• 제목/요약/키워드: Free standing

검색결과 255건 처리시간 0.029초

AZO박막을 이용한 Terephthalate가 삽입된 Zn-Al 층상 이중 수산화물의 합성 (Synthesis of Terephthalate Intercalated Zn-Al Layered Double Hydroxides Using AZO Thin Film)

  • 박기태;윤순길
    • 한국재료학회지
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    • 제27권3호
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    • pp.161-165
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    • 2017
  • In this paper, synthesis of terephthalate intercalated Zn-Al: Layered double hydroxides (LDHs) was studied. We designed freestanding Zn-Al: carbonate LDH nanosheets for a facile exchange technique. The as-prepared Zn-Al carbonate LDHs were converted to terephthalate intercalated Zn-Al:LDHs by ion exchange method. Initially, Al-doped ZnO (AZO) thin films were deposited on p-Si (001) by facing target sputtering. For synthesis of free standing carbonate Zn-Al:LDH, we dipped the AZO thin film in naturally carbonated water for 3 hours. Further, Zn-Al: carbonate LDH nanosheets were immersed in terepthalic acid (TA) solution. The ion exchange phenomena in the terephthalate assisted Zn-Al:LDH were confirmed using FT-IR analysis. The crystal structure of terephthalate intercalated Zn-Al:LDH was investigated by XRD pattern analysis with different mole concentrations of TA solution and reaction times. The optimal conditions for intercalation of terephthalate from carbonated Zn-Al LDH were established using 0.3 M aqueous solution of TA for 24 hours.

Reducing the wind pressure at the leading edge of a noise barrier

  • Han, Seong-Wook;Kim, Ho-Kyung;Park, Jun-Yong;Ahn, Sang Sup
    • Wind and Structures
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    • 제31권3호
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    • pp.185-196
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    • 2020
  • A method to reduce the wind pressure at the leading edge of a noise barrier was investigated by gradually lowering the height of a member added to the end of the noise barrier. The shape of the lowered height of the added member was defined by its length and slope, and the optimal variable was determined in wind tunnel testing via the boundary-layer wind profile. The goal of the optimal shape was to reduce the wind pressure at the leading edge of the noise barrier to the level suggested in the Eurocode and to maintain the base-bending moment of the added member at the same level as the noise-barrier section. Using parametric wind tunnel investigation, an added member with a slope of 1:2 that protruded 1.2 times the height of the noise barrier was proposed. This added member is expected to simplify, or at least minimize, the types of column members required to equidistantly support both added members and noise barriers, which should thereby improve the safety and construction convenience of noise-barrier structures.

Fabrication and Characterization of Dodecyl-derivatized Silicon Nanowires for Preventing Aggregation

  • Shin, Donghee;Sohn, Honglae
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3451-3455
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    • 2013
  • Single-crystalline silicon nanowires (SiNWs) were fabricated by using an electroless metal-assisted etching of bulk silicon wafers with silver nanoparticles obtained by wet electroless deposition. The etching of SiNWs is based on sequential treatment in aqueous solutions of silver nitrate followed by hydrofluoric acid and hydrogen peroxide. SEM observation shows that well-aligned nanowire arrays perpendicular to the surface of the Si substrate were produced. Free-standing SiNWs were then obtained using ultrasono-method in toluene. Alkyl-derivatized SiNWs were prepared to prevent the aggregation of SiNWs and obtained from the reaction of SiNWs and dodecene via hydrosilylation. Optical characterizations of SiNWs were achieved by FT-IR spectroscopy and indicated that the surface of SiNWs is terminated with hydrogen for fresh SiNWs and with dodecyl group for dodecyl-derivatized SiNWs, respectively. The main structures of dodecyl-derivatized SiNWs are wires and rods and their thicknesses of rods and wire are typically 150-250 and 10-20 nm, respectively. The morphology and chemical state of dodecyl-derivatized SiNWs are characterized by scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy.

