• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.675-680
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• 2009

This article describes NO emission characteristics in SM coal combustion. Combustion experiments was performed in the method of increasing temperature after feeding coal and feeding coal after increasing temperature. NOx emission is in inverse proportion to combustion temperature at the fuel rich condition and it was caused by conversion fuel N to $N_{2}$ at the strong reduction condition. In addition, feeding gas flow rate increased as total fuel NOx increase by conversion of fuel N to NO at the oxidation condition. It could be separated in total fuel-N, volatile-N, char-N to NO according to analysis of total fuel NO emission from char combustion at each temperature. In the result, almost total NOx emission was caused by volatile-N in SM-coal.

• Journal of Aerospace System Engineering
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• v.11 no.4
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• pp.8-14
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• 2017

In this study, the production of proper emulsion fuel and the evaluation of its rheological stability in various experimental conditions were carried out. The W/O (water-in-oil) emulsion fuel was made using n-decane, pure water, and Span 80 was used as a surfactant. Increments of water volume ratio and fuel temperature were the factors, which boosted the phase separation of the emulsion fuel. Rheological characteristics for different water/oil volume ratio, temperature, and elapsed time after the fuel production were examined. As the water volume ratio in the fuel increased, the behavior of non-Newtonian fluid was observed. Viscosity declined as the fuel temperature increased due to the cohesion of water droplets in the fuel. The effect of elapsed time on viscosity was not severe for lower water ratio. However, gradual decrease of viscosity 3 hours after fuel production, in the case of ratio of 3:7, was clearly observed.

• Journal of the Korean Society of Combustion
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• v.20 no.3
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• pp.21-26
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• 2015

This study was performed to provide the information of the combustion characteristics of n-butanol fuel in accordance with the n-heptane fuel mixing ratio. The closed homogeneous reactor model was used for the analysis. The analysis conditions were set to 800 K of the initial temperature, 20 atm of initial pressure and 1.0 of equivalence ratio. The results of analysis were compared in terms of combustion temperature, combustion pressure, CO, Soot and $NO_X$ emissions. The results of combustion and exhaust emission characteristics showed that ignition delay was decreased and the combustion temperature was increased as the n-heptane mixing ratio was increased. Also, the carbon monoxide(CO) was slightly decreased however, the soot and nitrogen oxides($NO_X$) increased a little in accordance with the n-heptane fuel mixing ratio. In addition, the pressure difference was almost the same in any conditions.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.1
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• pp.35-42
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• 2009

In this study, a spark ignition engine operated with LPG and DME blended fuel was studied experimentally. The effect of n-butane and propane on performance and emissions of a SI engine fuelled by LPG/DME blended fuel were examined. Stable engine operation was achieved for a wide range of engine loads with propane containing LPG/DME blended fuel compare to butane containing LPG/DME blended fuel since octane number of propane was much higher than that of butane. Also, engine output operated with propane containing blended fuel was comparable to pure LPG fuel operation. Engine output power was decreased and break specific fuel consumption (BSFC) was increased with the blended fuel since the energy content of DME was much lower than that of LPG. Considering the results of engine output power, bsfc, and exhaust emissions, the propane containing LPG/DME blended fuel could be used as an alternative fuel for LPG.

• Journal of Power System Engineering
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• v.9 no.3
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• pp.15-20
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• 2005

In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated for an indirect injection diesel engine. It was tested to estimate change of engine performance and exhaust emission characteristics for the commercial diesel fuel and oxygenated blended fuel which has four kinds of mixed ratio. And, the effects of exhaust gas recirculation(EGR) on the characteristics of NOx emission have been investigated. Ethylene glycol mono-n-butyl ether(EGBE) contains oxygen component 27% in itself, and it is a kind of effective oxygenated fuel of mono-ether group that the smoke emission of EGBE is reduced remarkably compared with commercial diesel fuel, that is, it can supply oxygen component sufficiently at higher loads and speeds in diesel engine. It was found that simultaneous reduction of smoke and NOx was achieved with oxygenated fuel(10vol-%) and cooled EGR method(10%).

