• Journal of Korean Society of Water and Wastewater
• /
• v.30 no.6
• /
• pp.737-744
• /
• 2016

The investigation of effects on fouling propensity with various viscosity of feed solutions would be better understanding for forward osmosis (FO) performance since the fouling propensity was directly influenced with solution viscosity. Therefore, this study was focused on the FO fouling with model foultants (humic acid, alginate) by altering solution viscosity with change of ionic strength (I.S) and $Ca^{2+}$ concentrations. In the comparison between humic acid and alginate, as expected, the alginate generally caused more severe fouling (almost 35.8 % of flux reduction) based on the solution characteristics (high viscosity) and fouling patterns (coil and gel layer). However, interesting point to note is that the fouling propensity of alginate was more severe even though it was applied with low viscosity of feed conditions (I.S = 20 mM, $Ca^{2+}=1mM$). This might be due to that crossed linked gel layer of alginate on the FO membrane surface could be best formed in the condition of $Ca^{2+}$ presence and higher I.S, and that is more dominant to fouling propensity than the low viscosity of feed solutions.

• Journal of the Korean Society of Combustion
• /
• v.22 no.4
• /
• pp.27-34
• /
• 2017

Various approaches have been proposed to predict the ash deposition (slagging and fouling) propensity of coal, which is essential in maintaining high efficiency and preventing corrosion/damage of a coal-fired boiler. The common method is to establish an index of the ash deposition propensity based on elementary coal composition and advanced characterization of ash properties, which is readily applicable to design, operation and maintenance of coal-fired boilers. Although many indexes have been developed for this purpose, their validity is still not satisfactory in actual applications to particular coal types or operating conditions. This paper reviews the status of predictive approaches for the ash deposition propensity, and assesses the performance of existing indexes by comparing the results for selected coals. This work will contribute to the development of a comprehensive and practical method for prediction of the ash deposition propensity.

• Journal of Korean Society of Water and Wastewater
• /
• v.30 no.5
• /
• pp.511-519
• /
• 2016

Shale gas has become increasingly important as a viable alternative to conventional gas resources. However, one of the critical issues in the development of shale gas is the generation of produced water, which contains high concentration of ionic compounds (> TDS of 100,000 mg/L). Accordingly, membrane distillation (MD) was considered to treat such produced water. Experiments were carried out using a laboratory-scale direct contact MD (DCMD). Synthetic produced water was prepared to examine its fouling propensity in MD process. Antiscalants and in-line filtration were applied to control fouling by scale formation. Fouling rates (-dJ/dt) were calculated for in-depth analysis of fouling behaviors. Results showed that severe fouling occurred during the treatment of high range produced water (TDS of 308 g/L). Application of antiscalant was not effective to retard scale formation. On the other hand, in-line filtration increased the induction time and reduced fouling.

• Environmental Engineering Research
• /
• v.21 no.2
• /
• pp.109-120
• /
• 2016

Conventional treatment techniques cannot meet the stringent modern water quality regulations emanating from the need to provide high quality drinking water. Therefore, a number of studies have suggested low pressure membrane filtration as a worthwhile alternative. However, a major constraint to the extensive use of this technology in low and middle income countries is the high operating and maintenance costs caused by the inherent predisposition to membrane fouling. Notwithstanding, pretreatment of feed water using techniques such as coagulation, adsorption, oxidation and bio-filtration is believed to control fouling. In this review paper, the existing scientific knowledge on membrane fouling and pretreatment techniques for controlling fouling in low pressure membranes is analyzed with the aim of providing new and valuable insights into such techniques, as well as unveiling crucial issues noteworthy for further studies. Among the techniques reviewed, coagulation was observed to be the most cost-effective and will remain the most dominant in the coming years. Although oxidants and magnetic ion exchange resins can also control fouling, the propensity of oxidants to form health treating precursors and the high economic implications of magnetic ion exchange resins will hinder their adoption in developing countries.

• 한국연소학회:학술대회논문집
• /
• 2013.06a
• /
• pp.87-90
• /
• 2013

In pulverized coal fired boilers, slagging and fouling may cause significant effect on the operational life of boiler. As increasing a consumption of low rank coal, slagging and fouling are main issues in pulverized coal combustion. This study predicts ash deposition propensity in a 0.7 MW pilot-scale furnace. Slagging model is employed as a User-Defined Function (UDF) of FLUENT and validated against measurement and prediction. The results show good agreement compared with experiment. There is need to development of a pulverized coal combustion and slagging analysis at low coal.

