• Journal of Hydrogen and New Energy
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• v.26 no.3
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• pp.227-233
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• 2015

In this study, we evaluate catalytic activity of Pd/C catalyst that is synthesized by modified polyol method. With such formed Pd/C is used as anodic catalyst for direct formic acid fuel cell (DFAFC) and performances of the DFAFC are measured to verify whether the new catalyst is effective for enhancing DFAFC performance and to determine optimal loadings of the Pd/C needed for obtaining best DFAFC performance. Pd particle distribution of the Pd/C catalyst is analyzed by TEM, while its catalytic activity is estimated by using cyclic voltammogram (CV) as measuring formic acid oxidation reaction and active surface area. As a result of that, the Pd/C catalyst synthesized by modified polyol shows better catalytic activity and DFAFC performance with small loading amount of Pd/C. When loading amount of Pd/C is $1.5mgcm^{-2}$, maximum power density of DFAFC adopting the catalyst is $122mWcm^{-2}$.

• Nuclear Engineering and Technology
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• v.54 no.9
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• pp.3272-3282
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• 2022

To improve the safety and life extension qualities of nuclear fuel rods which is currently made of zirconium (Zr) alloy, research on the application of chromium (Cr) coating was conducted. Cr coating has advantages such as increased corrosion resistance and reduced oxidation rate, but non-destructive thickness evaluation studies are needed to ensure the reliability of the steps taken to provide uniform coating thickness. Eddy current testing (ECT) is a representative non-destructive technique for such as thickness evaluation and surface defect inspection. To inspect changes in thickness at micron scale, the Swept Frequency Eddy Current Testing (SFECT) method was applied to select a frequency range sensitive to changes in thickness. The coating thickness was evaluated using changes in signals, such as that for impedance. In this study, basic research was performed to evaluate the thickness of the Cr coating on a rod using an encircling sensor and the SFECT technique. The sensor design parameters were determined through simulation, after which the new sensor was manufactured. A sensor capable of measuring the thickness of a non-uniformly Cr-coating rod was selected through an experiment evaluating the performance of the manufactured sensor. This was done using the impedance-difference of a Cr-coating rod and a Zr alloy rod. The possibility of evaluation of the Cr coating thickness was confirmed by comparing the experimental results with the selected sensor and the signals of the measured Cr-coating rod. All simulation results were verified experimentally.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.3
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• pp.233-239
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• 2014

The accurate engine output is basically one of important factors for the analysis of engine performance. Nowadays in-cylinder pressure analyzer in internal combustion engine is also an indispensable tool for engine research and development, environment regulation and maintenance of engine. The combustion analysis is desperately needed in order to induce a correct judgment on the condition of the engine and suggest the specific ways to improvement as well as the correct engine output. And these tool is advantageous to reduce fuel consumption and maintenance of the engine. In this study, using the developed measuring kit, combustion analysis of marine generator engine which was adapted as test engine was carried out. It was verified that the good operation condition of the engine as well as contributing to fuel savings by checking and readjusting accurately the irregular combustion of the test engine were accomplished. From the results all above, it was recognized that the measuring kit by new method for engine output was developed and verified for its utilities.

• Korean Chemical Engineering Research
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• v.59 no.1
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• pp.1-5
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• 2021

The PEM(Proton Exchange Membrane)water electrolysis uses the same PEM electrolyte membrane as the PEM fuel cell and proceeds by the same reaction but the opposite direction. The PEM fuel cell has many methods of degradation analysis since many studies have been conducted on the degradation and durability of the membrane and catalyst. We examined whether PEM fuel cell durability evaluation method can be applied to PEM electrolytic durability evaluation. During the PEM electrolytic degradation process, LSV(Linear sweep voltammetry), CV(Cyclic voltammetry), Impedance, SEM(Scanning Electron Microscope) and FT-IR(Fourier Transform Infrared spectroscopy) were analyzed and compared under the same conditions as the PEM fuel cell. As the PEM fuel cell, hydrogen passing through the membrane was oxidized at the Pt/C electrode, and the hydrogen permeation current density was measured to analyze the degree of degradation of the PEM membrane. Electrode degradation could be analyzed by measuring the electrode active area (ECSA) by CV under hydrogen/nitrogen flowing conditions. While supplying hydrogen and air to the Pt/C electrode and the IrO2 electrode, the impedance of each electrode was measured to evaluate the durability of the electrode and membrane.

