• Title/Summary/Keyword: Fuel-cell grade

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Experimental Study of Automotive Gasolines in a Light Aircraft Engine (자동차용 가솔린의 경비행기 엔진 적합성에 관한 실험적 연구)

  • Sung, N.M.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.1
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    • pp.108-117
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    • 1995
  • The primary purpose of this extensive test effort was to observe real-time operational performance characteristics associated with automotive grade fuel utilized by piston engine powered light aviation aircraft. In fulfillment of this effort, baseline engine operations were established with 100LL aviation grade fuel followed by four blends of automotive grade fuel. A comprehensive sea-level-static test cell/flight test data collection and evaluation effort were conducted to review operational characteristics of a carbureted light aircraft piston engine as related to fuel volatility, fuel temperature, and fuel system pressure. Presented herein are results, data, and conclusions drawn from test cell engine operation as well as flight test operation on 100LL aviation grade and four blends of automotive grade fuel.

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Solid Oxide Fuel Cells Designs, Materials, and Applications

  • Singhal Subhash C.
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.777-786
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    • 2005
  • The Solid Oxide Fuel Cell (SOFC) is an electrochemical device to convert chemical energy of a fuel into electricity at temperatures from about 600 to $1000^{\circ}C$. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use CO as a fuel rather than being poisoned by it, and high grade exhaust heat for combined heat and power, or combined cycle gas turbine applications. This paper reviews the operating principle, materials for different cell and stack components, cell designs, and applications of SOFCs. Among all designs of Solid Oxide Fuel Cells (SOFCs), the most progress has been achieved with the tubular design. However, the electrical resistance of tubular SOFCs is high, and specific power output $(W/cm^2)$ and volumetric power density $(W/cm^3)$ low. Planar SOFCs, in contrast, are capable of achieving very high power densities.

Comparison of Electrode Backing Materials for Polymer Electrolyte Membrane Fuel Cells

  • Sasikumar, G.;Ryu, H.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.183-186
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    • 2003
  • In a PEM fuel cell electrode, backing layer has tremendous impact on electrode performance. The backing layer provides structural support for the porous electrode, distributes the reactants to the other layers and acts as a current collector. It has major influence on the water management in a PEM fuel cell. Selection of suitable backing layer material for the fabrication of electrode is thus very important to achieve high performance. In this paper we have compared the performance of PEM fuel cell electrodes fabricated using carbon paper EC-TPI-060T, carbon cloth EC-CCI-060T, (ElectroChem Inc.USA) and Carbon cloth from Textron, USA (CPW 003 grade). Mass transport problem was observed under non-pressurized condition, at high current densities, in the caie of EC-CC1-060T carbon cloth electrode (at $50^{\circ}C$), due to its higher thickness. The performance of carbon paper electrode was higher than EC-CCI-060T carbon cloth electrode. The performance of Textron carbon cloth was comparable to EC-TPI -060T carbon paper.

Analyses and improvement of fuel temperature coefficient of rock-like oxide fuel in LWRs from neutronic aspect

  • Shelley, Afroza
    • Nuclear Engineering and Technology
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    • v.52 no.6
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    • pp.1156-1163
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    • 2020
  • Fuel temperature coefficient (FTC) of PuO2+ZrO2 (ROX) fueled LWR cell is analyzed neutronically with reactor- and weapons-grade plutonium fuels in comparison with a U-free PuO2+ThO2 (TOX), and a conventional MOX fuel cells. The FTC value of a ROX fueled LWR is smaller compared to a TOX or a MOX fueled LWRs and becomes extremely positive especially, at EOL. This is because when fuel temperature is increased, thermal neutron spectrum is shifted to harder, which is extreme at EOL in ROX fuel than that in TOX and MOX fuels. Consequently at EOL, 239Pu and 241Pu contributes to positive fuel temperature reactivity (FTR) in ROX fuel, while they have negative contribution in TOX and MOX fuels. The FTC problem of ROX fuel is mitigated by additive ThO2, UO2 or Er2O3. In ROX-additive fuel, the atomic density of fissile Pu becomes more than additive free ROX fuel especially at EOL, which is the main cause to improve the FTC problem. The density of fissile Pu is more effective to decrease the thermal spectrum shifts with increase the fuel temperature than additive ThO2, UO2 or Er2O3 in ROX fuel.

