• Bulletin of the Korean Chemical Society
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• v.30 no.4
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• pp.771-772
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• 2009

• Proceedings of the PSK Conference
• /
• 2002.10a
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• pp.345.3-346
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• 2002

In connection with the asymmetric synthesis of chiral l.2-diol. we report here the total synthesis of (＋)-frontalin using diastereoselective alkylation featuring tridentate chelation-controlled asymmetric alkylation of a-hydroxyketone, in which the chiral auxiliary is attached to the hydroxyl group as ether linkage. The starting D-glyceraldehyde acetonide was converted (S)- ［(4R)-2.2-dimethyH,3-dioxolan-4-yl］ (4-methoxyphenyl) methanol. (omitted)

• Bulletin of the Korean Chemical Society
• /
• v.16 no.2
• /
• pp.191-193
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• 1995