• Title/Summary/Keyword: Frequencies

Search Result 10,427, Processing Time 0.038 seconds

Ab Initio Studies of Hydrogen Bihalide Anions: Anharmonic Frequencies and Hydrogen-Bond Energies

  • Cheong, Byeong-Seo
    • Journal of the Korean Chemical Society
    • /
    • v.63 no.4
    • /
    • pp.237-245
    • /
    • 2019
  • Hydrogen bihalide anions, $XHX^-$ (X = F, Cl, and Br) have been studied by high level ab initio methods to determine the molecular structure, vibrational frequencies, and energetics of the anions. All bihalide anions are found to be of linear and symmetric structures, and the calculated bond lengths are consistent with experimental data. The harmonic frequencies exhibit large deviations from the experimental frequencies, suggesting the vibrations of these anions are very anharmonic. Two different approaches, the VSCF and VPT2 methods, are employed to calculate the anharmonic frequencies, and the results are compared with the experimental frequencies. While the ${\nu}_1$ and ${\nu}_2$ frequencies are in reasonable agreement with the experimental values, the ${\nu}_3$ and ${\nu}_1+{\nu}_3$ frequencies still exhibit large deviations. The hydrogen-bond energies and enthalpies are calculated at various levels including the W1BD and G4 composite methods. The hydrogen-bond enthalpies calculated are in good agreement with the experimental values.

Experimental study of extracting artificial boundary condition frequencies for dynamic model updating

  • Hou, Chuanchuan;Mao, Lei;Lu, Yong
    • Smart Structures and Systems
    • /
    • v.20 no.2
    • /
    • pp.247-261
    • /
    • 2017
  • In the field of dynamic measurement and structural damage identification, it is generally known that modal frequencies may be measured with higher accuracy than mode shapes. However, the number of natural frequencies within a measurable range is limited. Accessing additional forms of modal frequencies is thus desirable. The present study is concerned about the extraction of artificial boundary condition (ABC) frequencies from modal testing. The ABC frequencies correspond to the natural frequencies of the structure with a perturbed boundary condition, but they can be extracted from processing the frequency response functions (FRF) measured in a specific configuration from the structure in its existing state without the need of actually altering the physical support condition. This paper presents a comprehensive experimental investigation into the measurability of the ABC frequencies from physical experiments. It covers the testing procedure through modal testing, the data processing and data analysis requirements, and the FRF matrix operations leading to the extraction of the ABC frequencies. Specific sources of measurement errors and their effects on the accuracy of the extracted ABC frequencies are scrutinised. The extracted ABC frequencies are subsequently applied in the damage identification in beams by means of finite element model updating. Results demonstrate that it is possible to extract the first few ABC frequencies from the modal testing for a variety of artificial boundary conditions incorporating one or two virtual pin supports, and the inclusion of ABC frequencies enables the identification of structural damages without the need to involve the mode shape information.

An LSP Extraction Method Based on the Spectral Difference (스펙트럼차에 기초한 LSP 추출방법)

  • 김홍국
    • Proceedings of the Acoustical Society of Korea Conference
    • /
    • 1993.06a
    • /
    • pp.253-258
    • /
    • 1993
  • In this paper, we propose a new method to extract the line spectrum pair (LSP) frequencies. When speech signal is analyzed by the autocorrelation method, the spectral difference in the logarithmic spectra of the model at steps p and p-1 oscillates. There are p-1 frequency points where the values of the spectral dfference take on either maximum or minimum between 0 and half sampling frequency. We show that these frequencies are excatly the LSP frequencies of order p-1, which can be found by searching the frequencies where the spectral difference reaches either maxima or minima. also, the LSP frequencies of order p can be obtained from this spectral difference. In this case, we derive the expression governing the pth order LSP frequencies. The efficient search for finding the LSP frequencies of order p can be done by proving the property that the LSP frequencies of order p and p-1 are interlaced with each other.

