• Journal of the Korean Society of Mechanical Technology
• /
• v.13 no.2
• /
• pp.123-128
• /
• 2011

It has been stand high in estimation to converse from Carbon dioxide to Dimethyl Ether in new alternative fuel energy division in 21C, especially Using of DME in point of view of transportation fuel has been discussed of a new clean energy which is very lower of exhaust gas than gasoline and diesel energy. In this paper it is used ZSM-5 and I developed new catalyst by addition of cerium to control acidity. The new catalyst was proved high conversion rate, when it was conversed from methanol to DME, there wasn't any additional material except DME and water, and I overlooked reaction temperature, reaction time, amount of catalyst, amount of added cerium, effect of water content in methanol, reaction temperature by making change of reaction time. I have conclude that conversion rate to DME was increased as increased of catalyst amounts. The best catalyst condition of without additional product was treated poisoning from ZSM-5 to 5% cerium and new catalyst was not effected in purity of fuel methanol.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.4 no.3
• /
• pp.102-111
• /
• 1996

For the air-fuel ratio control in a fuel injection SI engine, the Jump-Ramp control algorithm has been widely adopted by using the on/off type oxygen sensor. But the Jump-Ramp control method has limitation on treating the frequency and amplitude of the air-fuel ratio oscillation. This study suggests another feedback control logic named modulated fuel feedback control, which has a concept of pre-tuned air-fuel ratio oscillation. In the modulation method, the oxygen sensor output is not treated as on/off signal but as analog signal for feedback. By using the modulation method, the frequency and the amplitude of air-fuel ratio oscillation can be adjustable to some extent for improving the conversion efficiency of the Three-Way Catalyst. The result shows that the performance of the modulation method is better than that Jump-Ramp control method in reducing the amplitude of the air-fuel ratio oscillation as well as in increasing the frequency of the air-fuel ratio oscillation.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.33 no.9
• /
• pp.709-717
• /
• 2009

Heat transfer rate is a very important factor for the performance of a steam reformer because a steam reforming reaction is an endothermic reaction. Coaxial cylindrical reactor is the reactor design which can improve the heat transfer rate. Temperature, fuel conversion and heat flux in the coaxial cylindrical steam reformer are studied in this paper using numerical method under various operating conditions. Langmuir-Hinshelwood model and pseudo-homogeneous model are incorporated for the catalytic surface reaction. Dominant chemical reactions are assumed as a Steam Reforming (SR) reaction, a Water-Gas Shift (WGS) reaction, and a Direct Steam Reforming (DSR) reaction. Although coaxial cylindrical steam reformer uses 33% less amount of catalyst than cylindrical steam reformer, its fuel conversion is increased 10 % more and its temperature is also high as about 30 degree. There is no heat transfer limitation near the inlet area at coaxial-type reactor. However, pressure drop of the coaxial cylindrical reactor is 10 times higher than that of cylindrical reactor. Operating parameters of coaxial cylindrical steam reformer are the wall temperature, the inlet temperature, and the Gas Hourly Space Velocity (GHSV). When the wall temperature is high, the temperature and the fuel conversion are increased due to the high heat transfer rate. The fuel conversion rate is increased with the high inlet temperature. However, temperature drop clearly occurs near the inlet area since an endothermic reaction is active due to the high inlet temperature. When GHSV is increased, the fuel conversion is decreased because of the heat transfer limitation and short residence time.

• Journal of Advanced Marine Engineering and Technology
• /
• v.28 no.3
• /
• pp.516-521
• /
• 2004

In this paper, the effects of ethanol blended gasoline on emissions and their catalytic conversion efficiencies characteristics were investigated in gasoline engine with an electronic fuel injection. The results showed that the increase of ethanol concentration in the blended fuels brought the reduction of THC and $CO_2$ emissions from the gasoline engine. THC emissions were drastically reduced up to thirty percent. And brake specific fuel consumption was increased. but brake specific energy consumption was similar level. However. unburned ethanol and acetaldehyde emissions increased. The conversion efficiency of Pt/Rh based three-way catalysts and the effect of ethanol on CO and NOx emissions were investigated by the change of engine speed. load and air/fuel ratio. Furthermore, the ethanol blended fuel results in the reduction effect of THC. CO and NOx emissions at idle speed.

