• Bulletin of the Korean Chemical Society
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• v.22 no.8
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• pp.837-841
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• 2001

The electronic absorption and Raman spectra of $\alpha\omega-diphenylpolyenyl$, anions Ph(CH)nPh- (DPn- , n = 3, 5, 7, 9, and 13), with odd number of carbons at the polyene part, have been studied in the tetrahydrofuran (THF) solutions and in their solid film states, respectively. In the case of Raman spectra for DPn- , the frequencies and relative intensities of some Raman peaks regularly change with the increase of polyene chain length. The spectral patterns of anions (DPn- ) are very similar with those of radical anion (DPn${\cdot}$- ). However, the C=C stretching peaks of DPn- anions are observed in the 25-35 cm-1 higher frequency region than those of DPn${\cdot}$- radical anions. In the case of long chain models such as DP9- and DP13- , the C=C stretching peaks are observed in even higher frequency region than those of the corresponding neutral polyenes such as DP8, DP10, and DP12. The Raman patterns of DPn- anions in the THF solutions are similar with those in their solid film states. On the other hand, their electronic absorption spectra show a considerable difference each other. The n- ${\pi}*$ electronic absorption bands of DPn- anions in the THF solutions have been observed in the 0.27-0.39 eV lower energy region than those in their solid film states due to the solvent effects on polyene anions.

• Journal of the Earthquake Engineering Society of Korea
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• v.25 no.4
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• pp.179-189
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• 2021

Conditional spectra (CS) are applied to the seismic fragility assessment of a nuclear power plant (NPP) containment building for comparison with a relevant conventional uniform hazard response spectrum (UHRS). Three different control frequencies are considered in developing conditional spectra. The contribution of diverse magnitudes and epicentral distances is identified from deaggregation for the UHRS at a control frequency and incorporated into the conditional spectra. A total of 30 ground motion records are selected and scaled to simulate the probability distribution of each conditional spectra, respectively. A set of lumped mass stick models for the containment building are built considering nonlinear bending and shear deformation and uncertainty in modeling parameters using the Latin hypercube sampling technique. Incremental dynamic analysis is conducted for different seismic input models in order to estimate seismic fragility functions. The seismic fragility functions and high confidence of low probability of failure (HCLPF) are calculated for different seismic input models and analyzed comparatively.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2000.10a
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• pp.27-32
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• 2000

Microearthquake records with magnitude 2.6~3.1 recorded in the southeastern part of the Korean peninsula during 1994~1998 are analyzed. Total of 42 records consisted of 12 events instrumented at 7 stations. The response spectra with the above data shows that the frequency range of the dominant response is about 10~25Hz and are compared with the standard response spectrum. The result implies that the characteristics of the microearthquake ground motion differ from those of standard response spectrum presented in US NRC Reg. Guide 1.60 especially at higher frequencies.

• Bulletin of the Korean Chemical Society
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• v.20 no.11
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• pp.1340-1344
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• 1999

The electrochemical behavior of oxide layers on aluminium was studied using electrochemical impedance spectroscopy. Impedance spectra were taken at a compact and a porous oxide layer of Al. The anodic films on Al have a variable stoichiometry with gradual reduction of oxygen deficiency towards the oxide-electrolyte interface. Thus, the interpretation of impedance spectra for oxide layers is complicated, with the impedance of surface layers differing from those of ideal capacitors. This layer behavior with conductance gradients was caused by an inhomogeneous dielectric. The frequency response cannot be described by a single RC element. The oxide layers of Al are properly described by the Young model of dielectric constant with a vertical decay of conductivity.