  • PDF

A Study of Gene Frequency of Proline-rich Protein, Double-band Protein and Pa Protien in Patotic Saliva according to Family Name of Korean People (한국인 성씨에 따른 이하선 탕개 내 Pr,Db,Pa의 유전자빈도에 관한 연구)

  • Chong-Youl Kim
    • Journal of Oral Medicine and Pain
    • /
    • v.15 no.1
    • /
    • pp.55-60
    • /
    • 1991
  • After dividing 372 Korean people of 47 different family names into 307 people of 28 indigenous family name groups and 65 people of 19 immigrated family name groups and investigating Pr. Db, Pa gene frequency of each family name groups based on phenotype of parotid saliva character the author have got following conclusions. 1. The gene frequencies of indigenous family name groups were Pr1=0.686, Pr2=0.314, Pr gene frequencies of immigrated family name groups were Pr1=0.7, Pr2=0.3. 2. The gene frequencies of indigenous family name groups were Db==0.021, Db-=0.979, Pr gene frequencies of immigrated family name groups were Db+=0.023, Db-=0.977. 3. The gene frequencies of indigenous family name groups were Pa+=0.248, Pa-=0.752, Pr gene frequencies of immigrated family name groups were Pa+=0.206, Pa-=0.794. 4. The Pr gene frequencies of immigrated family name groups were in the middle of those of Chinese people and indigenous people groups. 5. There was no significant difference of Db gene frequencies between indigenous and immigrated family name groups. 6. Pa gene frequencies of immigrated family name groups were similar to those of Chinese people.

  • PDF

A hybrid inverse method for small scale parameter estimation of FG nanobeams

  • Darabi, A.;Vosoughi, Ali R.
    • Steel and Composite Structures
    • /
    • v.20 no.5
    • /
    • pp.1119-1131
    • /
    • 2016
  • As a first attempt, an inverse hybrid numerical method for small scale parameter estimation of functionally graded (FG) nanobeams using measured frequencies is presented. The governing equations are obtained with the Eringen's nonlocal elasticity assumptions and the first-order shear deformation theory (FSDT). The equations are discretized by using the differential quadrature method (DQM). The discretized equations are transferred from temporal domain to frequency domain and frequencies of the nanobeam are obtained. By applying random error to these frequencies, measured frequencies are generated. The measured frequencies are considered as input data and inversely, the small scale parameter of the beam is obtained by minimizing a defined functional. The functional is defined as root mean square error between the measured frequencies and calculated frequencies by the DQM. Then, the conjugate gradient (CG) optimization method is employed to minimize the functional and the small scale parameter is obtained. Efficiency, convergence and accuracy of the presented hybrid method for small scale parameter estimation of the beams for different applied random error, boundary conditions, length-to-thickness ratio and volume fraction coefficients are demonstrated.

Application of Kelvin's theory for structural assessment of FG rotating cylindrical shell: Vibration control

  • Khadimallah, Mohamed A.;Hussain, Muzamal;Harbaoui, Imene
    • Advances in concrete construction
    • /
    • v.10 no.6
    • /
    • pp.499-507
    • /
    • 2020
  • In current study, utilizing the Kelvin's theory with polynomial, exponential and trigonometric volume fraction laws for functionally graded cylindrical shell vibrations. Effects of different parameters for ratios of length- and height-to-radius and angular speed versus fundamental natural frequencies been determined for two categories of cylindrical shells with clamped-free edge condition. By increasing different value of height-to-radius ratio, the resulting backward and forward frequencies increase and frequencies decrease on increasing length-to-radius ratio. Moreover, on increasing the rotating speed, the backward frequencies increases and forward frequencies decreases. The frequencies are same when the cylinder is stationary. The frequencies increases and decreases on changing the constituent materials. The frequency results are verified with the earlier literature for the applicability of present model.

A study on the Acoustic Mode and Cavity-Tone in a Perforated Tube Muffler (다공형 소음기의 음향 모우드와 공동음에 관한 연구)

  • 권영필
    • Proceedings of the Acoustical Society of Korea Conference
    • /
    • 1993.06a
    • /
    • pp.17-20
    • /
    • 1993
  • The acoustic mode of a perforated tube muffler was investigated both theoretically and experimentally to explain the cavity-tones induced by through-flow. The cutoff frequencies for the axisymmetric modes were obtained and confirmed experimentally. It was found that the cutoff frequencies are decreased significantly by the perforated tube. The onset frequencies of the cavity-tones were compared with the cutoff frequencies of the acoustic mode and it was found that the cavity-tones are induced by the radial acoustic modes and their frequency stages are coincident with the discrete cutoff frequencies.

