• Environmental Engineering Research
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• v.19 no.3
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• pp.205-214
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• 2014

Petroleum a vital commodity affecting every aspect of 21st century. Toxicity and adverse effects of sulphur as catalyst in petroleum products is of great concern required development of techniques for desulphurization in compliance with the International standards. Installation of desulphurizing units costs over $200 million per unit placing economic burden on developing countries like Pakistan. Present study analysis of commercial fuels (station petrol and jet fuel JP8) on gas chromatography-mass spectrometry (GC-MS) identified sulphur concentration of 19.94 mg/L and 21.75 mg/L, respectively. This scenario urged the researcher to attempt synthesis of material that is likely to offer good adsorption capacity for sulphur. Following protocol of sol-gel method, transition metals (Ni, Cu, Zn) solution is gelated with tetraethoxysilane (TEOS; silica precursor) using glycerol. Fourier transform infrared spectroscopy (FTIR) spectra revealed bonding of Zn-O, Cu-O, and Ni-O by stretching vibrations at $468cm^{-1}$, $617cm^{-1}$, and $468cm^{-1}$, respectively. Thiophene and Benzothiophene mixed in n-heptane and benzene (4:1) for preparation of Model Fuels I and II, respectively. Each of silica based metal was applied as adsorbent in batch mode to assess the removal efficiency. Results demonstrated optimal desulphurization of more than 90% following efficacy order as Si-Ni > Si-Zn > Si-Cu based adsorbents. Proposed multilayered (Freundlich) adsorption mechanism follows ${\pi}$-complexation with pseudo secnd order kinetics.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.2
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• pp.108-114
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• 2018

In this study, the thermal and rheological characteristics of a 10 wt.% addition of aluminum particles and the effect of the particle size were investigated to qualitatively analyze the paraffin fuel entrainment regression rate. The results revealed that the addition of aluminum particles and their relative particle size affected the rheological characteristics, rather than the thermal characteristics. Moreover, it was found that the variation of thermal properties had a minor effect on the entrainment regression rate, in comparison to the variation in rheological properties.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.7
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• pp.476-482
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• 2014

In this study, the characteristics of emulsified fuel and engine emissions were studied with engine dynamometer. Microexplosion took place in the combustion chamber. While combustion, emulsion fuel scattered to micro particles and it caused to smoke reduction. The heat produced from water vapour reduce the temperature of internal combustion chamber and it caused to inhibition of NOx production. It can be verified by the lower exhaust temperature of each ND-13 mode using emulsion fuel than that of MDO fuel. The NOx and smoke concentration were reduced by increasing water content in emulsion fuel. The power also decreased according to the increment of water content of emulsion fuel because emulsion fuel has low calorific value due to high water content than MDO. As a result of ND-13 mode test with 17% moisture content, it was achieved 24% reduction in NOx production, 76% reduction in smoke density, 11% reduction of $SO_2$ and 13% reduction in power loss.

• 한국연소학회:학술대회논문집
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• 1997.06a
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• pp.61-68
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• 1997

The morphology and size distribution of chromium oxides and the concentration measurement of atomic arsenic have been studied in laminar diffusion flames. Nitrogen was added to vary flame temperatures in hydrogen flames. Ethene flames were used in order to investigate the potential for interaction between the soot aerosol that is formed in these flames and the chromium aerosol. Two sources of chromium compounds were introduced: chromium nitrate and chromium hexacarbonyl. A detailed investigation of the morphology was carried out by scanning electron microscopy (SEM). The amounts of Cr(VI) and total Cr were determined by a spectrophotometric method and by X-ray fluorescence spectrometry, respectively. Also, LIF was used for the measurement of atomic arsenic, which was excited at 197.2 nm and was detected at 249.6 nm. Results showed that the morphology of the particles varied with the flame temperature and with the chromium source. The particles were characterized by porous structures, cenospheres and agglomerated dense particles when chromium nitrate solution was added to the flames. At low to moderate temperatures, porous sintered cenospheric structures were formed, in some cases with a blow hole. At higher temperatures, an agglomerated cluster which was composed of loosely sintered submicron particles was observed. It was also found that the emission of Cr(VI) from the undiluted $H_2$ flame was more than 10 times larger than in the 50% $H_2$ / 50% $N_2$ flame on a mass basis. Single point LIF measurement of atomic arsenic indicated that arsenic exist only in the low temperature, fuel rich region.

• Journal of Environmental Health Sciences
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• v.38 no.5
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• pp.393-397
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• 2012

Objectives: The objectives of this study were to measure passengers' exposure to ultrafine particles (UFP) and to determine effects of fuel, operating condition and position of seat. Method: UFP exposures in front and back seats of the Elephant vehicle in Seoul Grand Park were simultaneously measured by a condensation particle counter (P-Trak model 8525, TSI). The measurements were conducted 7 times with diesel-powered vehicle and 3 times with electricity vehicle in one day. The vehicle stopped at 3 locations along with 2.2 km of driving route. Results: UFP concentration in diesel-powered vehicle was significantly higher than electricity vehicle. At front seat of diesel-powered vehicle, average UFP exposure during stopping was significantly higher than during moving. When diesel-powered vehicle moved, UFP exposure in back seat was significantly higher than in front seat. Conclusions: Passengers in the diesel-powered Elephant vehicle could be exposed to high level of UFP. The UFP exposure was associated with operation condition and position of seat.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.568-571
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• 2008

