• 제목/요약/키워드: Fuel type identification

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The Identification of Spilled Oil by the Pattern of Alkyl PAH

  • Bae, Il-Sang;Shin, Ho-Sang;Lee, Jae-Young;Jung, Kweon;Lee, Yeon-soo
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.289-292
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    • 2004
  • In order to identify the origin and nature of the spilled oil in the potential source, we analyzed the pattern of alkyi PAM(Polynuclear Aromatic Hydrocarbons) in fuel standard and environmental samples. Alkyl PAM patterns are used for fuel-type identification in weathered environmental samples. Detection of alkyl PAH was achieved by operation CC/MS in the SIM mode. We chose ions of naphthalene(m/z 128), C1-naphthalene(m/z 142), C2-naphthalene(m/z 156), C3-naphthalene(m/z 170), C4-naphthalene(m/z 184) for the comparison of this pattern according to the type of fuel. We analyzed tile pattern of alkyl PAH in neat gasoline, kerosene, diesel, and JP-8, and in groundwater samples which were collected in monitoring wells. The distribution map of alkyl-naphthalene shows different patterns among four different fuel types (gasoline, kerosene, diesel, and JP-8). Particularly, tile distribution map of kerosene and JP-8 is found to be of value in identifying fuel type in that the difference is clear. Therefore distribution patterns of alkyl-PAH compounds provide another useful tool for fuel-type identification of petroleum fuels.

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The Source Identification of Spilled Oil by Pristane/Phytane Ratio

  • Bae, Il-Sang;Kweon Jung;Oh, Hyun-Jung;Shin, Ho-Sang;Lee, Jae-Young
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제8권4호
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    • pp.64-67
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    • 2003
  • 잠재오염원에서 누출된 유류의 기원을 확인하기 위해서 표준연료와 환경시료중의 유류 구성성분의 농도를 분석하였다. pristane/phytane의 비는 환경시료 중 같은 휘발성을 가지고 있기 때문에 실질적으로 변하지 않는다. 이것은 미생물분해와 풍화의 영향을 평가하고 유류의 오염원을 확인하는데 유용하였다. L과 S 주유소에서 백등유, 보일러등유, JP-8, 경유의 pristane/phytane 비를 측정하였다. L-백등유와 JP-8에서 pristane/phytane 비는 각각 3.10$\pm$0.03, 1.77$\pm$0.01였으며, 유류와 물을 분배시킨 후 물층에서 pristane/phytane 비는 백등유 2.97$\pm$0.02, JP-8 1.65$\pm$0.02였다. pristane/phytane 비는 백등유와 JP-8을 구분하는 유효하였으며, 또한 관측정에서 수집된 자유상유류와 지하수시료에서 유종을 확인하는데 유용하였다.

AIS를 활용한 인천항 선박의 온실가스 배출량 추정 (Assessment of greenhouse gas emissions from ships operation at the Port of Incheon using AIS)

  • ;장영태;이수형;최경숙
    • 한국항만경제학회지
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    • 제34권1호
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    • pp.65-80
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    • 2018
  • 본 연구는 2014년 10월 동안 인천항만에 기항하는 선박들의 온실가스 배출량을 추정하고자 시도되었다. 온실가스 배출량 추정을 위하여 AIS 데이터를 토대로 한 Bottom-up 방식을 활용하였으며 연료소비총량과 연료소비의 결과로서 발생한 이산화탄소 총량을 함께 분석하였다. 배출량 추정은 선박의 종류를 토대로 추정되었으며 각각 개별 선박의 날짜-시간 스템프 사이에서 그들의 움직임에 따라 계산되었다. 인천항에서 운항되는 최종 330 척(AIS-데이터)의 선박 샘플의 결과에 따르면 선박들의 총 이산화탄소 배출량은 164693.06 톤으로 추정되었으며, 연구기간동안 이들 선박의 총 연료소비량은 51953.64 톤에 이르는 것으로 나타났다. 선박의 종류에 따른 구체적 분석 결과를 살펴보면, 여객선이 배출량 81409.6톤으로 가장 오염이 심한 선박으로 나타났으며, 그 뒤를 이어 예인선 (37248.4톤), 화물선 (32154.6톤), 다른 활동에 사용된 선박 (9039.1톤), 화학 탱커 (4027.06톤) 그리고 어선 (814.048톤) 순으로 확인되었다.

