• Title/Summary/Keyword: Fuel Composition

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A DNS Study of Ignition Characteristics of Lean PRF/Air Mixtures under HCCI Conditions (HCCI 조건에 일어나는 희박 PRF/공기 혼합물의 점화특성에 관한 직접수치모사 연구)

  • Luong, Minh Bau;Yoo, Chun Sang
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.153-156
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    • 2012
  • Direct numerical simulations (DNSs) of ignition of lean primary reference fuel (PRF)/air mixtures under homogeneous charge compression ignition (HCCI) conditions are performed using 116-species reduced chemistry. The influence of variations in the initial temperature field, imposed by changing the variance of temperature, and the fuel composition on ignition of lean PRF/air mixtures is studied using the displacement speed analysis.

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Estimation of the chemical compositions and corresponding microstructures of AgInCd absorber under irradiation condition

  • Chen, Hongsheng;Long, Chongsheng;Xiao, Hongxing;Wei, Tianguo;Le, Guan
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.344-351
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    • 2020
  • AgInCd alloy is widely used as neutron absorber in nuclear reactors. However, the AgInCd control rods may fail during service due to the irradiation swelling. In the present study, a calculational method is proposed to calculate the composition change of the AgInCd absorber. Calculated results show that neutron fluence has significant impact on the chemical compositions. Ag and In contents gradually decrease while Cd and Sn conversely increases from the center to the rim of AgInCd absorber due to the depression of neutron flux. The composition change at the surface is higher almost two times than that at the center. Based on the calculated compositions, six simulated AgInCdSn alloys were prepared and examined. With the increase of Cd and Sn, the simulated AgInCdSn alloys transform from a single fcc phase into the mixed fcc and hcp phases, and finally into the single hcp phase. The atomic volume of the hcp phase is obviously larger than the fcc phase. The fcc-hcp transformation results in considerable volume swelling of the AgInCd absorber. Moreover, the lattice parameters of the fcc and hcp phases gradually increase with Cd and Sn contents, which also can induce small volume swelling.

A Review of Strategies to Improve the Stability of Carbon-supported PtNi Octahedral for Cathode Electrocatalysts in Polymer Electrolyte Membrane Fuel Cells

  • In Gyeom Kim;Sung Jong Yoo;Jin Young Kim;Hyun S. Park;So Young Lee;Bora Seo;Kwan-Young Lee;Jong Hyun Jang;Hee-Young Park
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.96-110
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    • 2024
  • Polymer electrolyte membrane fuel cells (PEMFCs) are green energy conversion devices, for which commercial markets have been established, owing to their application in fuel cell vehicles (FCVs). Development of cathode electrocatalysts, replacing commercial Pt/C, plays a crucial role in factors such as cost reduction, high performance, and durability in FCVs. PtNi octahedral catalysts are promising for oxygen reduction reactions owing to their significantly higher mass activity (10-15 times) than that of Pt/C; however, their application in membrane electrode assemblies (MEAs) is challenged by their low stability. To overcome this durability issue, various approaches, such as third-metal doping, composition control, halide treatment, formation of a Pt layer, annealing treatment, and size control, have been explored and have shown promising improvements in stability in rotating disk electrode (RDE) testing. In this review, we aimed to compare the features of each strategy in terms of enhancing stability by introducing a stability improvement factor for a direct and reasonable comparison. The limitations of each strategy for enhancing stability of PtNi octahedral are also described. This review can serve as a valuable guide for the development of strategies to enhance the durability of octahedral PtNi.

Dynamic Simulation of Molten Carbonate Fuel Cell and Mechanical Balance of Plant (용융탄산염연료전지 및 주변기기의 동적시뮬레이션)

  • Sung, Taehong;Kim, Kyung Chun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.2
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    • pp.121-128
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    • 2014
  • This study aims to develop a simulation bed for the mechanical balance of plants of high temperature fuel cells such as molten carbonate fuel cells. For using fuel cells in transportation, the optimization of the balance of plants should be considered. In this study, the dynamic model of a molten carbonate fuel cell and the model's responses to inlet gas composition, pressure, flow rate, and stack temperature were analyzed. On/off simulation was performed for testing the dynamic model's feasibility. The simulation results are in reasonable agreement with the experimental results from published literatures.