• Nuclear Engineering and Technology
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• v.52 no.12
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• pp.2847-2851
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• 2020

A simple water level measurement method based on wavelength division multiplexing (WDM) is proposed and demonstrated. The measurement principle is based on the change of Fresnel reflection occurring at the end facet of the optical fiber tip (OFT). To increase the spatial resolution of water level sensing, a broadband light source (BLS) and an arrayed waveguide grating (AWG) are employed. The OFTs are multiplexed with the dedicated wavelength channels of AWG. By measuring all of the reflection powers reflected at the OFTs with a proposed on-site reflectometer, the water level can be monitored continuously for a fast emergency response. Moreover, it can be implemented easily with the commercially available optical components and devices with the simple configuration.

• Applied Chemistry for Engineering
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• v.28 no.3
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• pp.345-350
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• 2017

The sintered density of uranium oxide pellets for pressurized water reactors is generally analyzed with pellet's samples completed with the sintering process. In this paper, the sintered density was analyzed by the newly developed method measuring the chromatography of ammonium diuranate, a precursor of uranium oxide, by a spectrophotometer (CM-5, Konica Minolta) before completing the sintering process. As a result of the sintered density analysis based on the brightness, color coordinate values (L, a, b) obtained from five ammonium diuranate samples by a spectrophotometer and the trend line of sintered density analyzed by a previous method, the sintered density with respect to the L value was observed with 0.9967 of the decision factor $R^2$. In case of a value, $R^2$ value was 0.9534 indicating lower reliability than that of the L value. However, b value with $R^2$ value of 0.4349 showed a very low correlation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.4
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• pp.1675-1682
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• 2013

To resolve the Global Warming problem, it have to reduce $CO_2$ emission. Korea need to do actively more the effort to reduce the emission because $CO_2$ emission per person is top level in the world. It is performing variously. However, we should recognize the $CO_2$ emission attribute to decrease $CO_2$. Analyzing $CO_2$ emission of the construction equipment is important in this aspect. Present, the most popular $CO_2$ emission measuring method is the way using fuel consumption and emission factor. But this method have the problem of reliability because can't reflect the factor being out of proportion at fuel consumption. This study analyzed the reason of difference and compared to the emission factor method after calculate $CO_2$ emission in direct measurement method.

• Journal of the Korean Electrochemical Society
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• v.25 no.2
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• pp.88-94
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• 2022

The anion exchange membrane used in alkaline membrane fuel cells transports hydroxide ions, and ion conductivity affects fuel cell performance. Thus, the measurement of absolute hydroxide ion conductivity is essential. However, it is challenging to accurately measure hydroxide ion conductivity since hydroxide ions are easily poisoned in the form of bicarbonate by carbon dioxide in the atmosphere. In this study, we applied electrochemical ion exchange treatment to measure the absolute hydroxide ion conductivity of the anion exchange membrane. In addition, we investigated the effect of carbon dioxide poisoning of hydroxide ions on electrochemical performance by measuring bicarbonate conductivity. Commercial anion exchange membranes (FAA-3-50 and Orion TM1) and polyphenylene-based block copolymer (QPP-6F) were used.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.2
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• pp.100-106
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• 1998

The wide open throttle performance and piston temperatures were measured by the change of fuel : gasoline and liquefied petroleum gas(LPG). Bench test method was developed and experimented to study the effect of temperature on the formation of carbon deposit. The bench test results were confirmed by measuring the piston temperature and observing the deposit production rate at an actual engine running condition. Results show that if the fuel of spark ignition engine is changed from gasoline to LPG, the output power decreases about 10% and the piston temperatures increase about 40~55$^{\circ}C$. In actual engine tests, because of this temperature increase, it was observed that the quantity of carbon deposit in the top ring groove increased in a big degree. Consuquently, it is known that the fing sticking may occur if the gasoline engine was rebuilt to LPG fuelled engine. Therefore, in order to preserve the durability of LPG fuelled engine, it is necessary to lower the piston temperature by hardware modificationor to reduce the carbon deposit by the improvement of engine oil.

• Nuclear Engineering and Technology
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• v.52 no.1
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• pp.14-18
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• 2020

Korea Atomic Energy Research Institute (KAERI) has carried out various neutronics experiments in the commissioning stage of the Jordan Research and Training Reactor (JRTR), and this paper introduces the results of first criticality prediction and experiment for the JRTR. The Monte Carlo Code for Advanced Reactor Design and analysis (McCARD) with the ENDF/B-VII.0 nuclear library was used for prediction calculations in the process of the first criticality approach, which was performed to provide reference for the first criticality experiment. In the experiment, fuel loading was carried out by measuring the inverse multiplication factor (1/M) to predict the number of fuel assemblies at the first criticality, and the first critical was reached on April 25, 2016. Comparing the first criticality prediction and experiment, the calculated and measured CAR (Control Absorber Rod) heights for the first criticality were 575 mm and 570.5 mm, respectively, that is, the difference between the two results was approximately 5 mm. From this result, it was confirmed that JRTR manufacturing and various experiments had successfully progressed as designed.