• Journal of the Korean Ceramic Society
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• v.55 no.4
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• pp.358-363
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• 2018

To improve the polarization property of cathodes, which is the main factor limiting the performance of protonic ceramic fuel cells (PCFCs), $K_2NiF_4-type$ $Pr_2NiO_{4+{\delta}}$, which is expected to exhibit a triple conducting property (proton, oxygen ion, and hole conductions) was applied to PCFCs and its properties were investigated. Low-temperature microwave heat-treatment was used to achieve both sufficient interface adhesion between the electrolyte and the cathode layers and suppression of the secondary phase formation due to migration of elements such as barium and cerium. Through this fabrication method, a high performance of $0.82W{\cdot}cm^{-2}$ and low ohmic resistance of $0.06{\Omega}{\cdot}cm^2$ were obtained in an $Ni-BaCe_{0.55}Zr_{0.3}Y_{0.15}O_{3-{\delta}}$ | $BaCe_{0.55}Zr_{0.3}Y_{0.15}O_{3-{\delta}}$ | $Pr_2NiO_{4+{\delta}}$ single cell at $650^{\circ}C$. This result verifies that the $K_2NiF_{4+{\delta}}-type$ cathode shows good chemical compatibility which, in turn, will make it a potent candidate as a PCFC cathode.

• Journal of the Korean Ceramic Society
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• v.52 no.5
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• pp.344-349
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• 2015

An interconnect is the key component of solid oxide fuel cells that electrically connects unit cells and separates fuel from oxidant in the adjoining cells. To improve their surface stability in high-temperature oxidizing environments, metallic interconnects are usually coated with conductive oxides. In this study, lanthanum nickelates ($LaNiO_3$) with a perovskite structure are synthesized and applied as protective coatings on a metallic interconnect (Crofer 22 APU). The partial substitution of Co, Cu, and Fe for Ni improves electrical conductivity as well as thermal expansion match with the Crofer interconnect. The protective perovskite layers are fabricated on the interconnects by a slurry coating process combined with optimized heat-treatment. The perovskite-coated interconnects show area-specific resistances as low as $16.5-37.5m{\Omega}{\cdot}cm^2$ at $800^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.52 no.5
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• pp.308-314
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• 2015

The electrochemical performance and Cr poisoning behavior of $La_{1-x}Ba_xCo_{0.9}Fe_{0.1}O_{3-{\delta}}$ (LBCF, x = 0.3, 0.4, 0.5) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF) cathodes were investigated for solid oxide fuel cells (SOFCs). The polarization resistance of the LBCF/GDC/LBCF symmetrical cell was found to decrease with increasing Ba content (x value). This phenomenon might be associated with the high oxygen vacancy concentration in the LBCF sample, with x = 0.5. In addition, there was no chromium poisoning in the LBCF cathode. On the other hand, the polarization resistance of the LSCF cathode was found to significantly increase after exposure to gaseous chromium species; it appears that this result stemmed from the formation of $SrCrO_4$ phase. Therefore, it can be expected that LBCF can be a durable potential cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFC).

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.319.1-319.1
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• 2013

Solid oxide fuel cells (SOFCs) have been recognized as one of emerging renewable energy sources, due to minimized pollutant production and high efficiency in operation. The performance of SOFCs is largely dependent on the electrode polarization which involves the oxidation/reduction in cathodes and anodes along with the charge transport of ions and electronic carriers. Atomic layer deposition is based on the alternate chemical surface reaction occurring at low temperatures with high uniformity and superior step coverage. Such features can be extended into the coating of metal oxide and/or metal layer onto the porous materials. In particular, the atomic layer deposition is can manipulated in controlling the charge transport in terms of triple phase boundaries, in order to control artificially the electrochemical polarization in electrodes of SOFC. The current work applied atomic layer deposition of metal oxides intro the electrodes of SOFCs. The corresponding effect was monitored in terms of the electrochemical characterization. The roles of atomic layer deposition in solid oxide fuel cells are discussed towards optimized towards long-term durability at intermediate temperature.

• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.101-111
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• 2021

To improve the potential of single chamber microbial fuel cells (SCMFCs) as an applicable technology, the main challenge is a practical application for larger scales bioenergy production from potent exoelectrogenic microorganism with real dairy wastewater. To increase power generation, three individual MFCs were together operated in series best under the fed batch condition for 15 days. The volume of MFC 1 and MFC 2 is "300 mL" and MFC 3 is "500 mL" respectively. The individual MFCs 1, MFC 2 and MFC 3 gives an open circuit voltage of 0.60 V, 0.66 V and 0.55 V and result in total working voltage when connected in series of 1.745V, which lead an LED to glow. The maximum power densities obtained from MFC 1, MFC 2 and MFC 3 are 62 mW/㎡, 50 mW/㎡ and 45 mW/㎡ (normalized to the surface area of the anodic electrode, which was 50 ㎠ for all three MFCs), and corresponding to current densities of 141 mA/㎡, 155 mA/㎡ and 123 mA/㎡, respectively. Therefore this work suggests the cheapest way to connect microbial fuel cells in series to gain power with the lowest operating cost and chemical oxygen demand (COD) removal.