Novel Sorption Enhanced Reaction Process for Direct Production of Fuel-Cell Grade $H_2$ from Synthesis Gas (합성가스로부터 연료전지급 수소의 직접 생산을 위한 흡착분리 반응 동시 공정)

  • Lee, Ki-Bong;Jeon, Sang-Goo;Na, Jeong-Geol;Ryu, Ho-Jung
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.745-748
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    • 2009
  • 수소는 지구상에 풍부하게 존재하는 원소로 최근 수소경제시대에 대한 기대와 함께 청정 에너지 carrier로 주목받고 있다. 본 연구에서는 고순도 수소 생산을 위해 water gas shift (WGS) 반응과 $CO_2$의 분리를 하나의 unit operation의 형태로 수행하는 신개념의 thermal swing sorption enhanced reaction (TSSER) 공정의 타당성을 테스트하는데 목적을 두고 있다. Le Chatelier 원리를 기본으로 하는 흡착분리 동시 반응 (sorption enhanced reaction, SER)에서는 수소생산 반응의 열역학적 한계를 극복할 수 있고 정반응의 속도를 증대시킬 수 있다. 본 연구에서는 $K_2CO_3$가 첨가된 hydrotalcite에 대한 고온에서의 $CO_2$ 화학흡착 평형 및 거동 데이터를 실험을 통하여 측정하였다. 또한 WGS 상용촉매와 화학 흡착제를 이용하여 흡착분리 동시 반응을 실험과 수치해석 시뮬레이션으로 수행하였고, 연구결과로부터 연료전지에 사용할 수 있는 고순도의 수소 (~10 ppm CO)를 직접 생산할 수 있으며, 동시에 고압상태의 $CO_2$를 고순도로 포집할 수 있음을 확인할 수 있었다. 고압, 고순도의 $CO_2$ 포집은 이후 $CO_2$ 저장에 용이하게 이용되어 온실가스 저감에 기여할 수 있을 것으로 기대된다.

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A First Principles Study on Nano-scale Pt Alloy Structures for Fuel Cell Catalysts (제일원리전산을 이용한 연료전지용 나노 스케일 백금 합금촉매에 대한 열역학적 구조 분석)

  • Noh, Seung-Hyo;Han, Byung-Chan
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.217-221
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    • 2012
  • Over the last decade, performances of low temperature fuel cells are substantially improved by developing highly active Pt-M alloy catalysts. The electrochemical stability of those catalysts, however, still does not meet the commercial grade for fuel cells to be long-term power sources of electrical vehicles. To unveil a major mechanism causing such weak durability, we extensively utilize ab-initio computations on nano-scale Pt-Co alloy catalysts and analyze thermodynamically the most stable structure as a function of compositional variation. Our results indicate that there is a certain feature governing the particle distribution of a specific alloy element on the nano-scale catalysts, which aggravates the electrochemical degradation.

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Electrochemical Characteristics of MMO(Ti/Ru)-Coated Titanium in a Cathode Environment of Polymer Electrolyte Membrane Fuel Cell (MMO(Ti/Ru) 코팅된 타이타늄의 고분자 전해질 연료전지 양극환경에서의 전기화학적 거동)

  • Heo, Ho-Seong;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.5
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    • pp.340-347
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    • 2022
  • In this research, mixed metal oxide (TiO2, RuO2) coating was applied to grade 1 titanium as a bipolar plate for polymer electrolyte membrane fuel cell (PEMFC). Electrochemical experiments were carried out in an aqueous solution of pH 3 (H2SO4 + 0.1 ppm HF, 80 ℃) determined by DoE. The air was bubbled to simulate a cathode environment. Potentiodynamic polarization test revealed that corrosion current densities of the titanium substrate and MMO-coated specimen were 0.180 µA/cm2 and 4.381 µA/cm2, respectively. There was no active peak. After potentiostatic experiment, current densities of the titanium substrate and the MMO-coated specimen were 0.19 µA/cm2 and 1.05 µA/cm2, respectively. As a result of observing the surface before and after the potentiostatic experiment, cracked dried clay structures were observed without corrosion damage. Both the titanium substrate and the MMO-coated specimen could not satisfy the interfacial contact resistance suggested by the DoE. Thus, further research is needed before they could be applied as bipolar plates.