• Proceedings of the KSR Conference
• /
• 2008.06a
• /
• pp.1984-1989
• /
• 2008

A powered system with fuel cell is regarded as a high current and low voltage source. Effects of the loads on the electrical power source are important to optimize the integrated power system. The design parameters of the system should be chosen by taking into account the characteristics of the fuel cell, so the costs of the power system at given operating conditions can be reduced. Furthermore, the dynamics characteristic of the system is crucial to acquire performance in applications, particularly interactions between loads and the fuel cell system. Currently, no integrated simulation has been approached to analyze interrelated effects. Therefore, the dynamic models of power conversion system with a PEM fuel cell that includes the PEM fuel cell stack, DC/DC converter and associated controls is developed. Electric lads for the system are derived by using a power theory that separates a load current into active, reactive, distortion or a mixed current component. Dependency of the DC capacitor on the loads are analyzed.

• 한국전산유체공학회:학술대회논문집
• /
• 2011.05a
• /
• pp.112-116
• /
• 2011

In this paper, a preconverter of MCFC for an emergence electric power supplier is numerically simulated to increase the hydrogen production from natural gas (methane). Commercial code is used to simulated the porous catalyst with user subroutine to model three dominant chemical reactions which are Stream Reforming(SR), Water-Gas Shift(WGS), and Direct Stram Reforming(DSR). To get 10% fuel conversion rate in preconverter. the required external heat flux is supplied from outer wall of preconverter. The calculated results show that very nonuniform temperature distribution and chemical reaction happen near the wall of preconverter. These phenomena can be explained by the low heat conductivity of porous catalyst and the endothermic reforming reaction.

• Proceedings of the Korea Crystallographic Association Conference
• /
• 2003.11a
• /
• pp.7-7
• /
• 2003

• Transactions of the Korean Society of Automotive Engineers
• /
• v.23 no.2
• /
• pp.169-177
• /
• 2015

In this study we investigated the regeneration methods for the lean $NO_x$ trap (LNT) catalyst in a 2.2L direct injection diesel engine. The regeneration methods were 1) in-cylinder post fuel injection and 2) external fuel injection strategy. The in-cylinder post fuel injection method uses in-cylinder injectors with the addition of the post fuel injection to supply enough reductants such as CO, $H_2$, THC. The external fuel injection method was enabled by installing a fuel injector with a wide spray angle before the LNT catalyst. Through the engine experiment, the $NO_x$ conversion efficiency, the amount of reductant exhaust gases, fuel consumption, and temperature behavior in the LNT catalyst were evaluated and compared for the two regeneration methods.

• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2015-2020
• /
• 2007

Diesel is an excellent candidate fuel for fuel cell applications due to its high hydrogen density and well-established infrastructure. But, it is hard to guarantee desirable performance of diesel reformer because diesel reforming has several problems such as sulfur poisoning of catalyst and carbon deposition. We have been focusing on diesel autothermal reforming(ATR) for substantial period. It is reported that ATR of diesel has several technical advantages such as relatively high efficiency and fuel conversion compared to steam reforming(SR) and partial oxidation(POX). In this paper, we investigate characteristics of diesel reforming under various ratios of reactants(oxygen to carbon ratio, steam to carbon ratio) for improvement of reforming performances(high reforming efficiency, high fuel conversion, low carbon deposition). We also exhibit calculated heat balance of autothermal reformer at each condition to help thermal management of SOFC system.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.23 no.4
• /
• pp.444-453
• /
• 2015

In the previous study, several problems were observed in a NG conversion vehicle, which were fail of air-fuel ratio closed loop control, aggravated fuel economy, increased harmful emission and declined roadability. It was provisionally supposed that the mismatch of injection system with the engine caused these performance deterioration. In this context, the characteristics of fuel injection system of commercial conversion kit for NG were investigated experimentally varying the engine speed, fuel rail pressure and volume. The results are as follows; The injection quantity decreases as the engine speed increases due to the extremely small rail volume of the presenting system and flow rate of No. 2 injector are always lower than that of the other ones regardless of the speed under the dynamic operation condition. Furthermore the existing system does not meet the required fuel quantity for the normal engine operation over 3000 RPM. On the other hands, the large rail volume systems ease and/or eliminate the difference of injection quantity between the injectors according to the speed variation, however, these systems decrease injection flow rate and still cannot supply sufficient fuel. Finally, suitable combination of the higher rail pressure and the larger rail volume might be a solution about these problems.