Study on Feasibility Biomethane as a Transport Fuel in Korea (국내 바이오메탄의 차량 연료화 타당성 연구)

  • Kim, Jae-Kon;Lee, Donmin;Park, Chunkyu;Lim, Eui Soon;Jung, Choong-Sub;Kim, Ki-Dong;Oh, Youngsam
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.174.1-174.1
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    • 2011
  • Biogas production and utilisation is an emerging alternative energy technology. Biogas is produced from the biological breakdown of organic matter through anaerobic digestion. Biogas can be utilized for various energy services such as heating, electricity generation and vehicle fuel. Especially, to be utilized as vehicle fuel, raw biogas needs to be upgraded, that is, mainly the removal of carbon dioxide to increase the methane content, up to more than 95% in some cases, similar to the composition of fossil-based natural gas. Biogas fuelled vehicles can reduce $CO_2$ emission by between 75% and 200% compared with fossil fuels. Biomethane development is largely driven by national initiative and predominately by concerns for national air pollution and waste management. Recently, biogas projects for vehicle fuels by some companies are ongoing and Korea government also announced investment to develop biogas as a transport fuel. Therefore, the aim of this study is to examine the feasibility of biomethane as a transport fuel in Korea. In this study, we investigated quality characteristics, quality standard and upgrading technology to use vehicle fuel of transport sector in Korea.

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Determination of Plutonium Present in Highly Radioactive Irradiated Fuel Solution by Spectrophotometric Method

  • Dhamodharan, Krishnan;Pius, Anitha
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.727-732
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    • 2016
  • A simple and rapid spectrophotometric method has been developed to enable the determination of plutonium concentration in an irradiated fuel solution in the presence of all fission products. An excess of ceric ammonium nitrate solution was employed to oxidize all the valence states of plutonium to +6 oxidation state. Interference due to the presence of fission products such as ruthenium and zirconium, and corrosion products such as iron in the envisaged concentration range, as in the irradiated fuel solution, was studied in the determination of plutonium concentration by the direct spectrophotometric method. The stability of plutonium in +6 oxidation state was monitored under experimental conditions as a function of time. Results obtained are reproducible, and this method is applicable to radioactive samples resulting before the solvent extraction process during the reprocessing of fast reactor spent fuel. An analysis of the concentration of plutonium shows a relative standard deviation of <1.2% in standard as well as in simulated conditions. This reflects the fast reactor fuel composition with respect to uranium, plutonium, fission products such as ruthenium and zirconium, and corrosion products such as iron.

The Study of Flow Rate Performance and Engine Application with LPG Composition Rate for LPi Fuel Supplying System Consisted of Turbine Type Pump (터빈방식 연료펌프로 구성된 LPi 연료공급 시스템의 LPG 조성비에 따른 토출성능 및 엔진적용성에 관한 연구)

  • Lim, Mu-Chang;Myung, Cha-Lee;Park, Sim-Soo;Park, Jeong-Nam;Kim, Sung-Kun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.99-105
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    • 2007
  • Currently, BLDC fuel pump was applied on LPi vehicle using 3rd fuel supply system as liquified phase LPG injection method had already shown better performance than others. Its cost, however, is rather expensive because of drawbacks such as complicated structure, a fault of localization of system. In this work, demonstration system for a developed turbine type fuel pump to replace BLDC system was setup and investigated. This study results that fuel mass flow rate of turbine type pump and injection performance of injector were better compared to BLDC type. Comparing flow rate of summer LPG with that of winter LPG, the flow rate decreased about 25% using winter LPG. Performance applying turbine type LPi fuel pump to engine is confirmed.