Development of Micro-Blast Type Scabbling Technology for Contaminated Concrete Structure in Nuclear Power Plant Decommissioning

  • Lee, Kyungho;Chung, Sewon;Park, Kihyun;Park, SeongHee
    • 방사성폐기물학회지
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    • 제20권1호
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    • pp.99-110
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    • 2022
  • In decommissioning a nuclear power plant, numerous concrete structures need to be demolished and decontaminated. Although concrete decontamination technologies have been developed globally, concrete cutting remains problematic due to the secondary waste production and dispersion risk from concrete scabbling. To minimize workers' radiation exposure and secondary waste in dismantling and decontaminating concrete structures, the following conceptual designs were developed. A micro-blast type scabbling technology using explosive materials and a multi-dimensional contamination measurement and artificial intelligence (AI) mapping technology capable of identifying the contamination status of concrete surfaces. Trials revealed that this technology has several merits, including nuclide identification of more than 5 nuclides, radioactivity measurement capability of 0.1-107 Bq·g-1, 1.5 kg robot weight for easy handling, 10 cm robot self-running capability, 100% detonator performance, decontamination factor (DF) of 100 and 8,000 cm2·hr-1 decontamination speed, better than that of TWI (7,500 cm2·hr-1). Hence, the micro-blast type scabbling technology is a suitable method for concrete decontamination. As the Korean explosives industry is well developed and robot and mapping systems are supported by government research and development, this scabbling technology can efficiently aid the Korean decommissioning industry.

Practical Challenges Associated with Catalyst Development for the Commercialization of Li-air Batteries

  • Park, Myounggu;Kim, Ka Young;Seo, Hyeryun;Cheon, Young Eun;Koh, Jae Hyun;Sun, Heeyoung;Kim, Tae Jin
    • Journal of Electrochemical Science and Technology
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    • 제5권1호
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    • pp.1-18
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    • 2014
  • Li-air cell is an exotic type of energy storage and conversion device considered to be half battery and half fuel cell. Its successful commercialization highly depends on the timely development of key components. Among these key components, the catalyst (i.e., the core portion of the air electrode) is of critical importance and of the upmost priority. Indeed, it is expected that these catalysts will have a direct and dramatic impact on the Li-air cell's performance by reducing overpotentials, as well as by enhancing the overall capacity and cycle life of Li-air cells. Unfortunately, the technological advancement related to catalysts is sluggish at present. Based on the insights gained from this review, this sluggishness is due to challenges in both the commercialization of the catalyst, and the fundamental studies pertaining to its development. Challenges in the commercialization of the catalyst can be summarized as 1) the identification of superior materials for Li-air cell catalysts, 2) the development of fundamental, material-based assessments for potential catalyst materials, 3) the achievement of a reduction in both cost and time concerning the design of the Li-air cell catalysts. As for the challenges concerning the fundamental studies of Li-air cell catalysts, they are 1) the development of experimental techniques for determining both the nano and micro structure of catalysts, 2) the attainment of both repeatable and verifiable experimental characteristics of catalyst degradation, 3) the development of the predictive capability pertaining to the performance of the catalyst using fundamental material properties. Therefore, under the current circumstances, it is going to be an extremely daunting task to develop appropriate catalysts for the commercialization of Li-air batteries; at least within the foreseeable future. Regardless, nano materials are expected to play a crucial role in this field.

