• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2005년도 춘계학술대회
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• pp.260-263
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• 2005

The effects of internal manifold designs the reactant feed-stream in Polymer Electrolyte Fuel Cells (PEFCs) is studied to figure out mass flow-distribution patterns over an entire fuel cell stack domain. Reactants flows are modeled either laminar or turbulent depending on regions and the open channels in the bipolar plates are simulated by porous media where permeability should be pre-determined for computational analysis. In this work, numerical models for reactant feed-stream in the PEFC manifolds are classified into two major flow patterns: Z-shape and U-shape. Several types of manifold geometries are analyzed to find the optimal manifold configurations. The effect of heat generation in PEFC on the flow distribution is also investigated applying a simplified heat transfer model in the stack level (i.e. multi-cell electrochemical power-generation unit). This modeling technique is well suited for many large scale problems and this scheme can be used not only to account for the manifold flow pattern but also to obtain information on the optimal design and operation of a PEMC system.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2005년도 제17회 워크샵 및 추계학술대회
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• pp.554-557
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• 2005

The bipolar plate is a major component of the PEM fuel cell stack, which takes a large portion of stack cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity. To achieve desired electric properties, specimens made with different mixing ratio, processing pressure and temperature were tested. To increase mechanical strength, one or two layer of woven carbon fabric were added to the original graphite and resin composite. Thus, the composite material is consisted of the three phases: graphite particles, epoxy resin, and carbon fabric. By increasing mixing ratio, fabricated pressure and process temperature, electric conductivity was improved. The results of tensile test showed that the tensile strength of two-phase graphite composite was about 5MPa, and that of three-phase composite was increased to 54MPa.

• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.643-659
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• 2022

For the economic analysis of fuel cells, levelized cost of electricity was calculated according to the type, capacity, and annual production of the fuel cells. The cost of every component was calculated through the system component breakdown. The direct cost of the system included stack cost, component cost, assembly, test, and conditioning cost, and profit markup cost were added. The effect of capacity and annual production was analyzed by fuel cell type. Sensitivity analysis was performed according to stack life, capital cost, project period, and fuel cost. As a result, it was derived how much the economic efficiency of the fuel cell improves as the capacity increases and the annual production increases.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.79.2-79.2
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• 2010

FCEV(Fuel Cell Electric Vehicle)는 연료전지스택의 각 셀에서 반응하는 화학에너지를 전기에너지로 변환하여 차량을 구동하는 시스템이다. 이러한 연료전지 셀이 정상적인 발전이 되지 않을 경우 비정상적인 전압이 발전되고 이것을 방치한다면 연료전지 스택의 영구적인 고장을 야기할 수 있다. 이를 방지하기 위해 SVM(Stack Voltage monitor) 제어기는 각 셀의 전압을 측정하고 그 정보를 상위 제어기인 FCU(Fuel cell Control Unit)에 전달한다. 이에 FCU는 연료전지스택의 고장을 운전자에게 알리고 연료전지스택의 발전을 멈추게 한다. 기존에 SVM 제어기는 각 셀마다 분압저항을 통하여 측정하며 이 전압의 차를 이용하여 셀 전압을 계산하는 방식이었다. 이는 상위 셀로 갈수록 오차가 커지는 문제가 있고 다수의 CPU 및 DC/DC 컨버터가 적용이 필요하여 복잡한 구성과 가격이 높은 문제가 있었다. 이러한 문제점을 해결하기 위하여 cell monitoring IC를 적용하였고 좀 더 정밀한 측정과 간단한 인터페이스를 구성할 수 있었다. 본 연구에서는 기존 SVM 제어기보다 안정되고 정밀한 SVM 제어기의 개발에 대해 기술하였다.