• 한국연소학회:학술대회논문집
• /
• 1995.06a
• /
• pp.91-103
• /
• 1995

In recent years, significant advances have been made in the development of methods to predict ash behavior in utility boilers. This paper provides an overview of methods used to assess and predict ash formation and deposition. It has discussed some of the key problems associated with the formation and deposition of ash during the combustion of pulverized coal. Although considerable progress has been made in understanding of the fundamental mechanisms of ash formation, transport, growth, and strength development, there is still much work to be done. There is a need to develop quantitative relationships between the characteristics of the entrained ash and the physical properties of ash deposits that influence deposit growth, strength development, and cleanability. Also data from bench-scale, pilot-scale, and full-scale units are needed in order to determine operating conditions which will minimize deposition problems, maximize efficiency, and reduce emissions.

• Korean Membrane Journal
• /
• v.7 no.1
• /
• pp.1-18
• /
• 2005

The permeate flux decline due to membrane fouling can be addressed using a variety of theoretical stand-points. Judicious selection of an appropriate theory is a key toward successful prediction of the permeate flux. The essential criterion f3r such a decision appears to be a detailed characterization of the feed solution and membrane properties. Modem theories are capable of accurately predicting several properties of colloidal systems that are important in membrane separation processes from fundamental information pertaining to the particle size, charge, and solution ionic strength. Based on such information, it is relatively straight-forward to determine the properties of the concentrated colloidal dispersion in a polarized layer or the cake layer properties. Incorporation of such information in the framework of the standard theories of membrane filtration, namely, the convective diffusion equation coupled with an appropriate permeate transport model, can lead to reasonably accurate prediction of the permeate flux due to colloidal fouling. The schematic of the essential approach has been delineated in Figure 5. The modern approaches based on appropriate cell models appear to predict the permeate flux behavior in crossflow membrane filtration processes quite accurately without invoking novel theoretical descriptions of particle back transport mechanisms or depending on adjust-able parameters. Such agreements have been observed for a wide range of particle size ranging from small proteins like BSA (diameter ${\~}$6 nm) to latex suspensions (diameter ${\~}1\;{\mu}m$). There we, however, several areas that need further exploration. Some of these include: 1) A clear mechanistic description of the cake formation mechanisms that clearly identifies the disorder to order transition point in different colloidal systems. 2) Determining the structure of a cake layer based on the interparticle and hydrodynamic interactions instead of assuming a fixed geometrical structure on the basis of cell models. 3) Performing well controlled experiments where the cake deposition mechanism can be observed for small colloidal particles (< $1\;{\mu}m$). 4) A clear mechanistic description of the critical operating conditions (for instance, critical pressure) which can minimize the propensity of colloidal membrane fluting. 5) Developing theoretical approaches to account for polydisperse systems that can render the models capable of handing realistic feed solutions typically encountered in diverse applications of membrane filtration.

• Journal of Korean Society of Water and Wastewater
• /
• v.30 no.4
• /
• pp.441-447
• /
• 2016

Development of shale gas has drawn increasing attention since it is one of promising alternative energy resources. However, contamination of groundwater and surface water during the extraction of shale gas is becoming a serious environmental issues, which brings the needs to treat wastewater generated from hydraulic fracking. In this study, the feasibility of membrane distillation (MD) for the treatment of shale gas wastewater was investigated using a laboratory scale experimental setup. Flat-sheet MD membranes were used to treat produced water from a shale gas well in the United States. Different configurations such as direct contact MD (DCMD) and air gap MD (AGMD) were compared in terms of flux and fouling propensity. The foulants on the surface of the membranes were examined. The results suggest that MD can treat the shale gas produced water containing more than 200,000 mg/L of total dissolved solids, which is impossible by other technologies such as reverse osmosis (RO) and forward osmosis (FO). In this study, we investigated the possibility of processing and characterization of shale gas produce wastewater using membrane distillation. Laboratory scale membrane distillation experimental device was developed. It was compared the flat-sheet direct contact membrane distillation and flat-sheet air gap membrane distillation. AGMD flux in lower than the flux of DCMD, it was expected that the contamination caused by organic matters.

• Journal of Korean Society of Water and Wastewater
• /
• v.30 no.6
• /
• pp.755-764
• /
• 2016

Pressure retarded osmosis (PRO) processes can be implemented on a number of water types, using different technologies and achieving various power outcomes. In this study, Sewage facility effluent was used for feed solution of PRO and synthetic NaCl water for draw solution. This study was conducted to investigate effect of water quality of pretreatment on power density and flux decline in PRO process. The results show that organic and particulate foulants have to be removed for more stable operation. Flourescence technique with EEM enables to investigate the chemical properties of aquatic organic matter by extracting spectral information. Humic/fulvic matters and soluble microbial by-products were analyzed as the most affecting factors on the PRO performance. As a result of analyzing the whole system based on the energy consumption of the unit process, specific energy consumption(SEC) of the applicable technology for PRO pre-treatment should be about $0.2kWh/m^3$ or less.