GC/MS 분석과 베이지안 분류 모형을 이용한 새 윤활유와 사용 엔진 오일의 동일성 추적과 분류 (Identification and classification of fresh lubricants and used engine oils by GC/MS and bayesian model)

  • 김남이;남금문;김유나;이동계;박세연;이경재;이재용
    • 분석과학
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    • 제27권1호
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    • pp.41-59
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    • 2014
  • 국내 시판제품으로 서울시내에서 구입한 산업용 윤활유, 이륜구동 윤활유, 선박용 윤활유, 자동차용 윤활유(엔진오일, 수동 변속기 기어유, 자동변속기 오일) 등 80종(기유 4종 포함)의 새 윤활유들(80 classes)과 8종의 경유 차량과 16종의 휘발유 차량에 각각 3종씩의 경유와 휘발유 전용 엔진 오일로 교환하여 차량별 및 주행거리별로 각각 채취한 사용 엔진 오일 86종을 GC/MS로 분석한 TIC로 데이터베이스를 만들고, 새 윤활유와 사용 엔진오일들의 동일성 추적과 차량별 분류를 위하여 차원 축소와 베이지안 방식의 분류 모형을 개발하였다. 새 윤활유의 분류는 웨이블렛 적합방법과 주성분 분석방법으로 차원 축소하여 베이지안 방식의 분류 모형을 적용한 결과 각각 97.5%와 96.7%의 정분류율을 보여 차원 축소는 웨이블렛 적합방법이 더 좋은 결과를 나타냈다. 그리고 새 윤활유의 분류에서 선택된 웨이블렛 적합방법의 차원 축소와 베이지안 방식의 분류 모형에 의한 사용 엔진 오일의 차량별 분류(총 24 classes)는 86.4%의 정분류율을 보였고, 경유 차량인지 휘발유 차량인지를 구분하는 차량 연료 타입별 분류(총 2 classes)는 99.6%의 정분류율을 나타내었고, 사용 엔진 오일 브랜드별 분류(총 6 classes)는 97.3%의 정분류율을 나타내었다.

