• Journal of the Korean Ceramic Society
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• v.53 no.5
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• pp.494-499
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• 2016

In this work, the effects of different sintering inhibitors added to $La_{0.8}Sr_{0.2}MnO_{3-{\partial}}$ (LSM) were studied to obtain an optimum cathode material for cathode-supported type of Solid oxide fuel cell (SOFC) in terms of phase stability, mechanical strength, electric conductivity and porosity. Four different sintering inhibitors of $Al_2O_3$, $CeO_2$, NiO and gadolinium doped ceria (GDC) were mixed with LSM powder, sintered at $1300^{\circ}C$ and then they were evaluated. The phase stability, sintering behavior, electrical conductivity, mechanical strength and microstructure were evaluated in order to assess the performance of the mixture powder as cathode support material. It has been found that the addition of $Al_2O_3$ undesirably decreased the electrical conductivity of LSM; other sintering inhibitors, however, showed sufficient levels of electrical conductivity. GDC and NiO addition showed a promising increase in mechanical strength of the LSM material, which is one of the basic requirements in cathode-supported designs of fuel cells. However, NiO showed a high reactivity with LSM during high temperature ($1300^{\circ}C$) sintering. So, this study concluded that GDC is a potential candidate for use as a sintering inhibitor for high temperature sintering of cathode materials.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.554-557
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• 2008

In this study, two types of central flow distributor designs are presented and compared to obtain the optimal compact design which has the least flow resistance and the uniform flow distribution in a vehicular fuel cell stack. For effective and reliable prediction on the thermo-flow characteristics of the reactants flow over the entire fuel cell stack domain, open channel flow in the bipolar plates of the power generating cells were simulated by applying a simplified flow resistance model with an empirical porous concept. A number of case studies were performed to figure out an optimal configuration of a central flow distributor device in terms of the time-dependent thermo-flow behavior and load-dependent flow distribution. The results showed that the stable and load-independent thermo-flow uniformity is very design specific, which is closely associated with the design of central manifolding devices in order to achieve the enhanced volumetric power density and the reliable long-lasting operating of fuel cells.

• Journal of the Korean Ceramic Society
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• v.44 no.12
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• pp.727-732
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• 2007

In order to fabricate a highly performing cathode for low-temperature type solid oxide fuel cells working at below $700^{\circ}C$, electrode microstructure control and electrode polarization measurement were performed with an electronic conductor, $La_{0.8}Sr_{0.2}MnO_3$ (LSM) and a mixed conductor, $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$(LSCF). For both cathode materials, when $Sm_{0.2}Ce_{0.8}O_2$ (SDC) buffer layer was formed between the cathode and yttria-stabilized zirconia (YSZ) electrolyte, interfacial reaction products were effectively prevented at the high temperature of cathode sintering and the electrode polarization was also reduced. Moreover, cathode polarization was greatly reduced by applying the SDC sol-gel coating on the cathode pore surface, which can increase triple phase boundary from the electrolyte interface to the electrode surface. For the LSCF cathode with the SDC buffer layer and modified by the SDC sol-gel coating on the cathode pore surface, the cathode resistance was as low as 0.11 ${\Omega}{\cdot}cm^2$ measured at $700^{\circ}C$ in air atmosphere.

• Advances in Energy Research
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• v.2 no.1
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• pp.21-31
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• 2014

The use of a microporous membrane along with Au/C catalyst for direct glycerol alkaline fuel cell was investigated. In comparison with Nafion 112, the microporous Celgard 3401 membrane provides a better cell performance due to the lower ionic resistance as confirmed by impedance spectra. The single cell using Au/C as anode catalyst prepared by using PVA protection techniques provided a higher maximum power density than the single cell with commercial PtRu/C at $18.65mW\;cm^{-2}$ The short-term current decay studies show a better stability of Au/C single cell. The higher activity of Au/C over PtRu/C was owing to the lower activation loss of Awe. The magnitude of current decay indicates a low problem of glycerol crossover from anode to cathode side. The similar performance of single cell with and without humudification at cathode points out an adequate transport of water through the microporous membrane.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.6
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• pp.868-877
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• 2011

This paper presents a parallel computing methodology for polymer electrolyte fuel cells (PEFCs) and detailed simulation contours of a real-scale fuel cell. In this work, a three-dimensional two-phase PEFC model is applied to a large-scale 200 $cm^2$ fuel cell geometry that requires roughly 13.5 million grid points based on grid-independence study. For parallel computing, the large-scale computational domain is decomposed into 12 sub-domains and parallel simulations are carried out using 12 processors of 2.53 GHz Intel core i7 and 48GB RECC DDR3-1333. The work represents the first attempt to parallelize a two-phase PEFC code and illustrate two-phase contours in a representative industrial cell.

