• Title/Summary/Keyword: Fuel Particles

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WO3 Fabrication and Thermal Spray Coating of WC-Co using Recycled Ammonium Paratungstate (APT) (재활용 APT를 이용한 WO3 제조와 WC-Co 의 용사코팅)

  • Chung, J. K.;Kim, S. J.;On, J. H.;Moon, H. S.;Pee, J. H.;Ha, T. K.;Park, S. Y.
    • Transactions of Materials Processing
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    • v.24 no.4
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    • pp.287-292
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    • 2015
  • The possibility of chemical precipitation for recycled ammonium paratungstate (APT) was studied. WO3 particles were synthesized by chemical precipitation method using a 1:2 weight ratio of APT:DI-water. At the 500℃ sintering temperature, the X-ray diffraction results showed that APT completely decomposed to WO3. For the granulated powder WC-Co, vacuum heat treatment at proper temperatures increases tap density and flow-ability. Hardness of the WC-Co thermal spray coating layer was measured in the range HV 831~1266. Spray conditions for the best characteristic values were an oxygen flow rate=1500 scfh, a fuel flow rate = 5.25gph and a gun distance = 320mm.

Measurement of soot concentration in flames using laser-induced incandescence method (이중 동축 확산화염의 형상 및 배출 특성)

  • Jurng, Jong-Soo;Lee, Gyo-Woo
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.49-57
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    • 1999
  • An experimental study on double-concentric diffusion flame has been carried out in order to investigate the shape, the flame length, and the other characteristics of the flame. Flow visualization of the flame by the $TiO_2$ particles and also the emission measurements are conducted. The commercial grade LP gases are used as fuel. The inverse diffusion flames are formed at the center when the central air flow rate is about 0.1 L/min. With a larger flow rate of the central air jet than 0.2 L/min the flame turns to be an annular-shaped flame, which is very bright. When the central air flow rate increases over 2.4 L/min, the flame turns to blue and the flame tips are opened because of the lifting of the inner part of the flame. Because of this lifting and the incomplete combustion, the CO emission increases abruptly from 25 ppm to more than 150 ppm. On the contrary, the NOx emission is decreased.

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Study on Coal Combustion Characteristics with 1MWth Test Facility (1MWth 실험연소로를 이용한 석탄의 연소특성 연구)

  • Jang, Gil Hong;Chang, In Gab;Jeong, Seok Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1464-1472
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    • 1999
  • Design and operation of $1MW_{th}$ pulverized coal combustion testing facility are described. Also the influence of air staging on NOx emission and burnout of coal flames was investigated in this facility. The test facility consisted of coal feeding system, firing system and flue gas treatment system. A top-fired externally air staging burner was adopted in order to avoid influence of gravity on the coal particles and for easy maintenance. Distribution of temperature and chemical species concentration of coal flames could be measured in vertical pass of furnace. Main fuel was pulverized (83.4% less than $80{\mu}m$) Australian high bituminous coal. From variety of test conditions, overall excess air ratio was selected at 1.2(20% excess air). Tho study showed that increasing the staged air resulted in lower NOx omission, and it was suggested to be more than 40% of the total combustion air for the substantial NOx reduction. Sufficient burnout was not achievable when NOx emission was less than 500ppm. Also, the amount of core air did not influence tho NOx reduction.

Concept Design of Hydro Reactive Solid Propellant for Underwater High Speed Ramjet Engine System (수(水)반응성 고체추진제를 이용한 수중고속램제트엔진 시스템 개념 설계)

  • Chae Jae-Ou;Sim Ju-Hyen;Kwak Yong-Whan;Koo Hyung-Joon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.121-131
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    • 2005
  • For thrust motion of high speed underwater torpedo the special hydro reactive fuels that burns in vapor water and water supply from aboard is used. The main component of this hydro reactive fuel is the powder of active metal (Mg, Al) that can burn in water vapor with large heat generation in the rocket combustion chamber. The thermodynamic analysis of combustion properties of the burning of the particles of these active metal in the vapor water have been carried out. The conception for the possible content variants of the hydro reactive fuels have been discussed using the geometrical and thermodynamic combustion conditions with the basic recommendation for contents of designed hydro reactive fuels in future.

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Manufacture Properties of the Ultrafine NiO/YSZ Solid Oxide Composite (초미분체 NiO/YSZ 고체산화물 복합재료의 제조특성)

  • 최창주;김창석;오무송;김태성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1080-1083
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    • 2001
  • Ultrafine NiO/YSZ composite powders were prepared by using a glycine nitrate process for anode material of solid oxide fuel cells. The specific surface areas of synthesized NiO/YSZ composite powders were examined with controlling pH of a precursor solution and the content of glycine. The characteristics of synthesized composite powders were examined with X-ray diffractometer, a BET method with N$_2$absorption, scanning and transmission electron microscopy. The strongly acid precursor solution increased the specific surface area of the synthesized composite powders. This is suggested to be caused by the increased binding of metal ions and glycine under a strong acid solution of pH=0.5 that lets glycine consist of mainly the amine group of NH$_3$$\^$+/. After sintering and reducing treatment of NiO/YSZ composite powders synthesized by GNP, the Ni/YSZ pellet showed ideal micro-structure very fine Ni parties of 3-5${\mu}$m were distributed uniformly and fine pores around Ni metal particles were formed, thes, leading to an increase of the triple phase boundary among gas Ni and YSZ.