A Study on the Heat Rejection to Coolant in a Gasoline Engine (가솔린 엔진에서의 냉각수로의 전열량에 대한 연구)

  • 류택용;신승용;이은현;최재권
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.6
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    • pp.77-88
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    • 1997
  • The heat rejection to coolant is a dominant factor for building vehicle cooling system such as radiator and cooling fan. Since the vehicle cooling system also has effects on fuel consumption and noise, the study of heat rejection to coolant has been emphasized. However, the study on heat rejection to coolant has been mainly focused on the field that related to the characteristics of combustion and localized heat loss. It is no much of use in design for the entire cooling system because it is focused on such a specific point. In this work, the heat rejection rate to coolant for four different engines are obtained to derive a simple heat transfer empirical formula that can be applied to the engine cooling system design, and it is compared with the other studies. Also, to observe effects of engine operation factors and heat transfer factors on coolant, we measured the metal temperature and the heat rejection rate. The heat rejection to coolant does not depend significantly upon the coolant flowrate, but mainly upon the amount of air fuel mixture and the air fuel ratio as long as the composition of coolant does not change. The reduction of heat rejection to coolant did not effectively improve the fuel consumption, but was mostly converted to raise the exhaust gas temperature and the oil temperature.

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An analysis of the Wi-Ni Carbide Alloy Diffusion Bonding technique in its application for DME Engine Fuel Pump

  • Chun, Dong-Joon
    • International Journal of Advanced Culture Technology
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    • v.8 no.2
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    • pp.246-251
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    • 2020
  • Dimethyl Ether(DME) engine use a highly efficient alternative fuel having a great quantity of oxygen and has a advantage no polluting PM gas. The existing DME fuel cam material is a highly expensive carbide alloy, and it is difficult to take a price advantage. Therefore the study of replacing body area with inexpensive steel material excluding piston shoe and contact area which demands high characteristics is needed. The development of WC-Ni base carbide alloy optimal bonding composition technique was accomplished in this study. To check out the influence of bonding temperature and time, bonding characteristics of sintering temperature was experimented. The hardness of specimen and bonding rate were measured using ultrasound equipment. The bonding state of each condition was excellent, and the thickness of mid-layer, temperature and maintaining time were measured. The mid-layer thickness according to bonding temperature and maintaining time were observed with optical microscope. We analyzed the micro-structural analysis, formation of bonding specimen, wafer fabrication and fuel cam abrasion test. Throughout this study, we confirmed that the fuel cam for DME engine which demands high durability against velocity and pressure is excellent.

ANALYSIS OF HIGH BURNUP PRESSURIZED WATER REACTOR FUEL USING URANIUM, PLUTONIUM, NEODYMIUM, AND CESIUM ISOTOPE CORRELATIONS WITH BURNUP

  • KIM, JUNG SUK;JEON, YOUNG SHIN;PARK, SOON DAL;HA, YEONG-KEONG;SONG, KYUSEOK
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.924-933
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    • 2015
  • The correlation of the isotopic composition of uranium, plutonium, neodymium, and cesium with the burnup for high burnup pressurized water reactor fuels irradiated in nuclear power reactors has been experimentally investigated. The total burnup was determined by Nd-148 and the fractional $^{235}U$ burnup was determined by U and Pu mass spectrometric methods. The isotopic compositions of U, Pu, Nd, and Cs after their separation from the irradiated fuel samples were measured using thermal ionization mass spectrometry. The contents of these elements in the irradiated fuel were determined through an isotope dilution mass spectrometric method using $^{233}U$, $^{242}Pu$, $^{150}Nd$, and $^{133}Cs$ as spikes. The activity ratios of Cs isotopes in the fuel samples were determined using gamma-ray spectrometry. The content of each element and its isotopic compositions in the irradiated fuel were expressed by their correlation with the total and fractional burnup, burnup parameters, and the isotopic compositions of different elements. The results obtained from the experimental methods were compared with those calculated using the ORIGEN-S code.