• Transactions of the Korean hydrogen and new energy society
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• v.19 no.3
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• pp.209-216
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• 2008

In the present study, a mathematical model has been formulated for the performance of polymer electrolyte fuel cells. Modify the concentration polarization equation using concentration coefficient that represents the characteristics of bipolar plate reactant distribution. The model predictions have been compared with experimental results and good agreement has been demonstrated for the cell polarization curves. The effects of operating parameters on the performance of fuel cells have been studied. Increases of operation pressure reduce the effect of temperature on the performance.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.04a
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• pp.206-209
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• 2004

Mechanical behavior of a fuel stack was studied using an orthotropic material model. The fuel stack is essentially composed of a bipolar plate (BP), a gasket, an end plate, a membrane electrolyte assembly (MEA), and a gas diffusion layer (GDL). Each component is fastened with a suitable pressure. It is important to maintain a suitable contact pressure distribution of BP, because it influences the power efficiency of the fuel cell stack. When it is exposed to high temperature, its behavior must be stable. Hence, we performed stress analysis at high temperature as well as at room temperature. At high temperature, the contact pressure distribution becomes poor. Many patents have shown that using an elastomer can overcome this phenomena. Its effect was also studied. By using an elastomer, we found a good contact pressure distribution at high temperature as well as at room temperature.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.5
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• pp.557-565
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• 2022

The effect of flow configuration in ammonia-fed solid oxide fuel cell are investigated by using a three-dimensional numerical model. Typical flow configurations including co-flow and counter-flow are considered. The ammonia is directly fed into the stack without any external reforming process, resulting in an internal decomposition of NH3 in the anode electrode of the stack. The result showed that temperature profile in the case of counter-flow is more uniform than the co-flow configuration. The counter-flow cell, the temperature is highest at the middle of the channel while in the case of co-flow, the temperature is continuously increased and reached maximum value at the outlet area. This leads to a higher averaged current density in counter-flow compared to that of co-flow, about 5%.

• Transactions of the Korean hydrogen and new energy society
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• v.12 no.4
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• pp.239-246
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• 2001

Fossil fuel such as oil and natural gas has been used and will be no longer supplied enough to demand in the beginning of thisg century. The use of the fuel makes a lot of environmental pollution to threaten human being's health especially in big cities and produces a lot of $CO_{2}$ to make green house effect of the earth. It is the time to use clean fuel such as hydrogen to prevent the expected energy crisis and the pollution. A new engine such as fuel cell can be used instead of the conventional internal combustion engine with 2 to 3 times higher efficiency of the conventional engine. The fuel cell uses hydrogen and oxygen and produces electric energy and pure water, which is a calm engine without air pollution. In big cities the city buses and the taxies powered by hydrogen fuel cells are suggested to be operated for clean environment. The energy and cost analysis performed for hydrogen and electricity production from wind power and solar cell.

• Transactions of the Korean hydrogen and new energy society
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• v.35 no.4
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• pp.370-376
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• 2024

Load variations reduce the lifespan of polymer electrolyte fuel cells (PEFCs). To analyze the impact of load variations on durability of PEFCs, two stacks were built and operated continuously for 400 hours, one under load variations and the other under constant current condition with the same energy output. Using the example model provided by Mathworks, we obtained load variation data for the experiments. The performance curves were measured every 100 hours and analyzed by current interruption method and electrochemical impedance spectroscopy. The degradation comparison shows a much larger decrease in performance under the load variation. The activation resistance, electrical resistance, and mass transfer resistance are all found to increase more.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3440-3445
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• 2007

For proton exchange membrane fuel cell, it is very important to design the flow channel on separation plate optimally to maximize the current density at same electrochemical reaction surface and reduce the concentration polarization occurred at high current density. In this paper, three dimensional computation model including anode and cathode domain together was developed to examine effects of flow patterns and operation conditions such as humidity and operating temperature on performance of fuel cell. Results show that voltage at counter flow condition is higher than that at coflow condition in parallel and interdigitated flow pattern. And fuel cell with interdigitated flow pattern which has better mass transport by convection flow through gas diffusion layer has higher performance than with parallel flow pattern but its pressure drop is increased such that the trade off between performance and pressure drop should be considered for selection of flow pattern of fuel cell.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.4
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• pp.422-431
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• 2007

Polymer electrolyte membrane fuel cell(PEMFC) is very interesting power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, improvement of performance and effect of temperature. These problems can be approached to be solved by using mathematical models which are useful tools for analysis and optimization of fuel cell performance and for heat and water management. In this paper, the present work is to develop an electrochemical model to examine the electrochemical process inside PEM fuel cell. A complete set of considerations of mass, momentum, species and charge is developed and solved numerically with proper account of electrochemical kinetics. When depth of gas channel becomes thinner, diffusion of reactant makes well into gas diffusion layer(GDL) and the performance increases. Although at low current region there is little voltage difference between experimental data of PEM fuel cell and numerical data. When the porosity size of gas diffusion layer for PEM fuel cell is bigger, oxygen diffusion occurs well and oxygen mass fraction appears high in catalyst layer.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.5
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• pp.44-52
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• 2012

Fuel cell electric vehicles have some noise problems due to its air processing unit which is required to feed the ambient air into the fuel cell stack. Discrete-frequency noises are radiated from a centrifugal blower due to rotor-stator interaction. Their fundamental frequency is the blade passing frequency, which is determined by the number of rotor blades and their rotating speed. To reduce such noises, multi-chamber perforated muffler has been designed. In this paper, in order to improve the transmission loss of a perforated muffler, the relationship between the impedance model of a perforated hole and its noise reduction performance is studied, and the applicability of a short-length perforated muffler to air processing unit of fuel cell system is described using acoustic simulation results and experimental data. The acoustic velocity vector across the neck of a perforated hole is very important design factor to optimize the transmission of an intake muffler. The suggested short-length perforated muffler is effective on discrete-frequency noises while keeping the volume of intake muffler minimized.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.4
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• pp.517-529
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• 2023

The objectives of this paper are: (1) to conduct the thermal analyses of the disposal cell using COMSOL Multiphysics; (2) to determine whether the design of the disposal cell satisfies the thermal design requirement; and (3) to evaluate the effect of design modifications on the temperature of the disposal cell. Specifically, the analysis incorporated a heterogeneous model of 236 fuel rod heat sources of spent nuclear fuel (SNF) to improve the reality of the modeling. In the reference case, the design, featuring 8 m between deposition holes and 30 m between deposition tunnels for 40 years of the SNF cooling time, did not meet the design requirement. For the first modified case, the designs with 9 m and 10 m between the deposition holes for the cooling time of 40 years and five spacings for 50 and 60 years were found to meet the requirement. For the second modified case, the designs with 35 m and 40 m between the deposition tunnels for 40 years, 25 m to 40 m for 50 years and five spacings for 60 years also met the requirement. This study contributes to the advancement of the thermal analysis technique of a disposal cell.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.789-798
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• 2018

The role of empirical equation to predict the performance of polymer electrolyte membrane fuel cell is important. The activation, ohmic and mass transfer losses were separated in a polarization curve, and the curve fitting according to each region was performed using Kim's model and Hao's model. Changes of each loss were compared according to operation variables of the temperature, pressure, oxygen concentration and membrane thickness. The existing model showed a good fitting convergence, but less fitting accuracy in the separated loss region. A new model using the convergence coefficient was suggested to improve the accuracy of performance prediction of fuel cells of which results were demonstrated.