• Clean Technology
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• v.27 no.1
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• pp.93-103
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• 2021

As the seriousness and necessity of responding to climate change and reducing carbon emissions increases, countries around the world are continuing their efforts to reduce greenhouse gases. Among various efforts, research on CCUS, capturing and utilizing carbon dioxide generated when using carbon-based fuels, is actively being conducted. Studies on pressurized oxy-fuel combustion (POFC) that can be used with CCUS are also being conducted by many researchers. The purpose of this study is to analyze basic information related to the flame structure and pollutant emissions of pressurized oxy-fuel combustion. For this, a counter-flow diffusion flame model was used to analyze the combustion characteristics according to pressure and oxygen concentration. As the pressure increased, the flame temperature increased and the flame thickness decreased due to a reaction rate improvement caused by the activation of the chemical reaction. As oxygen concentration increased, both the flame temperature and the flame thickness increased due to an improvement to the reaction rate and diffusion because of a change in oxidizer momentum. Analyzing the related heat release reaction by dividing it into three sections as the oxygen concentration increased showed that the chemical reaction from the oxidizer side was subdivided into two regions according to the mixture fraction. In addition, the emission index of NO classified according to the NO formation mechanism was analyzed. The formation trend of NO according to each analysis condition was presented.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.3 s.258
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• pp.292-299
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• 2007

In gas turbine technology, the flame stability is inherently greater in conventional diffusion type combustion over a wider range fuel to oxidizer ratio. However, premixed type combustion which has narrow flame stability region, is widely used due to environmental reason. It has been observed in experiments that combustion instability of low frequency (${\sim}10Hz$) results from the modulation of equivalence ratio at fuel injection hole when a pressure fluctuation propagates upwards along the channel of the burner under an unchoked fuel flow condition. In this study, a commercial program was used to determine how the fuel flow rate changed with respect to the pressure, velocity of the fuel flow and the mass fraction in a choked and an unchoked condition. The calculation focuses on the upstream of the dump plane to know how the forced pressure with the fuel injection conditions affects the modulation of the equivalence ratio. Therefore, it is found that pressure fluctuation leads to oscillation of mass flow rate and then results in equivalence ratio modulation under the unchoked fuel flow condition.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.19-24
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• 2007

The deposition behavior of soot particles in a diffusion flame along a solid wall was examined experimentally by getting rid of the effect of natural convection utilizing microgravity environment. The microgravity environment was realized by using a drop tower facility. The fuel for the flame was an ethylene ($C_2H_4$) and the surrounding oxygen concentration 35% with the surrounding air velocity of $V_a$=2.5, 5, and 10 cm/s. Laser extinction method was adopted to measure the soot volume fraction distribution between the flame and burner wall. The results show that observation of soot deposition in normal flame was difficult from buoyancy and the relative position of flame and solid surface changes with time. The soot particle distribution region moves closer to the surface of the wall as the surrounding air velocity is increased. And the experiments determined the trace of the maximum soot concentration line. It was found that the distance between soot line and flame line is around 5 mm. That is, the soot particle near the flame zone tends to move away from flame zone because of thermophoretic force and to concentrate at a certain narrow area inside of the flame, finally, to adhere the solid wall.

• Journal of the Korean Society of Combustion
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• v.7 no.1
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• pp.1-7
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• 2002

Experiments have been performed to investigate the structure of axisymmetric hydrogen diffusion flame in a supersonic coflow air. The characteristics and structure of supersonic flames are compared with those of subsonic flames as the velocity of coflow air increases from subsonic to supersonic velocity of Mach 1.8. Also, the subsonic and supersonic flow fields are analyzed numerically for the non-reacting conditions and the possible flame contours indicated by fuel mass fraction are compared with the measured OH radical distributions. It is found that the flame structure indicates more like a partially premixed flame as the coflow air velocity is increased from subsonic to supersonic regimes; strong reaction zone indicated by intense OH signal is found at the center, which is different from subsonic flame cases. And it is shown that the fuel jet passes along the recirculation zones behind the bluff-body fuel nozzle resulting in relatively long mixing time. This is believed to be the reason of the partially premixed flame characteristics found in the present supersonic flames.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1172-1177
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• 2004

The evolution of incipient soot particles has been examined by high resolution electron microscopy (HRTEM) and elemental analyzer in ethylene-air inverse diffusion flames. Laser Induced Incandescence(LII) and laser scattering methods were introduced for examining the change of soot volume fraction and morphological properties in combustion generated soot qualitatively. Soot particles, collected by thermophoretic sampling were analyzed by using HRTEM to examine the nano structure of precursor particles. HRTEM micrographs apparently reveal a transformation of condensed phase of semitransparent tar-like material into precursor particles with relatively distinct boundary and crystalline which looks like regular layer structures. During this evolution histories C/H analysis was also performed to estimate the chemical evolution of precursor particles. The changes of C/H ratio of soot particles with respect to residence time can be divided into two parts: one is a very slowly increasing regime where tar-like materials are transformed into precursor particles (inception process) the other is an increasing region with constant rate where surface growth affects the increase of C/H ratio dominantly (surface growth region). These results provide a clear picture of a transition to mature soot from precursor materials.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.7 s.250
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• pp.692-699
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• 2006