APPLICATION OF FUZZY SET THEORY IN SAFEGUARDS

  • Fattah, A.;Nishiwaki, Y.
    • 한국지능시스템학회:학술대회논문집
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    • 한국퍼지및지능시스템학회 1993년도 Fifth International Fuzzy Systems Association World Congress 93
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    • pp.1051-1054
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    • 1993
  • The International Atomic Energy Agency's Statute in Article III.A.5 allows it“to establish and administer safeguards designed to ensure that special fissionable and other materials, services, equipment, facilities and information made available by the Agency or at its request or under its supervision or control are not used in such a way as to further any military purpose; and to apply safeguards, at the request of the parties, to any bilateral or multilateral arrangement, or at the request of a State, to any of that State's activities in the field of atomic energy”. Safeguards are essentially a technical means of verifying the fulfilment of political obligations undertaken by States and given a legal force in international agreements relating to the peaceful uses of nuclear energy. The main political objectives are: to assure the international community that States are complying with their non-proliferation and other peaceful undertakings; and to deter (a) the diversion of afeguarded nuclear materials to the production of nuclear explosives or for military purposes and (b) the misuse of safeguarded facilities with the aim of producing unsafeguarded nuclear material. It is clear that no international safeguards system can physically prevent diversion. The IAEA safeguards system is basically a verification measure designed to provide assurance in those cases in which diversion has not occurred. Verification is accomplished by two basic means: material accountancy and containment and surveillance measures. Nuclear material accountancy is the fundamental IAEA safeguards mechanism, while containment and surveillance serve as important complementary measures. Material accountancy refers to a collection of measurements and other determinations which enable the State and the Agency to maintain a current picture of the location and movement of nuclear material into and out of material balance areas, i. e. areas where all material entering or leaving is measurab e. A containment measure is one that is designed by taking advantage of structural characteristics, such as containers, tanks or pipes, etc. To establish the physical integrity of an area or item by preventing the undetected movement of nuclear material or equipment. Such measures involve the application of tamper-indicating or surveillance devices. Surveillance refers to both human and instrumental observation aimed at indicating the movement of nuclear material. The verification process consists of three over-lapping elements: (a) Provision by the State of information such as - design information describing nuclear installations; - accounting reports listing nuclear material inventories, receipts and shipments; - documents amplifying and clarifying reports, as applicable; - notification of international transfers of nuclear material. (b) Collection by the IAEA of information through inspection activities such as - verification of design information - examination of records and repo ts - measurement of nuclear material - examination of containment and surveillance measures - follow-up activities in case of unusual findings. (c) Evaluation of the information provided by the State and of that collected by inspectors to determine the completeness, accuracy and validity of the information provided by the State and to resolve any anomalies and discrepancies. To design an effective verification system, one must identify possible ways and means by which nuclear material could be diverted from peaceful uses, including means to conceal such diversions. These theoretical ways and means, which have become known as diversion strategies, are used as one of the basic inputs for the development of safeguards procedures, equipment and instrumentation. For analysis of implementation strategy purposes, it is assumed that non-compliance cannot be excluded a priori and that consequently there is a low but non-zero probability that a diversion could be attempted in all safeguards ituations. An important element of diversion strategies is the identification of various possible diversion paths; the amount, type and location of nuclear material involved, the physical route and conversion of the material that may take place, rate of removal and concealment methods, as appropriate. With regard to the physical route and conversion of nuclear material the following main categories may be considered: - unreported removal of nuclear material from an installation or during transit - unreported introduction of nuclear material into an installation - unreported transfer of nuclear material from one material balance area to another - unreported production of nuclear material, e. g. enrichment of uranium or production of plutonium - undeclared uses of the material within the installation. With respect to the amount of nuclear material that might be diverted in a given time (the diversion rate), the continuum between the following two limiting cases is cons dered: - one significant quantity or more in a short time, often known as abrupt diversion; and - one significant quantity or more per year, for example, by accumulation of smaller amounts each time to add up to a significant quantity over a period of one year, often called protracted diversion. Concealment methods may include: - restriction of access of inspectors - falsification of records, reports and other material balance areas - replacement of nuclear material, e. g. use of dummy objects - falsification of measurements or of their evaluation - interference with IAEA installed equipment.As a result of diversion and its concealment or other actions, anomalies will occur. All reasonable diversion routes, scenarios/strategies and concealment methods have to be taken into account in designing safeguards implementation strategies so as to provide sufficient opportunities for the IAEA to observe such anomalies. The safeguards approach for each facility will make a different use of these procedures, equipment and instrumentation according to the various diversion strategies which could be applicable to that facility and according to the detection and inspection goals which are applied. Postulated pathways sets of scenarios comprise those elements of diversion strategies which might be carried out at a facility or across a State's fuel cycle with declared or undeclared activities. All such factors, however, contain a degree of fuzziness that need a human judgment to make the ultimate conclusion that all material is being used for peaceful purposes. Safeguards has been traditionally based on verification of declared material and facilities using material accountancy as a fundamental measure. The strength of material accountancy is based on the fact that it allows to detect any diversion independent of the diversion route taken. Material accountancy detects a diversion after it actually happened and thus is powerless to physically prevent it and can only deter by the risk of early detection any contemplation by State authorities to carry out a diversion. Recently the IAEA has been faced with new challenges. To deal with these, various measures are being reconsidered to strengthen the safeguards system such as enhanced assessment of the completeness of the State's initial declaration of nuclear material and installations under its jurisdiction enhanced monitoring and analysis of open information and analysis of open information that may indicate inconsistencies with the State's safeguards obligations. Precise information vital for such enhanced assessments and analyses is normally not available or, if available, difficult and expensive collection of information would be necessary. Above all, realistic appraisal of truth needs sound human judgment.

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