake regions of New York State, the system simulated three growing seasons for estimating the risk of grape downy mildew with 1 km resolution. Outputs were represented as regional maps or as site-specific graphs. The highest resolutions were achieved over North America, but the system is functional for any global location. The system is expected to be a powerful tool for site selection and reanalysis of historical plant disease epidemics.

Different expression of human GFAP promoter-derived GFP in different subsets of astrocytes in the mouse brain

  • Moon, Young-Hye;Kim, Hyun-Jung;Kim, Joo-Yeon;Kim, Hyun;Kim, Woon-Ryoung;Sun, Woong
    • Animal cells and systems
    • /
    • v.15 no.4
    • /
    • pp.268-273
    • /
    • 2011
  • Transgenic mice expressing green fluorescent protein (GFP) under the control of human glial fibrillary acidic protein promoter (hGFAP) have been utilized for in vivo labeling of astrocytes. Although it has been considered that virtually all astrocytes express GFP in this transgenic mouse, we found that different subsets of GFAP-expressing astrocytes express considerably different levels of GFP in the adult brain. Astrocytes in the spinal cord, the molecular layer of thecerebellum, meninges, white matter, corpus callosum and blood vessels exhibited strong GFP, whereas subsets of astrocytes associated with granule cells in the cerebellum and dentate gyrus did not or only marginally exhibited GFP. We also found that a small subset of GFP-expressing cells in the periglomeruli of the olfactory bulb did not express GFAP immunoreactivity. Collectively, these results suggest that human GFAP promoter-derived GFP expression does not faithfully recapitulate the endogenous GFAP expression in mice, suggesting that upstream regulatory mechanisms controlling GFAP transcription are different in different populations of astrocytes, and may reflect the functional diversity of astrocytes.