• Journal of Microbiology and Biotechnology
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• v.22 no.2
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• pp.270-273
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• 2012

These studies were conducted to determine the effects of various concentrations of ammonium and nitrate on current generation using dual-cathode microbial fuel cells (MFCs). Current generation was not affected by ammonium up to $51.8{\pm}0.0$ mg/l, whereas $103.5{\pm}0.0$ mg/l ammonium chloride reduced the current slightly. On the other hand, when $60.0{\pm}0.0$ and $123.3{\pm}0.1$ mg/l nitrate were supplied, the current was decreased from $10.23{\pm}0.07$ mA to $3.20{\pm}0.24$ and $0.20{\pm}0.01$ mA, respectively. Nitrate did not seem to serve as a fuel for current generation in these studies. At this time, COD and nitrate removal were increased except at $123{\pm}0.1$ mg ${NO_3}^-/l$. These results show that proper management of ammonium and nitrate is very important for increasing the current in a microbial fuel cell.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.4
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• pp.369-380
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• 2023

There is no clear standard for estimating the power distribution of fuel cells and batteries to meet the required power in hydrogen electric vehicles. In this study, a hydrogen electric vehicle simulation model equipped with a vehicle electric component model including a fuel cell system was built, and a power distribution strategy between fuel cells and batteries was established. The power distribution model was operated through two control strategies using step control and fuzzy control, and each control strategy was evaluated through data derived from the simulation. As a result of evaluation through the behavior data of state of charge, fuel cell current and balance of plant, fuzzy control was evaluated as a proper strategy in terms of control stability and durability.

• Journal of the Society of Naval Architects of Korea
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• v.60 no.3
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• pp.146-154
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• 2023

Efforts have been made to reduce the greenhouse gas emissions from ships by limiting the energy efficiency index, and net zero CO₂ emission was proposed recently. The most ideal measure to achieve zero emission ship is electrification, and fuel cells are considered as a practical power source of the electrified propulsion system. The electric efficiency in the electrochemical reaction of fuel cells can be achieved up to 60% practically. The remaining energy is converted to heat energy but most of them are dissipated by cooling. In the author's previous research, a hybrid propulsion system utilizing not only electricity but also heat was introduced by combining electric motor and steam turbine. In this article, long term efficiency is evaluated for the introduced hybrid propulsion system by considering a virtual 24,000 TEU class container carrier model. To reflect a more practical operating condition, the actual navigation data of a similar real ship in the real world were collected from automatic identification system data and applied. From the result, the overall efficiency of the hybrid propulsion system is expected to be higher than a conventional electric propulsion fuel cell ship by 30%.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.83.1-83.1
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• 2010

A Dead-end mode operation is one of the best way to maximize the gas usage rate. But, some components of fuel cell stack like gas diffusion layer(GDL) or membrane can be damaged in dead-end mode operation. In this study, a Large Scale Polymer electrolyte membrane fuel cell(PEMFC) for a dead-end operation has been developed. The stack is composed with 4 cells which has over 400cm2 of active area. Hydrogen is used as a fuel, and oxygen is used as a oxidant. The dead-end operation performance was evaluated by a long-term dead-end mode operation. The fuel cell stack is operated over 1,500 hours in dead-end mode operating fuel cell test station. And the performance change of the fuel cell stack was investigated.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.2
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• pp.156-163
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• 2015

The fuel cells have been investigated in the applications of marine as the high efficient and eco-friendly power generating systems. In this study, modeling of IR Type molten carbonate fuel cell (Internal Reforming Type molten carbonate fuel cell) has been developed to analyze the feasibility of thermal energy utilization. The model is developed under Aspen plus and used for the study of system performances over regarding fuel types. The simulation results show that the efficiency of MCFC system based on NG fuel is the highest. Also, it is also verified that the steam reforming is suitable as pre-reforming for diesel fuel.