• Archives of Pharmacal Research
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• v.10 no.1
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• pp.1-8
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• 1987

One of the problems of derivatie spectrophotometry, the decrease of signal-to-noise ratio by derivative operations, was solved by three concepts of digital filtering, ensemble averaging, least squares polynomial smoothing and Fourier smoothing. The suthors made several compouter programs written in APPLE SOFT BASIC language for the actual applications of the concepts of these digital filters on UV spectrophotometer system. As a result, ensemble averaging could not be used as a routine operation for the spectrophotometer used. The maximum S/N ratio enhancement factors achieved by least squares polynomial smoothing were 6.17 and 7.47 for the spectra of Gaussian and Lorentzian distribution models, and by Fourier smoothing 16.42 and 11.78 for the spectra of two models, respectively.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.15 no.6 s.99
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• pp.652-659
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• 2005

In this paper, seismic qualification analysis for the Plant control Panel is carried out to confirm the structural integrity under the seismic conditions represented by required response spectra(RRS). The finite element method(FEM) is used for the analysis and a mode combination method is adopted to obtain a more reliable spectrum analysis results. In addition, the experimental analysis is performed to compare the reliability of the analytical results. The analysis results shows that the plant control panel system is designed to have the dynamic rigidity with no resonance frequency below 33 Hz. The analytically calculated maximum stress of the plant control panel system is $36\%$ of the field strength of material, thus it can be shown that the system has a stable structure for the seismic load.

• Journal of Magnetics
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• v.3 no.2
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• pp.41-43
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• 1998

The frequency spectra of complex permeability have been measured as a function of ac field amplitude in the annealed amorphous $Fe_{83}Zr_7B_8Cu_2 $ ribbons. The longitudinal permeability results from the rotational magnetization at small fields, $h_o$<5 mOe in as-quenched samples. However, at the further increase of ho, the wall motion begins to be involved in the low frequency region. The permeability from the wall motion drastically decreases in the annealed sample, while that from the rotational magnetization increases up to annealing temperature of 50$0^{\circ}C$ and then drops there after.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.64 no.9
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• pp.1281-1287
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• 2015

We report the characteristics and differences of two types of attenuation measurement methods for electromagnetic partial discharge signal in GIS. The pulse method is to measure the attenuated waveforms in time domain and coverts them into frequency domain to get the attenuation spectra of given GIS section. This method simulates the real partial discharge signal. The frequency swept continuous wave method can obtain attenuation spectra directly so that it gives attenuation with low noise floor and simplicity. We show that both methods are effective and exchangeable because the attenuation results measured by two methods have similar trends

• Korean Journal of Optics and Photonics
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• v.6 no.2
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• pp.165-171
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• 1995

Infrared-Radio frequency double resonance (IRRFDR) and Infrared-Microwave double resonance (IRMWDR) spectroscopy have been used to probe a level of A symmetry for $CD_{3}$OH. Double resonance spectra of $CD_{3}$OH have been investigated over the range of 940 to 1020 $cm ^{-1}$ . Twenty K-type doublet transitions have been observed in both the radio frequency region, which covers 50 MHz to 1 GHz, and the microwave region, which covers 8 GHz to 12 GHz. The results propose new assignments of infrared (IR) absorption transitions and far-infrared (FIR) laser emission lines. These involve torsional excited levels and CO stretch states. Measurements of the A state splitting have permitted the determination of the asymmetry splitting parameters $S^{o}$(n, K) and $^{co}$ (n, K) for (n, K)=(0.3) and (1.3)

• The Bulletin of The Korean Astronomical Society
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• v.39 no.1
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• pp.45.1-45.1
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• 2014

We present the results of a time series analysis of the long-term radio lightcurves of four blazars: 3C 279, 3C 345, 3C 446, and BL Lacertae. We exploit the data base of the University of Michigan Radio Astronomy Observatory (UMRAO) monitoring program which provides densely sampled lightcurves spanning 32 years in time in three frequency bands located at 4.8, 8, and 14.5,GHz. Our sources show mostly flat or inverted (spectral indices -0.5 < alpha < 0) spectra, in agreement with optically thick emission. All lightcurves show strong variability on all time scales. Analyzing the time lags between the lightcurves from different frequency bands, we find that we can distinguish high-peaking flares and low-peaking flares in accord with the classification of Valtaoja et al. (1992). The periodograms (temporal power spectra) of the observed lightcurves are consistent with random-walk powerlaw noise without any indication of (quasi-)periodic variability. The fact that all four sources studied are in agreement with being random-walk noise emitters at radio wavelengths suggests that such behavior is a general property of blazars.