• Applied Chemistry for Engineering
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• v.18 no.3
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• pp.284-290
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• 2007

Biodiesel and its blend fuels from soybean oil were characterized for their oxidation to apply automobile fuel from the analysis of FAME (fatty acid methyl ester) and chemical properties. Biodiesel produced from soybean oil contained unsaturated fatty acids (> 85 wt%) such as oleic acid, linoleic acid, and linolenic acid. Especially, polyunsaturated fatty acids such as linoleic acid and linolenic acid containing active methyl radical were over 60 wt%. It is believed that linoleic acid and linolenic acid cause oxidation. Linoleic acid and linolenic acid during oxidation were major reactants, and compounds with the carbon number having around 36 (boiling point of about $500^{\circ}C$) were produced from those of radical autoxidation.

• New & Renewable Energy
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• v.2 no.2 s.6
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• pp.118-125
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• 2006

The target of this work was the process development of demonstration plant to produce the high quality alternative fuel oil by the pyrolysis of mixed plastic waste. In the first step of research, the bench-scale units of 70 t/y and the pilot plant of 360 t/y had been developed. Main research contents in this step were the process performance test of pilot plant of 360 ton/year and the development of demonstration plant of 3,000 t/y, which was constructed at Korea R & D Company in Kimjae City. The process performance of pilot plant of 360 t/y showed about 80% yield of liquid product, which was obtained by both light gas oil(LGO) and heavy gas oil(HGO), The boiling point range distribution of LO product that was mainly consisting of olefin components in PONA group appeared at between that of commercial gasoline and kerosene. On the other hand, HO product was mainly paraffin and olefin components and also appeared at upper temperature distribution range than commercial diesel. Gas product showed a high fraction of $C_3\;and\;C_4$ product like LPG composition, but also a high fraction of $CO_2$ and CO by probably a little leak of process.

• Tribology and Lubricants
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• v.34 no.5
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• pp.191-196
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• 2018

Bunker C is used in heavy-lift ships, furnaces, and boilers for generating heat, and power. Bunker C has only four regulations for quality standards and is rarely inspected in Korea. For these reasons, other oils such as used lubricant oil are commonly blended with Bunker C. This illegal mixture of fuel can damage the boilers, engines and affect the environment adversely. In this study, we investigate the fuel properties and perform atomic analysis of illegal Bunker C blended with used lube oil. The test results show that higher quantities of used lube oil in Bunker C have higher flash points, total acid numbers, copper corruption, solid contamination, and metal components. Further, increasing quantities of used lube oil in Bunker C cause lower viscosity, sulfur, and V content. However, adequate sample (approximately 1 L) is needed to evaluate presence of adulterants in Bunker C, we attempted the SIMDIST analysis. In the SIMDIST chromatogram, the used engine oils are detected for longer retention times than Bunker C owing to the high boiling point. We also quantitatively analyzed the lube oil content using SIMDIST.

• Journal of the Korean Applied Science and Technology
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• v.23 no.1
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• pp.19-25
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• 2006

Flesh wasters from tannery create major environmental problems. Despite their considerable fat content, these waster do not find important usage. Their disposal is also troublesome and costly. We have investigated the possible use of this fat as the production of biodiesel(fatty acid methyl esters) by transesterification using with fossil fuels. The fat released the waste by boiling water under the optimal condition (i.e., temperature, $120^{\circ}C;$ decompression, 200mbar) and used to dry without refining for the production of fatty acid methyl esters. Under the optimal condition, the experimental value of biodiesel yield was about 96%. The result of the chemical and GC analysis showed fatty acid composition and characteristics of biodiesel. Evaluation of the product indicated that it was suitable for use as a biodiesel fuel. In result of this experiment oil extract from fleshing process can be transformed into an environmentally affination fuel, to provide economical and ecological profits.

• Corrosion Science and Technology
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• v.19 no.1
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• pp.1-7
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• 2020

Chalk River Unidentified Deposits (CRUDs) were collected from the Korean pressurized water reactor (PWR) plant (A, B, and C) where the axial offset anomaly (AOA) occurred. AOA, also known as a CRUD-induced power shift, is one of the key issues in maintaining stable PWR plant operations. CRUDs were sampled from spent nuclear fuel rods and analyzed using an electron probe micro-analyzer (EPMA). This paper describes the characteristics of boron-deposits from the CRUDs sampled from twice-burnt assemblies from the Korean PWR. The primary coolant of a PWR contains boron and lithium. It is known that boron deposition occurs in a thick CRUD layer under substantial sub-cooled nucleate boiling (SNB). The results of this study are summarized as follows. Boron was not found at the locations where the existence was confirmed in simulated CRUDs, in other words, the cladding and CRUD boundaries. Nevertheless, we clearly observed the presence of boron and confirmed that boron existed as a lump in crystalline form. In addition, the study confirmed that CRUD existed in a crystal form with a unique size of about 10 ㎛.