• 한국연소학회:학술대회논문집
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• 2002.06a
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• pp.185-191
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• 2002

The influence of N2 addition on soot formation, flame temperature and NOx emissions is investigated experimentally with methane fuel co-flow diffusion flames. The motivation of the present investigation is the differences in NOx reduction reported between fuel-side and oxidizer-side introduction of N2. To determine the influence of dilution alone, fuel was diluted with nitrogen while keeping the adiabatic flame temperature fixed by changing the temperature of the reactants. And to see the thermal effect only, air was supplied at different temperature without N2 addition. N2 addition into fuel side suppressed the soot formation than the case of oxidizer-side, while flame temperature enhanced the soot formation almost linearly. These results reveals the relative influences of the thermal, concentration effects of N2 additives on soot formation In accordance with experimental study, numerical simulation using CHEMKIN code was carried out to compare the temperature results with those acquired by CARS measurement, and we could find that there is good agreement between those results. Emission test revealed that NOx emissions were affected by not only flame temperature but also N2 addition.

• Journal of ILASS-Korea
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• v.21 no.1
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• pp.29-36
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• 2016

The effect of high ambient temperature and pressure conditions on the combustion performance of n-butanol, n-heptane and its mixing fuel (BH 20) were studied in this work. To reveal this, the closed homogeneous reactor model applied and 1000-1200 K of the initial temperature, 20-30 atm of initial pressure and 1.0 of equivalence ratio were set to numerical analysis. It was found that the results of combustion temperature was increased and the ignition delay was decreased when the ambient conditions were elevated since the combustion reactivity increased at the high ambient conditions. On the contrary, under the low combustion temperature condition, the combustion pressure was more influenced by the ambient temperature in the same ambient conditions. In addition, the total mass and the mass density of tested fuels were influenced by the ambient pressure and temperature. Also, soot generation of mixing fuel was decreased than n-heptane fuel due to the oxygen content of n-butanol fuel.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.118-127
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• 2012

TiN or Ti/TiN was coated on stainless steel as bipolar plate in polymer electrolyte membrane fuel cells (PEMFCs) to improve their corrosion resistance and electric conductivity, and their properties were examined under fuel cell operating condition. After 200 hours operation, the behaviors for the corrosion, crack and dissolution of coating layer were investigated by various techniques. The corrosion and exfoliation of coating layer were considerably generated except for SUS316L-Ti/TiN after fuel cell operation even if the electric conductivity and corrosion resistance of coated stainless steel bipolar plates were improved. The adoption of Ti layer between TiN layer and the surface of stainless steel enhanced the adhesion of TiN layer and decreased the possibility of corrosion by the increase of coating layer.

• Korean Journal of Environmental Agriculture
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• v.18 no.1
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• pp.83-85
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• 1999

This study was conducted to find out analytical method for diesel fuel using uv-spectrophotometer in water samples. The optimum wavelength, detection limit and recoveries for desel fuel extracted with n-pentane were 257nm, $100{\sim}800mg/l$ and $102{\sim}121%$, respectively. This method were stable for measuring concentrations of desel fuel for 1 hour at $20{\pm}1^{\circ}C$ condition.

• Nuclear Engineering and Technology
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• v.53 no.11
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• pp.3704-3710
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• 2021

The characteristics of the external radiation on the surface of the casks for spent nuclear fuel (SNF) storage by dry method are investigated for the case when the spatial distribution of SNF in the basket changes due to the destruction of the fuel rod claddings. The surface areas are determined, where the changes in fluxes of neutrons, produced by ²⁴⁴Cm actinide, and γ-quanta, produced by long-lived isotopes, are maximum in the result of the decrease in the height of the SNF area. Concrete (VSC-24) and metal (SC-21) casks are considered as examples. The procedure of periodic measurement of the dose rate of neutrons or γ-quanta at the specified points of the cask surface is proposed for identifying the fuel rod cladding destruction. Under normal operation, the decrease in the dose rate produced by neutrons as the function of SNF storage duration is determined by the half-life of ²⁴⁴Cm, and for γ-quanta - by the half-lives of long-lived SNF isotopes. Consequently, a stepwise change in the dose rate of neutrons or γ-quanta, detected by the measurements, as compared to the previous one, would indicate the destruction of the fuel rod claddings.