• 한국전기화학회:학술대회논문집
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• 2003.07a
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• pp.247-252
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• 2003

• New & Renewable Energy
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• v.3 no.3
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• pp.5-13
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• 2007

Stacks of solid oxide fuel cell with 1kW max power performance were designed on planar type employing anode-supported cells and metallic interconnects. The stacks composed of 3-cells, 8-cells, and 16-cells were fabricated and tested in serials by using anode-supported cells purchased from Indec, and sealants/interconnects prepared at RIST. In the performance test of the final 16-cells stack, OCV was recorded to be 16.7V. The peak power and the power density showed 1 kW, $0.77W/cm^2$ at $820^{\circ}C$, respectively. In addition, the long-term degradation rate of the power exhibited 2.25 % during 500h at $750^{\circ}C$.

• Journal of Fisheries and Marine Sciences Education
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• v.27 no.6
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• pp.1727-1733
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• 2015

In the present study, the heat transfer performance of dimpled double-pipe heat exchangers for fuel cells that are utilized as cooling systems of fuel cells was studied. In addition, to comparatively analyze the heat transfer performance of dimpled double-pipe heat exchanger for fuel cells, plain double-pipe heat exchangers were also studied. Experimental results were derived on changes in the Reynolds numbers of the cooling water flowing in dimpled and plain double-pipe heat exchangers and changes in the heat flux of the air. Thereafter, to verify the reliability of the experimental results, the theoretical overall heat transfer coefficients and the experimental overall heat transfer coefficients were comparatively analyzed and the following results were derived. The heat transfer rate lost by the hot air and that of the heat transfer rate obtained by the cooling water were well balanced. The experiments of plain double-pipe heat exchangers and dimpled double-pipe heat exchangers were conducted under normal conditions and the theoretical overall heat transfer coefficient and the experimental overall heat transfer coefficient coincided well with each other. In both plain double-pipe heat exchangers and dimpled double-pipe heat exchangers, heat transfer rates increased as the cooling water flow velocity increased. Under the same experimental conditions, the heat transfer performance of dimpled double-pipe heat exchangers was shown to be higher by 1.2 times than that of plain double-pipe heat exchangers.

• Journal of Microbiology and Biotechnology
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• v.11 no.5
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• pp.863-869
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• 2001

A systematic study of microbial fuel cells comprised of alkalophilic Bacillus sp. B-31 has been carried out under various operating conditions. A significant amount of electricity was generated when redox mediators were used. Among the phenothiazine-type redox dyes tested, azure A was found to be the most effective both in maintaining a high cell voltage and for the long-term operation. The maximum efficiency was and for the long-term operation. The maximum efficiency was obtained at ca. $50^{\circ}C$ giving an open circuit voltage of 0.7V. A small change in temperature did not significantly affect the cell performance, but a rapid decrease in performance was observed below $20^{\circ}C$ and above $70^{\circ}C$. It was noticeable that fuel cell efficiency and discharge pattern depended strongly on the carbon source used in the initial culture medium. Regardless of the initial carbon sources, only glucose and trehalose were utilized as substrates. Galactose, however, was not substantially utilized except when galactose was used in the initial medium. Glucose, in particular, showed $87\%$ coulombic efficiency, which was the highest value ever reported, when Bacillus sp. was cultured in a maltose-containing medium. This study demonstrates that highly efficient microbial fuel cells can be constructed with alkalophilic microorganisms by fine-tuning the operating conditions and by carefully selecting carbon sources in the initial culture medium.

• Journal of Powder Materials
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• v.21 no.3
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• pp.222-228
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• 2014

Much research into fuel cells operating at a temperature below $800^{\circ}C$. is being performed. There are significant efforts to replace the yttria-stabilized zirconia electrolyte with a doped ceria electrolyte that has high ionic conductivity even at a lower temperature. Even if the doped ceria electrolyte has high ionic conductivity, it also shows high electronic conductivity in a reducing environment, therefore, when used as a solid electrolyte of a fuel cell, the powergeneration efficiency and mechanical properties of the fuel cell may be degraded. In this study, gadolinium-doped ceria nanopowder with $Al_2O_3$ and $Mn_2O_3$ as a reinforcing and electron trapping agents were synthesized by ultrasonic pyrolysis process. After firing, their microstructure and mechanical and electrical properties were investigated and compared with those of pure gadolinium-doped ceria specimen.