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Trends of Technologies for High Performance Polymer Barriers against Radiation (고성능 방사선 고분자 차단막 기술동향)

  • Lee, Gi-Bbeum;Park, Sung-Eun;Kim, In-Woo;Jeong, Kwang-Un;Lee, Hong-Ki;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.94-101
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    • 2011
  • The conventional radiation barriers may show some disadvantages such as heavy weight and possibility of poisoning human bodies because they are composed of lead plates or resin plates containing large amounts of lead powders. Another disadvantage may be direct penetration of radiation through small pin holes. In this article, technologies of multi-layered polymer barriers against radiation, which has been extensively focused recently, will be introduced. A new concept of radiation protection as well as improving endurance with employing nano-layered inorganic particles is introduced.

Contribution of Carbon Dot Nanoparticles in Electrocatalysis: Development in Energy Conversion Process

  • Jana, Jayasmita;Ngo, Yen-Linh Thi;Chung, Jin Suk;Hur, Seung Hyun
    • Journal of Electrochemical Science and Technology
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    • v.11 no.3
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    • pp.220-237
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    • 2020
  • Modern electrochemical energy devices involve generation and reduction of fuel gases through electrochemical reactions of water splitting, alcohol oxidation, oxygen reduction, etc. Initially, these processes were executed in the presence of noble metal-based catalyst that showed low overpotential and high current density. However, its high cost, unavailability, corrosion and related toxicity limited its application. The search for alternative with high stability, durability, and efficiency led scientists towards carbon nanoparticles supported catalysts which has high surface area, good electrical conductivity, tunable morphology, low cost, ease of synthesis and stability. Carbon nanoparticles are classified into two groups based on morphology, one and zero dimensional particles. Carbon nanoparticles at zero dimension, denoted as carbon dots, are less used carbon support compared to other forms. However, recently carbon dots with improved electronic properties have become popular as catalyst as well as catalyst support. This review focused on the recent advances in electrocatalytic activities of carbon dots. The mechanisms of common electrocatalytic reactions and the role of the catalysts are also discussed. The review also proposed future developments and other research directions to overcome current limitations.

Spatio-Temporal Characteristics of PM2.5 in Gyeongnam Province during 2015-2016 (2015~2016년 경남지역의 PM2.5의 시·공간적 특성)

  • Shon, Zang-Ho
    • Journal of Environmental Science International
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    • v.26 no.9
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    • pp.1045-1055
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    • 2017
  • Characterization of spatio-temporal variations in $PM_{2.5}$ in Gyeongnam (GN) province during 2015-2016 was investigated to assess the air quality in this area in terms of fine particles. Yearly mean concentrations of $PM_{2.5}$ ranged from 19.1 to $29.5{\mu}gm^{-3}$. High concentrations of $PM_{2.5}$ were observed in spring ($21.2-30.3{\mu}gm^{-3}$) and winter ($20.2-30.3{\mu}gm^{-3}$). Low concentrations of $PM_{2.5}$ were generally observed in fall ($16.2-23.2{\mu}gm^{-3}$). $PM_{2.5}$ concentration was highest in the morning (10 AM). The fractions of $PM_{2.5}$ in $PM_{10}$ were 0.51-0.62 and two were significantly correlated (r=0.779-0.830), suggesting common sources (fossil fuel combustion, mobile sources, etc). CO was significantly correlated with $PM_{2.5}$ in highly urbanized areas such as the city of Changwon (CW, r=0.711), compared to other air pollutants ($SO_2$, $NO_2$, and $O_3$), suggesting dominance of industrial combustion sources.

Numerical Study on the Thermophoretic Deposition Characteristics of Soot Particles for Wall Temperature of Burner and Surrounding Air Temperature in Combustion Duct (버너의 벽면온도와 연소실내 주위공기온도에 따른 매연입자의 열영동 부착 특성에 관한 수치적 연구)

  • Choi, Jae-Hyuk;Han, Won-Hui;Yoon, Doo-Ho;Yoon, Seok-Hun;Chung, Suk-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.1
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    • pp.57-65
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    • 2008
  • The characteristics of soot deposition on the cold wall in laminar diffusion flames have been numerically analyzed with a two-dimension with the FDS (Fire Dynamics Simulator). In particular, the effects of surrounding air temperature and wall temperature have been discussed. The fuel for the flame is an ethylene ($C_2H_4$). The surrounding oxygen concentration is 35%. Surrounding air temperatures are 300K, 600K, 900K and 1200K. Wall temperatures are 300K, 600K and 1200K. The soot deposition length defined as the relative approach distance to the wall per a given axial distance is newly introduced as a parameter to evaluate the soot deposition tendency on the wall. The result shows that soot deposition length is increased with increasing the surrounding air temperatures and with decreasing the wall temperature. And the numerical results led to the conclusion that it is essential to consider the thermophoretic effect for understanding the soot deposition on the cold wall properly.

Alternative Breaching Methods of the TRISO Fuels

  • Lee Jong-Hyeon;Shim Joon-Bo;Ahn Byung-Gil;Kwon Sang-Woon;Kim Eung-Ho;Yoo Jae-Hyung;Park Seong-Won
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.92-106
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    • 2005
  • The head-end processes of spent TRISO fuel have been reviewed to understand the current status and the limitations of the reported processes. The main concerns in the TRISO treatment are to effectively breach and separate the carbon and SiC layers composing the TRISO particles. The crush-bum scheme which was considered in the early stages of the development has been replaced by the crush-leach or $CO_2$ burning and the succeeding CO decomposition process because of a sequestration problem of $CO_2$ containing $^{14}C$. However there are still many obstacles to overcome in the reported processes. Hence, innovative thermomechanical and pyrochemical concepts to breach the coating layers of the TRISO particle with a minimized amount of second waste are proposed in this paper and their principles are described in detail.

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