  • PDF

Identification of Defect Frequencies in Rolling Element Bearing Using Directional Spectra of Vibration Signals (구름 베어링의 결함 주파수 규명을 위한 방향 스펙트럼의 이용)

  • 박종포;이종원
    • Journal of KSNVE
    • /
    • v.9 no.2
    • /
    • pp.393-400
    • /
    • 1999
  • Defect frequencies of rolling element bearings are experimentally investigated utilizing the two-sided directional spectra of the complex-valued vibration signals measured from the outer ring of defective bearings. The directional spectra make it possible to discern backward and forward defect frequencies. The experimental results show that the directional zoom spectrum is superior to the conventional spectrum in identification of bearing defect frequencies, in particular the inner race defect frequencies.

  • PDF

A Study of Polymorphisms of Proline-rich Protein, Double-band Protein and Pa Protien in Ullung-do and Jawall-do (한국 울릉도,자월도 거주민의 이하선 타액내 Proline-rich protein(Pr), Double-band protein(Db)과 Salivary acidic protein(Pa)의 유전적 다형 현상에 관한 연구)

  • Soon-Min Chung;Chong-Youl Kim
    • Journal of Oral Medicine and Pain
    • /
    • v.15 no.1
    • /
    • pp.91-104
    • /
    • 1991
  • After alkaline slab polyacrylamide gel electrophoresis and 3.3'-DMB staining of parotid saliva from 48 peoples in Ullung-do and 35 peoples in Jawall-do, the author have got following conclusions. 1. The gene frequencies of Proline-rich protein in Ullung-do were Pr1 =0.719, Pr2=0.281 2. The gene frequencies of Proline-rich protein in Jawall-do were Pr1=0.671, Pr2=0.329 3. The gene frequencies of Double band protein in Ullung-do were Db+=0.087, Db-=0.913 4. The gene frequencies of Double band protein in Jawall-do were Db+=0.0.106, Db-=0.0.894 5. The gene frequencies of Pa protein in Ullung-do were Pa+=0.179, Pa-=0.821 6. The gene frequencies of Pa protein in Jawall-do were Pa+=0.167, Pa-=0.833 7. The gene frequencies of Pr1 of Ullung-do and jawall-do were lower than those of Pr1 in Seoul and Onyang, but similar to those of Pr1 in kangnung and Cheju. 8. The gene frequencies of Db- of Ullung-do and Jawall-do were much higher than those of Db+ in Japanese, Chinese and other populations in Korean.

  • PDF

Technical note: Estimation of Korean industry-average initiating event frequencies for use in probabilistic safety assessment

  • Kim, Dong-San;Park, Jin Hee;Lim, Ho-Gon
    • Nuclear Engineering and Technology
    • /
    • v.52 no.1
    • /
    • pp.211-221
    • /
    • 2020
  • One fundamental element of probabilistic safety assessment (PSA) is the initiating event (IE) analysis. Since IE frequencies can change over time, time-trend analysis is required to obtain optimized IE frequencies. Accordingly, such time-trend analyses have been employed to estimate industry-average IE frequencies for use in the PSAs of U.S. nuclear power plants (NPPs); existing PSAs of Korean NPPs, however, neglect such analysis in the estimation of IE frequencies. This article therefore provides the method for and results of estimating Korean industry-average IE frequencies using time-trend analysis. It also examines the effects of the IE frequencies obtained from this study on risk insights by applying them to recently updated internal events Level 1 PSA models (at-power and shutdown) for an OPR-1000 plant. As a result, at-power core damage frequency decreased while shutdown core damage frequency increased, with the related contributions from each IE category changing accordingly. These results imply that the incorporation of time-trend analysis leads to different IE frequencies and resulting risk insights. The IE frequency distributions presented in this study can be used in future PSA updates for Korean NPPs, and should be further updated themselves by adding more recent data.