In this work, $TiO_2$ nanoparticles were synthesized using $N_2-diluted$ and Oxygen-enriched co-flow hydrogen diffusion flames. The effect of flame temperature on the crystalline structure of the formed $TiO_2$ nanoparticles was investigated. The measured maximum centerline temperature of the flame ranged from 2,103k for oxygen-enriched flame to 1,339K for $N_2-diluted$ flame. The visible flame length and the height of the main reaction zone were characterized by direct photographs. The crystalline structures of $TiO_2$ nanoparticles were analyzed by XRD. From the XRD analysis, it was evident that the crystalline structures of the formed nanoparticles were divided into two sorts. In the higher temperature region, over the 1,700K, the fraction of formed $TiO_2$ nanoparticles having anatase-phase crystalline structure increased with increasing the flame temperature. On the contrary, in the lower temperature region, below the 1,600K, the fraction of anatase-phase nanoparticles increased with decreasing the flame temperature.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.3
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• pp.54-65
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• 1997

To quantify the LII signals from soot particle of flames in diesel engine cylinder, a new method has been proposed for correcting LII signal attenuated by soot particles between the measuring point and the detector. It has been verified by an experiment on a laminar jet ethylene-air diffusion flame. Being proportional to the attenuation, the ratio of LII signal at two different detection wavelengths can be used to correct the measured LIIsignal and obtain the unattenuated LII signal, from which the soot volume fraction in the flame can be estimated. Both the 1064-nm and frequency-doubled 532-nm beams from the Nd : YAG laser are used. Single-shot, one-dimensional(1-D) line images are recorded on the intensified CCD camera, with the rectangular-profile laser beam using 1-mm-diameter pinhole. Two broadband optical interference filters having the center wavelengths of 647 nm and 400 nm respectively and a bandwidth of 10 nm are used. This two-wavelength correction has been applied to the ethylene-air coannular laminar diffusion flame, previously studied on soot formation by the laser extinction method in this laboratory. The results by the LII measurement technique and the conventional laser extinction method at the height of 40 nm above the jet exit agreed well with each other except around outside of the peaks of soot concentration, where the soot concentration was relatively high and resulting attenuation of the LII signal was large. The radial profile shape of soot concentration was not changed a lot, but the absolute value of the soot volume fraction around outside edge changed from 4ppm to 6.5 ppm at r=2.8mm after correction. This means that the attenuation of LII signal was approximately 40% at this point, which is higher than the average attenuation rate of this flame, 10~15%.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.85-90
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• 2004

We have presented characteristics of a transitional behavior from a premixed flame to a triple flame in a lifted flame according to the change of equivalence ratio. The experimental apparatus consisted of a slot burner and a contraction nozzle for a lifted flame. As concentration difference of the both side of slot burner increases, the shape of flame changed from a premixed flame to a triple flame, and the liftoff height is decreased to the minimum value and then increase again. Around this minimum point, it is confirmed a transition regime from premixed flame to triple flame. Consequently, the experimental results of the liftoff height, flame curvature and luminescence intensity showed that the stabilized laminar lifted flame regime is categorized by regimes of premixed flame, triple flame and critical flame. In the visualization experiment of smoke wire, the flow divergence and redirection reappeared in premixed flame as well as triple flame. Thus we cannot express the flame front of lifted flame has a behavior of triple flame with only flow divergence and redirection. To differentiate triple flame and premixed flame, ${\Phi}$ value of partially premixed fraction is employed. The partially premixed fraction ${\Phi}$ was constant in premixed flame. In critical flame small gradient appears over the whole regime. In triple flame, typical diffusion flame shape is obtained as parabolic distribution type due to diffusion flame trailing.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.3
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• pp.403-412
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• 2006

The effect of a wall temperature on the soot deposition process from a diffusion flame to a solid wall was investigated in a microgravity environment to attain in-situ observations of the process. The fuel for the flames was an ethylene ($C_2H_4$). The surrounding oxygen concentration was 35% with surrounding air temperatures of $T_a=600K$. In the study, three different wall temperatures. $T_w$=300, 600, 800K, were selected as major test conditions. Laser extinction was adopted to determine the soot volume fraction distribution between the flame and burner wall. The experimental results showed that the maximum soot volume fractions at $T_w$=300, 800 K were $8.8{\times}10^{-6},\;9.2{\times}10^{-6}$, respectively. However, amount of soot deposition on wall surface was decreased because of lower temperature gradient near the wall with increasing wall temperature. A numerical simulation was also performed to understand the motion of soot particles in the flame and the characteristics of the soot deposition to the wall. The results from the numerical simulation successfully predicted the differences in the motion of soot particles by different wall temperature near the burner surface and are in good agreement with observed soot behavior that is, the 'soot line', in microgravity.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.195-198
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• 2014

$Fuel/N_2$ and fuel/air mixtures were treated with non-thermal DBD plasma and the changes in characteristics of laminar diffusion flame have been observed. Flame of $Fuel/N_2$ mixture generated more soot under plasma condition while less amount of soot was formed from fuel/air mixture flame. Luminescence spectrum and gas chromatography results confirmed that plasma energy converts a fraction of fuel molecules into radicals, which then form $C_2$, $C_3$, $C_4$ and higher hydrocarbon under no oxygen condition or turn into CO, $CO_2$ and $H_2O$ when oxygen is present.