• Title/Summary/Keyword: Fractionation process

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Reduction of eco-toxicity risk of heavy metals in the rotary drum composting of water hyacinth: Waste lime application and mechanisms

  • Singh, Jiwan;Kalamdhad, Ajay S.;Lee, Byeong-Kyu
    • Environmental Engineering Research
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    • v.20 no.3
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    • pp.212-222
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    • 2015
  • Experiments were conducted on the immobilization of eight heavy metals (HMs) (Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr) during 20-day rotary drum composting of water hyacinth. The Tessier sequential extraction procedure was used to investigate the fractionation of HMs. The eco-toxicity risk of HMs was assessed by risk assessment code (RAC). In the results, the bioavailability factor (BAF) for different HMs presented in the following order: Mn > Zn = Fe > Cu > Cr > Cd = Pb > Ni. The total concentration of Pb was higher than that of Zn, Cu, Mn, Cd and Cr; however, its BAF was the lowest among these HMs. These results confirmed that the eco-toxicity of HMs depends on bioavailable fractions rather than on the total concentration. The greatest reduction in bioavailability and eco-toxicity risk of HMs occurred in lime 1% and 2% as compared to control and lime 3%. The eco-toxicity risk of Fe, Ni, Pb, Cd and Cr was reduced from low risk to zero risk by rotary drum composting. These studies demonstrated the high efficiency of the rotary drum for degrading compost materials and for reducing the bioavailability and eco-toxicity risk of HMs during the composting process.

ONP 탈묵공정의 계면활성제와 지방산 비교

  • Ryu, Jeong-Yong;Song, Bong-Geun
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2010.04a
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    • pp.7-7
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    • 2010
  • Flotation deinking is a common practice for removing ink from recovered paper, and it is becoming a key process in many recycling paper mills. Flotation deinking was successfully introduced to the paper recycling industry in the 1980s, and its applications in wax removal, stickies control, and fiber fractionation have attracted great research interest. A successful flotation process has three major efficient subprocesses: the detachment of the ink particles from the fibers, the effective adhesion of the ink particles onto air bubble surfaces, and the removal of froth and ink particles from flotation cells. Surfactants can affect these subprocesses either positively or negatively. To understand how a surfactant can positively and negatively affect the flotation deinking process, the basic chemistry of surfactant in solution should be discussed.

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An expert system for hazard identification in chemical processes

  • Chae, Heeyeop;Yoon, Yeo-Hong;Yoon, En-Sup
    • 제어로봇시스템학회:학술대회논문집
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    • 1992.10b
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    • pp.430-435
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    • 1992
  • Hazard identification is one of the most important task in process design and operation. This work has focused on the development of a knowledge-based expert system for HAZOP (Hazard and Operability) studies which are regarded as one of the most systematic and logical qualitative hazard identification methodologies but which require a multidisciplinary team and demand much time-consuming, repetitious work. The developed system enables design engineers to implement existing checklists and past experiences for safe design. It will increase efficiency of hazard identification and be suitable for educational purposes. This system has a frame-based knowledge structure for equipment failures/process material properties and rule networks for consequence reasoning which uses both forward and backward chaining. To include wide process knowledge, it is open-ended and modular for future expansion. An application to LPG storage and fractionation system shows the efficiency and reliability of the developed system.

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Petrochemistry and magma process of Jurassic Boeun granodiorite in the central Ogcheon belt (중부 옥천대에 분포하는 쥬라기 보은 화강섬록암의 암석화학과 마그마과정)

  • 좌용주
    • The Journal of the Petrological Society of Korea
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    • v.5 no.2
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    • pp.188-199
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    • 1996
  • Boeun granodiorite, which intruded into the metasedimentary rocks of the Ogcheon Group, show chemical natures of metaluminous and calc-alkaline. Generating and emplacing environment of the Boeun granodiorite would have been a active continental margin. Comparing to the contemporaneous Inje-Hongcheon granodiorite in the Gyeonggi massif, the Boeun granodiorite seems likely to have formed under more immature continental arc environment. Compositional changes of major, trace and rare earth elements in granodiorite and felsic dyke are not certain to indicate crystallization differentiation. From this fact, the simple fractional crystallization model would be in question to explain the magma process which controlled the formation of the Boeun granitic mass. The model calculations for Rayleigh fractionation, fractionation with variable major-component composition, assimilation-fractional crystallization (AFC) were carried out to examine the magma process of the mass. The results of former two models do not agree with the compositional variations in the mass. The AFC model can be, however, applied to the magma process. The conditions for AFC process are (1) composition of assimilated wallrock is similar to that of primary magma. (2) assimilating rate is similar to crystallizing rate, and (3) mass of assimilated wallrock is about 10% of that of the magma. These conditions deny a possibility that the assimilated wallrock was the metasedimentary rocks of the Ogcheon Group. This indicates that after having experienced the assimilation process in deeper crust, the granodiorite magma intruded into the Ogcheon group. Every model calculating suggests that the felsic dyke was differentiated not from the granodiorite magma, but from a different source magma.