유기적 통합의 개념으로 본 프랭크 로이드 라이트의 가구디자인 특성 (The Characteristics of Frank Lloyd Wright's Furniture Design focused on Organic Integration)

  • 문은미
    • 한국실내디자인학회논문집
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    • 제15권4호
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    • pp.115-122
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    • 2006
  • The purpose of this study is to investigate the design principles of organic integration on furniture design by Frank Lloyd Wright. He consistently pursued organic principles in interior design, furniture and equipments. He insisted that every elements of a building can be integrated into architecture as if architecture can be a part of the nature. The study surveyed and analyzed the examples of furniture design in Wright houses from the viewpoints of spacial and formal integration as well as organic evolution. The study finds the characteristics of organic integration on furniture design as follows. He designed built-in furniture as an important part of the house, which seemed to grow up from the architecture design and a part of a building. He also designed and arranged free-standing furniture as spacial device in open floor plan. Moreover, furniture design repeated same geometry, modules, and proportion system of house design in order to integrate Into the building. In addition, material and color of furniture follow those of architecture. Wright's furniture design had changed from heavy forms in his early prairie houses to light and practical shapes in his Usonian period.

Wind tunnel model studies to predict the action of wind on the projected 558 m Jakarta Tower

  • Isyumov, N.;Case, P.C.;Ho, T.C.E.;Soegiarso, R.
    • Wind and Structures
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    • 제4권4호
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    • pp.299-314
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    • 2001
  • A study of wind effects was carried out at the Boundary Layer Wind Tunnel Laboratory (BLWTL) for the projected 558-m high free-standing telecommunication and observation tower for Jakarta, Indonesia. The objectives were to assist the designers with various aspects of wind action, including the overall structural loads and responses of the Tower shaft and the antenna superstructure, the local wind pressures on components of the exterior envelope, and winds in pedestrian areas. The designers of the Tower are the East China Architectural Design Institute (ECADI) and PT Menara Jakarta, Indonesia. Unfortunately, the project is halted due to the financial uncertainties in Indonesia. At the time of the stoppage, pile driving had been completed and slip forming of the concrete shaft of the Tower had begun. When completed, the Tower will exceed the height of the CN-Tower in Toronto, Canada by some 5 m.

교차결합의 변화에 따른 Polyaniline 필름의 전기적 성질과 전자기차폐 성질에 관한 연구 (Electrical and Electromagnetic Shielding Properties of Polyaniline Films with Different Degrees of Crosslinking)

  • 김재욱
    • E2M - 전기 전자와 첨단 소재
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    • 제10권1호
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    • pp.54-60
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    • 1997
  • The electrical and electromagnetic shielding properties have been investigated in polyaniline free standing films with different degrees of elongation cast from N-methyl 2-pyrrolidone(NMP) solution and camphorsulfonic acid(HCSA) doped polyaniline film. The degree of crystallinity of the crosslinked films increased with increasing the draw ratio. For the case of the oriented films doped with hydrochloric acid, we have the values of conductivities up to 173 S/cm. It is considered that the physical micro-crystalline crosslinking domains act as nucleation sites for the increase of relative crystallinity during stretching. We have obtained the value of conductivity 210 S/cm in the HCSA doped polyaniline film cast from the solvent of m-cresol, which is higher than that of the crosslinking oriented films. The electromagnetic shielding efficiency of HCSA doped polyaniline film obtained 37-41 dB in the frequency range of 10MHz-1GHlz, which is higher than that of the crosslinking oriented films. The higher value of electromagnetic shielding efficiency of HCSA doped polyaniline film suggests strong possibility of electromagnetic shielding material.

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무진동 PBD(플라스틱 보드 드레인) 시공장비 구조 최적 설계 (Structural Optimization of Vibration-free PBD(Plastic Board Drain) Construction Equipments)

  • 오성훈
    • 한국산학기술학회논문지
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    • 제8권5호
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    • pp.1300-1305
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    • 2007
  • 플라스틱보드드래인은 연약지반 개선공법의 하나로 경제적이고, 시공이 편리하며, 품질관리가 쉬워서 널리 사용되어 왔다. PBD를 지면에 수직하게 40m 깊이로 타설하는 PBD장비는 인출하중에 대해 안정적이면서 설치와 이동의 편의성을 위해 경량화 되어야한다. 본 연구에서는 구조해석을 통해 이전 장비와 철골구조에 대한 응력분포로 안전성을 평가하였다. 그리고 중량을 줄이면서 강도를 증가시킬 수 있는 철골구조를 제안하였다. 본 연구의 결과로 이전의 장비에 비해 중량이 700kg 가벼운 안전한 구조를 얻었다.