A novel self-humidifying composite membrane for the proton exchange membrane fuel cell (PEMFC) at low humidity condition was developed. The Pt/$TiO_2$ catalyst particles were synthesized via supercritical impregnation methods. Pt precursor was dissolved in supercritical carbon dioxide and impregnated onto $TiO_2$ particles. Pt precursors were platinum(II) acetylacetonate, Dimethyl(1,5-cyclooctadiene) platinum(II) and we controlled the ratio of Pt to $TiO_2$. The impregnated Pt precursor was converted to $TiO_2$ supported Pt nanoparticle under various reducing conditions. Pt/$TiO_2$ catalyst particles were dispersed uniformly into the Nafion solution, and then Pt/$TiO_2$/Nafion composite membrane was prepared using solution-cast method. The self-humidifying composite membrane could minimize membrane conductivity loss under dry conditions due to the presence of catalyst and hydrophilic Pt/$TiO_2$ particles. To optimize the performance of MEA, amount of ionomer loading was controlled. And mixed catalysts were used. The cell performance of MEA was obviously improved under dry conditions at $65^{\circ}C$.

• Particle and aerosol research
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• v.4 no.2
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• pp.51-67
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• 2008

In this study, we devoted to kinetic measurement of the catalytic oxidation of iron-containing flame soot particles and better understanding the role of catalytic particles on carbon oxidation in particular at low temperature, targeting on autothermal regeneration of diesel particulate filter by diesel exhaust gas. Carbon-based Fe-containing particles generated by spraying ferrocene-doped diesel fuel in an oxy-hydrogen flame are tested and compared with a commercial carbon black powder for thermogravimetric analysis (TGA), secondary ion mass spectrometry (SIMS), Fourier-transform infrared spectroscopy (FTIR), Induced coupled plasma-Atomic emission spectroscopy (ICP-AES), and High-resolution transmission electron microscopy (HR-TEM). As a result, we found that a small amount of the ferrocene addition led to significant reductions in a on-set temperature and an activation energy of the carbon oxidation as well. An oxygenated surface complex forming at the particle surface could be thought as active species that would be readily consumed in particular at low temperature.

• Atmosphere
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• v.28 no.3
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• pp.337-355
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• 2018

Ultrafine particles (< 100 nm in diameter, UFP) are known to be more toxic per unit mass than larger particles and contribute to more than 90% in particle number concentrations in urbanized cities but much less in mass. The major sources of UFP are vehicle emissions in urban areas. Due to their tiny size (the sizes of UFP from vehicle emissions range from 10 to 60 nm depending on engine and fuel types), inhaled UFP can reach the deepest area of respiratory track (e.g., pulmonary alveoli) as well as all of the body via lymph and blood circulation causing various adverse health effects. This article reviews the sources and emission factors of UFP, temporal and spatial distributions in urban areas and their health effects reported by toxicological and epidemiological studies. We also compared the levels of UFP concentrations measured in other countries with those in Korean cities to evaluate the public exposure to UFP in Korea. Ultimately, we expect this study can contribute to developing the risk assessment techniques for public exposure to UFP in the urbanized cities in Korea.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.5
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• pp.1211-1221
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• 1990

The purpose of this study is to get experimental data on the distribution of CWM (Coal- Water Mixture) droplets size and the presence of pulverized coal particles inside CWM droplets. Atomization of CWM is done by Twin-Fluid Atomizer. The operational parameters are atomizing air pressure, coal particle loading, mean size of pulverized coal particles and sampling positions across spray. Th data analysis is initiated by Impression Sampling Method(Magnesium Oxide Technique) and Photo-technique and counting works are followed. Experimental work induces following research results. The variation of particle loadings in slurry makes no appreciable effects on the mean size of CWM droplets. It is evident that atomizing air pressure has very strong effect on the atomization of slurry. The mean size of atomized fuel droplets is dramatically reduced with the increasing air pressure. The population ratio of droplets without coal particles to total number of droplets is decreased as atomizing air pressure or loading rises and the same trend is obtained as the mean size of coal particles becomes smaller but a certain tendency of coal particle presence inside droplets could not be found from the change of sampling positions.

• Journal of the Korean Society of Combustion
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• v.19 no.3
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• pp.18-25
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• 2014

Bottom ash from a coal-fired power plant is usually landfilled to a nearby site, which causes a growing environmental concern and increased operating costs. One way of recycling the bottom ash is to produce light-weight aggregate (LWA) using a rotary kiln. This study investigated the temperature profiles of raw LWA particles in a rotary kiln to identify the range of operating conditions appropriate for ideal bloating. For this purpose, a new simulation method was developed to integrate a 1-dimensional model for the bed of LWA particles and the computational fluid dynamics (CFD) for the fuel combustion and gas flow. The temperature of LWA particles was found very sensitive to the changes in the air preheating temperature and excess air ratio. Therefore, an accurate control of the operation parameters was essential to achieve the bloating of LWA particles without excessive sintering or melting.