• Nuclear Engineering and Technology
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• v.26 no.2
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• pp.237-246
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• 1994

A high flow critical heat flux (CHF) correlation, based on the single-pin CHF experimental data for finned and unfinned heated rods, was developed for the thermal-hydraulic design and safety analysis of the Korea Multi-purpose Research Reactor (KMRR) core. The correlation consists of dimensionless parameters such as Reynolds number, thermodynamic equilibrium quality, liquid-to-vapor density ratio, and hydraulic equivalent diameter ratio. The fin effect was taken into account in the correlation by a finned-to-unfinned heated perimeter ratio. The effects of a cold wall and non-uniform axial power distribution ore discussed to verify the applicability of the single-pin based correlation to the KMRR fuel bundle. The correlation limit departure from nucleate boiling ratio (DNBR) was determined as 1.44 from the statistical analysis of the CHF data.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.3
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• pp.508-516
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• 1989

The objective of this study is to investigate on the pulsating combustion of a granular coal in a Rijke type pulse combustor. The combustor is made of a 120cm long pipe with a honeycomb as a fire grate in the lower half. A fixed amount of coal is laid on the honeycomb and burned downward after ignition by using propane gas. Then the combustion driven acoustic oscillation occurs and makes the combustion pulsate with a very high amplitude. The effect of the pulsation and the air flow rate on the combustion characteristics is examined in comparison with the normal combustion. The non-pulsating combustion is made possible by placing absorbing material under the honeycomb. The combustion phenomena are observed visually, the burning time is measured in order to evaluate the combustion rate, and the variation of the gas temperatures is recorded. It is found that the fuel particle is greatly agitated like boiling by the flow pulsation and the burning-down velocity is so fast that the fuel is burned almost simultaneously. The combustion rate can be increased as twice as that of non-pulsating combustion with increase of the air flow rate. And the combustion becomes clean with less soot deposit and emission.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.5
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• pp.172-180
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• 2006

This study was to analyze the effect of mixed fuel composition and mass fraction on the characteristics of evaporating diesel spray and combustion under the various ambient conditions. The characteristics of vaporization distribution and combustion were visualized by laser induced fluorescent method and direct photography. The experiments were conducted in the constant volume vessel and rapid compression expansion machine with optical access. Multi-component fuels mixed i-octane, n-dodecane and n-hexadecane were injected the vessel and rapid compression expansion machine with electronically controlled common rail injector. Experimental results show that fuel vapor formed stratified distribution. And vaporization and diffusion are become actively increasing in mass fraction of low boiling point component. Consequently multi-component fuels were expected to control the evaporating behavior according to their suitable mass fraction.

• Nuclear Engineering and Technology
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• v.50 no.5
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• pp.639-647
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• 2018

In this study, the effects of selecting water/silver nanofluid as both a coolant and a reactivity controller during the first operating cycle of a light water nuclear reactor are investigated. To achieve this, coupled neutronic-thermo-hydraulic analysis is employed to simulate the reactor core. A detailed VVER1000/446 reactor core is modeled in monte carlo code (MCNP), and the model is verified using the porous media approach. Results show that the maximum required level of silver nanoparticles is 1.3 Vol.% at the beginning of the cycle; this value drops to zero at the end of cycle. Due to substitution of water/boric acid with water/Ag nanofluid, reactor operation time at maximum power extends to 357.3 days, and the energy generation increases by about 27.3%. The higher negative coolant temperature coefficient of reactivity in the presence of nanofluid in comparison with the water/boric acid indicates that the reactor is inherently safer. Considering the safety margins in the presence of the nanofluid, minimum departure from nucleate boiling ratio is calculated to be 2.16 (recommendation is 1.75).

• Progress in Superconductivity and Cryogenics
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• v.22 no.4
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• pp.51-56
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• 2020

In order to increase thrust of the space launch vehicle, liquid oxygen as an oxidizer and kerosene or liquid hydrogen as a fuel are generally used. The oxidizer tank and fuel tanks are manufactured by composite materials such as CFRP (Carbon Fiber Reinforced Plastic) to increase pay load. The thermal stress of the cryogenic propellant tank should be considered because it has large temperature gradient. In this study, to confirm the design integrity of the oxidizer tank of liquid oxygen, a numerical analysis was conducted on the thermal stress and temperature distribution of the tank for various charging speed of the cryogenic fluid from 100 ~ 900 LPM taking into account the evaporation rate of the liquid nitrogen by convective heat transfer outside the tank and boiling heat transfer inside the tank. The thermal stress was also calculated coupled with the temperature distribution of the CFRP tank. Based on the analysis results, the charging speed of the LN2 can majorly affects the charging time and the resultant thermal stress.