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변압기용 차음판의 진동 소음 특성 분석 (The vibration and noise characteristics analysis of Sound Insulation Panel for Transformer)

  • 정한얼;김효중;구동식;최병근
    • 동력기계공학회지
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    • 제10권4호
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    • pp.78-82
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    • 2006
  • Recently, The demands for the reduction of noise generated by transformers have been increasing. Almost all of the noise generated by transformers is a result of magnetostricitive vibration in the core. The noise radiates into the atmosphere from the tank through the insulation oil. As the noise of transformer irritates residents, needs for decreasing the noise of transformer have been arised. One method of reduction such a noise is to build a free-standing enclosure of concrete and steel plates around the transformer. However, this method has some disadvantages. Another method of noise reduction is to mount a close-fitting sound insulation panel on the side of a transformer tank. Side plate vibrations of transformer are transmitted to such a sound insulation panel along two paths. In one case, they are transmitted through air by sound pressure and in the other through supporting structures. In the paper, the vibration and noise effect which is transferred from reinforce channel to insulation panel generated by transformer have been identified for the several kinds of insulation panel and damping sheet analytically and experimetally.

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Permanent Support for Tunnels using NMT

  • Barton, Nick
    • 한국암반공학회:학술대회논문집
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    • 한국암반공학회 1995년도 정기총회 및 학술발표회
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    • pp.1-26
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    • 1995
  • Key aspects of the Norwegian Method of Tunnelling (NMT) are reviewed. These include a predictive method of support design using the six-parameter Q-system of rock mass characterisation. The rock mass rating or Q-value is updated during tunnel driving. The designed tunnel support generally consists of wet process, steel fibre reinforced shotcrete combined with fully grouted, untensioned rock bolts, Even in poor rock conditions S(fr) + B usually acts as the final rock reinforcement and tunnel lining. Since it is a drained lining, it is very economic compared to cast concrete with membranes. Light, free-standing steel liners are used to prevent water affecting the runnel environment. Rock mass conditions, and hence lining design and cost estimation can be assessed by careful use of seismic surveys. Relationships between the P-wave velocity, the rock mass deformation modulus and the Q-value have recently been established, where tunnel depth, rock porosity and the uniaxial compression strength of the rock are important variables. The rock mass modulus estimate, and simple index testing of the joints, provide the key input which joints are discretely represented (either in two dimensions with the UDEC code or in three dimensions with the 3DEC code) is generally favoured compared to continuum analysis. The latter may give a misleading impression of uniformity and deformations tend to be understimated. Q-system NMT designs of S(fr) + B (fibre reinforced shotcrete and bolting) are numerically checked and adjustments made to bolt capacities and shotcrete thickness if overloading is evident around the modelled profile.

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Electronic structure of the Au intercalated monolayer graphene on Ni(111)

  • Hwang, H.N.;Jee, H.G.;Han, J.H.;Tai, W.S.;Kim, Y.D.;Hwang, C.C.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.342-342
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    • 2010
  • We have investigated an Au intercalated monolayer graphene on Ni(111) using angle-resolved photoemission spectroscopy (ARPES), high resolution photoemission spectroscopy (HRPES), and low energy electron diffraction (LEED) at the 3A2 ARUPS beamline in Pohang Accelerator Laboratory. We find the monolayer graphene is well grown on the Ni(111) surface by the adsorption of acetylene. However, the graphene does not show the characteristic $\pi$ band near the Fermi level due to its strong interaction with the underlying substrate. When Au is adsorbed on the surface and then annealed at high temperature, we observe that Au is intercalated underneath the monolayer graphene. The process of the Au intercalation was monitored by HRPES of corresponding Au 4f and C 1s core levels as well as the electronic structure of the $\sigma$, $\pi$ states at $\Gamma$, K points. The $\sigma$, $\pi$ bands of graphene shift towards the Fermi level and the $\pi$ band is clearly observed at K point after the intercalation of full monolayer Au. The full width at half maximum (FWHM) of the C 1s peak narrows to approximately 0.42 eV after intercalation. These results imply that the interaction between the graphene and substrate is considerably weakened after the Au intercalation. We will discuss the graphene is really closer to ideal free standing graphene suggested recently.

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