• 한국재료학회지
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• 제4권7호
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• pp.741-749
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• 1994

The planar solid oxide fuel cell(SOFC) contains several ceramic materials depending on its structure and has rdfractory metal parts for manifolds, shrouds and current leads. Among ceramic materials for planar SOFC, joining of lanthanum chromite separator and yttria stabilized zirconia(YSZ) electoyte in planar SOFC stack to give strong gas tight seals is necessary for satisfactory operation and high performance. Nevertheless, for planar SOFC/sub s/, how to seal the cell stack and gas manifold remains as one of the unsolved problems. Therefore, in this study. we investigated the joining of sintered lanthanum chromite and YSZ pellets using unsintered lanthanum chromite green films as sealent. Scanning electron microscopy(SEM) and energy dispersive X-ray analysis(EDX) revealed that Ca in the sealing material diffused and dissolved into YSZ and sintered lanthanum chromite, and unsintered lanthanum chromite green films reacted with YSZ to from a new phase at the interface. Also, the densification of unsintered lanthanum chromite green films was inpeded by the Ca migration.

• 공업화학
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• 제3권4호
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• pp.535-546
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• 1992

The molten carbonate fuel cell(MCFC) has been under Intensive development for the last decade as a second generation fuel cell. The advantages of the MCFC over the phophoric acid fuel cell are higher efficiency, its ability to accept CO and $H_2$ as a fuel, lower material costs, and high operating temperature making internal reforming possible. These features, along with low atmospheric emissions, will open up a significant market as an attractive means of developing highly efficient power plant. This article reviews a status of the MCFC research and development, a principle of the MCFC, and cell and stack technology including the status of electrodes, matrices and electrolytes. Several technical difficulties which must be resolved to be commercialized art mainly focused.

• 한국수소및신에너지학회논문집
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• 제19권5호
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• pp.417-422
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• 2008

In this paper, a novel DC/DC low-voltage high-current converter circuit is proposed to improve the efficiency of power converter used in the grid-connected fuel-cell generator system. We proposed a novel high efficiency grid-connected power conditioning system for RPG fuel cell. On the result of that, the loss of system was decreased rapidly by driving stack within the condition of maximum efficiency. The peak currents of the current-type inductor and the transformer's coil are reduced by synchronizing switching frequency of Buck-type converter is increased twice as the Push-Pull converter's switching frequency. The novel structure of DC/DC converter is able to realize ZVS-ZCS in fuel-cell system is proposed. The proposed switching component of Push-Pull converter has the ZVS and ZCS function by using the circuit of new passive clamp.

• Journal of Electrical Engineering and Technology
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• 제3권2호
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• pp.143-151
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• 2008

This paper presents the operation of Fuel Cell Distributed Generation(FCDG) systems in distribution systems. Hence, modeling, controller design, and simulation study of a Solid Oxide Fuel Cell(SOFC) distributed generation(DG) system are investigated. The physical model of the fuel cell stack and dynamic models of power conditioning units are described. Then, suitable control architecture based on fuzzy logic and the neural network for the overall system is presented in order to activate power control and power quality improvement. A MATLAB/Simulink simulation model is developed for the SOFC DG system by combining the individual component models and the controllers designed for the power conditioning units. Simulation results are given to show the overall system performance including active power control and voltage regulation capability of the distribution system.

• 한국수소및신에너지학회논문집
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• 제18권4호
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• pp.439-445
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• 2007

Proton exchange membrane Fuel Cells(PEMFCs) have been spotlighted because of their broad potential application for potable electrical devices, automobiles and residential usages. However, their utilization is limited to low temperature operation due to the electrolyte dehydration at high temperature. High temperature PEMFC operation offers high CO tolerance and easy water management. This review presents development of high temperature($120{\sim}200^{\circ}C$) PEMFC. Especially, PEMFC which is based on acid-doped PBI membrane is discussed.

• Journal of Electrical Engineering and Technology
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• 제6권2호
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• pp.255-262
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• 2011

This paper proposes a grid-tied power conditioning system for fuel cell, which consists of three-phase current-fed DC-DC converter and three-phase PWM inverter. The three-phase current-fed DC-DC converter boosts fuel cell voltage of 26-48 V up to 400 V with zero-voltage switching (ZVS) scheme, while the three-phase PWM(Pulse Width Modulation) inverter controls the active and reactive power supplied to the grid. The operation of the proposed power conditioning system with fuel cell model is verified through simulations with PSCAD/EMTDC software. The feasibility of hardware implementation is verified through experimental works with a laboratory prototype with 1.2 kW proton exchange membrane (PEM) fuel cell stack. The proposed power conditioning system can be commercialized to interconnect the fuel cell with the power grid.