Comparison of Metal Cleaning Effect on Pt Particles Supported on Carbon and Pt Black Observed by NMR, CV, and TEM

  • Han, Kee-Sung;Han, Oc-Hee
    • Journal of the Korean Magnetic Resonance Society
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    • v.6 no.1
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    • pp.38-44
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    • 2002
  • 60% Pt on Vulcan XC-72 with similar Pt sizes to fuel cell grade Pt black was investigated by $\^$13/C nuclear magnetic resonance spectroscopy (NMR), cyclic voltammery (CV), transmission electron microscopy (TEM). Experiments were carried out on electrochemically cleaned samples as well as as-received. The TEM and CV results showed that the average particle sizes were changed by cleaning. However, the chemical shift ($\delta$$\_$G/) of $\^$13/C of $\^$13/CO absorbed on Pt surfaces did not show any appreciable variation with particle size change as did in Pt black. These results indicate that a combination of different analytic techniques is essential to understand the properties of the metal particle catalysts and that the presence of carbon black support strongly influences the NMR data, probably through metal-support interaction.

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A Study on the Preparation and Application of Au/TiO2 Nanofiber from AAO Template (AAO Template를 이용한 Au/TiO2 나노섬유 제조 및 응용에 관한 연구)

  • Eom, Seon-Mi;Park, Sang-Sun;Kim, Young-Deok;Kim, Yong-Rok;Shul, Yong-Gun
    • Journal of the Korean Electrochemical Society
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    • v.12 no.1
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    • pp.47-53
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    • 2009
  • In this study, highly ordered AAO (Anodic Aluminum Oxide) with nanopores was prepared by commercial grade Al substrate containing 3.5 wt.% impurities through two step anodizing method. Nanopores of prepared AAO arrays were used as templates for preparing nanofiber. $TiO_2$ was deposited by using DP (deposition-precipitation) method into AAO pores to grow nanofiber. Au particles were loaded on this $TiO_2$ nanofiber which was grown vertically. Prepared 2 wt.% $Au/TiO_2$ nanofiber was characterized by XRD, SEM and Raman. The crystal structure was analyzed by the XRD. SEM was used to observe pore size and pore wall thickness. Photocatalytic activity of co-oxidation was compared with $TiO_2$ and $Au/TiO_2$ nanofiber on AAO arrays.

Development of Urban Driving Cycle for Performance Evaluation of Electric Vehicles Part I : Development of Driving Cycle (전기 자동차 성능 평가를 위한 도심 주행 모드 개발 Part I : 주행 모드 개발)

  • Yang, Seong-Mo;Jeong, Nak-Tak;Kim, Kwang-Seup;Choi, Su-Bin;Wang, Maosen;Kim, Hyun-Soo;Suh, Myung-Won
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.7
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    • pp.117-126
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    • 2014
  • Recently, due to various environmental problems such as global warming, increasing of international oil prices and exhaustion of resource, a paradigm of world automobile market is rapidly changing from vehicles using internal combustion engine to eco-friendly vehicles using electric power such as EV (Electric Vehicle), HEV (Hybrid Electric Vehicle), PHEV (Plug-in Hybrid electric Vehicle) and FCEV (Fuel Cell Electric Vehicle). There are many driving cycles for performance evaluation of conventional vehicles. However there is a lack of researches on driving cycle for EV. This study is composed of part 1 and part 2. In this paper part 1, in order to develop urban driving cycle for performance evaluation of electric vehicles, Gwacheon-city patrol route of police patrol car was selected. Actual driving test was performed using EV. The driving data such as velocity, time, GPS information etc. were recorded. GUDC-EV (Gwacheon-city Urban Driving Cycle for Electric Vehicles) including road gradient was developed through the results of analyzing recorded data. Reliability of the driving cycle development method was substantiated through comparison of electricity performance. In the second part of this study, the developed driving cycle was compared to simulation result of the existing urban driving cycle. Verification of the developed driving cycle for EV performance evaluation was described.