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Recycling of Wastepaper(II) -Improvement of Drainage and Strength Properties of Testliner by Successive Treatments of Flotation and Mixed Enzyme- (고재재생연구(제2보)-부상부유 및 효소처리에 의한 라이너지의 탈수성 및 강도 개선)

  • 지경락;류정용;신종호;송봉근;오세균
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.10-16
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    • 1999
  • Air froth flotation was applied to OCC recycling process as a new pulp fractionation method and the effects of strength and drainage properties of testliner were also investigated. Fines including inks, stickies, and inorganic substances in OCC stock furnish were efficiently separated by the flotation. After the flotation, selective enzymatic treatment on the flotation reject was separately preformed, and then, the refined long fiber(flotation accept) portion was combined again with the fines(flotation reject) fraction for papermaking. This combination process was found to be effective in improving strength and drainage properties of testliner based on 100% OCC.

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An Integrated Process for the Separation and Purification of Biologically Active Proteins from Human Urine (인뇨로부터 유용단백질의 통합 분리정제 공정)

  • 김기용;정광회문흥모
    • KSBB Journal
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    • v.8 no.3
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    • pp.287-294
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    • 1993
  • For the purpose of combining the purification processes for several biologically active proteins form human urine, an efficient integrated fractionation procedure has been investigated. The procedure was started by concentration with ultrafiltration and pH precipitation followed by a selectable combination of chromatography on gel filtration, adsorption, ion exchanger, affinity, and reverse phase column. By this process, the purified urokinase, epidermal growth factor and albumin migrated as a single band on SDS-polyacrylamide gel electrophoresis and were fully active. The recoveries of these purified proteins were 48%, 17%, and 46%, respectively.

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Adsorptive Bubble Separation of Zinc (II) Using Capric Acid as Collector (추출제로 카프르산을 사용한 아연(II)의 흡착 기포 분리)

  • Chung Hee Kwak;Chul Lee
    • Nuclear Engineering and Technology
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    • v.15 no.2
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    • pp.149-153
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    • 1983
  • The removal of zinc (II) from aqueous solutions has been studied by the adsorptive bubble separation processes such as solvent sublation and foam fractionation processes using capric acid as collector. The efficiency of the remoal process has been studied by changing the ionic strength and pH and the bubble separation method has been compared with the solvent extraction process using the capric acid dissolved in benzene as extractant.

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The Changes in Drying Efficiency and Paper Properties of Linerboard by the Application of the Fractions of Wood Powder as a Bulking Agent (목질 벌크향상제 분획별 적용에 따른 라이너지의 건조효율 및 물성변화)

  • Kim, Dong-Seop;Yoon, Do-Hyun;Sung, Yong Joo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.61-68
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    • 2014
  • The energy efficiency of papermaking process becomes more significant because of various new regulation of the energy consumption and the green house gas emission. In this study, the effects of wood powder addition on the drainage and the drying efficiency of the OCC based paper products, linerboard, were deeply investigated for improving energy efficiency. The fractionation of wood powder depending on the size were conducted. The bigger size of wood powder resulted in the higher bulk and the higher drainage efficiency, but the lower paper strength. The drying efficiency were in detail evaluated depending on the drying process level. In the first section of drying process until the 80% solid level, there were no significant changes in the drying efficiency by the addition of wood powder. However, after the 80 % solid level, the drying efficiency was greatly improved by the addition of wood powder. Those results showed the addition of wood powder could greatly affect not only the drainage in forming and wet pressing but also the drying process.

Revisit to the Commercial-scale Production of Rhamnolipids (재조명되는 람노리피드 양산화 동향연구)

  • Oh, Kyeongseok
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.5
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    • pp.1219-1228
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    • 2021
  • Rhamnolipids are recognized as eco-friendly biosurfactants and produced by the bio-process employing bacteria. Pseudomons aeruginosa is well-known to produce rhamnolipids in high yield during fermentation process. Rhamnose and 𝛽-hydroxylated fatty acid are main chemicals for rhamnolipids, which are produced in the form of congener mixtures. In this paper, the synthetic mechanism of rhamnolipids within bacteria cells was presented in part and foam control technologies were qualitatively described. Foam control during fermentation process was important to regulate a continuous process. During last decade, the technologies are developed enough to challenge to a commercial-scale production. In particular, rhamnolipids will be more valuable if these can be applicable to value-added chemicals, such as medicines.

Separation of EPA and DHA from Fatty Acid of Fish Oil by Urea Adduct Formation Using Supercritical Carbon Dioxide Solvent (초임계 이산화탄소 용매하의 요소부가법에 의한 어유지방산으로부터 EPA와 DHA의 분리)

  • Kim, Jae-Duck;Lim, Jong-Sung;Lee, Youn-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.2
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    • pp.41-48
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    • 1997
  • Separation of EPA and DHA from fish oil fatty acid ethyl ester (FAFE) by urea adductive crystallization method was carried out in the supercritical carbon dioxide (SC $CO_2$) as a solvent. Our results showed that SC $CO_2$ is a good candidate as a solvent in the urea adductive crystallization to separate FAFE by the number of unsaturated bonds. Compared to the separation process using methanol. SC $CO_2$ yielded better performance in the overall selectivity of EPA and DHA. The effect of process variables on separation of EPA and DHA was discussed in detailed. A hybrid technology of SC $CO_2$ fractionation and urea adductive crystallization with SC $CO_2$ was conformed as a viable process to separate and concentrate EPA and DHA from fish oil.