• Title/Summary/Keyword: Fouling materials

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Evaluation of operating performance of secondary effluents treatment membrane system adapted chemical backwashing (약품역세를 적용한 하수재이용 막여과 시스템의 운전성능 평가)

  • Kim, Young-Hoon;Lee, Chang-Ha;Jeon, Min-Jung;Lee, Yong-Soo;Lee, Eui-Jong;Nam, Jong-Woo;Kim, Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.335-342
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    • 2011
  • Secondary effluent contains particle compounds which are comprised of microorganisms that occurs membrane fouling when the water is reused. This study evaluates the characteristics of membrane fouling of secondary effluent reuse. Effects of chemical backwashing are analyzed to reduce membrane fouling by regular chemical backwashing. As the result, major membrane foulants are verified EPS materials which include protein and polysaccharide that cause biofilm cake layer on the membrane. Also, sodium hypochlorite is applied to chemical backwashing. The backwashing improves recover rate when injected chemical concentration is increased and chemical backwashing cycle is amplified. Chemical backwashing cycle affects more than injected chemical concentration yet idle time does not noticeably influence on reducing membrane fouling.

Determination of Optimal Coagulation Condition for Coagulation-UF Water Treatment Process (응집-UF 정수공정을 위한 칠적응집조건의 결정)

  • Lee, Chul-Woo;An, Su-Kyong;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.8
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    • pp.799-806
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    • 2005
  • Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane alone. Also, slow mixing didn't affect the reduction of membrane fouling, and rapid mixing using an in-line static mixer was more effective than using backmixer. In addition, only 11 percent of dissolved organic matter in raw water was the primary cause of fouling. Furthermore, tile primary foulant of UF membrane was hydrophobic substance, which can easily be removed by coagulation.

Three newly recorded species of Korean fouling bryozoans

  • Chae, Hyun Sook;Yang, Ho Jin;Min, Bum Sik;Noh, Geon Woo;Lee, Dong Hee;Seo, Ji Eun
    • Journal of Species Research
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    • v.11 no.3
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    • pp.180-187
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    • 2022
  • We found three fouling bryozoans from the materials collected from seven localities (ports, yacht marina, intertidal and subtidal zones) in the coastal seas of South Korea from 2003 to 2021. These three species, Thalamoporella californica (Levinsen, 1909), Scruparia ambigua (d'Orbigny, 1841), and Tricellaria inopinata d'Hondt and Occhipinti Ambrogi, 1985, and one genus Scruparia Oken, 1815 are newly added to the Korean bryozoan fauna. Of the three species, Scruparia ambigua and Tricellaria inopinata are cosmopolitan or widespread, and Thalamoporella californica is from the East Pacific Ocean in tropical/temperate water. It seems that some of the previously reported T. occidentalis in Korea have a high probability of being T. inopinata. In this study, some Tricellaria occidentalis reported by Seo (2005) are synonymized into T. inopinata. A total of 77 species of fouling bryozoans has been reported in Korea, with three new bryozoans resulting from this study. Descriptions and illustrations of the three fouling bryozoans using scanning electron microscopy are provided in this study.

Using Coagulant and Activated Carbon as Pretreatment for Membrane Fouling Control in MBR (Membrane Bioreactor) (MBR반응기의 막오염방지를 위한 활성탄과 응집제를 이용한 전처리에 관한 연구)

  • Kim, Dong-Ha
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.122-127
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    • 2006
  • The aim of this study was to investigate the characteristics of membrane fouling caused by soluble organic materials in a membrane bioreactor process. For the removal of filterable organic materials (FOC) smaller than $1{\mu}m$, coagulants and activated carbon were added. A membrane bioreactor using a submerged $17{\mu}m$ metal sieve was operated in laboratory scale to examine the possibility of membrane fouling control. As the dosage of GAC and coagulant increased, the residual FOC concentration decreased and the permeate flow rate increased markedly. The permeate flux increased with an increased PACl addition at the range from 0 to 50 mg/l. At coagulant dosage of 27mg/l, the removal of FOC was about 46% and the flux increased to 3.5 times compared to the case without PACl addition. The permeate flux increased gradually with an increase in GAC dosage. At GAC dosage of 50mg/L, the permeate flux was about 2 times higher compared that for raw water. The particle in the range of $0.1{\sim}1.0{\mu}m$ were removed effectively by the addition of GAC and coagulant. Higher osage of GAC and coagulant, led to higher removal of FOC. A different set of experiments was also performed to investigate the effect of pretreatment on the permeation ability of MBR system using the metal sieve membrane. After 40 hours of operation, the permeate flux was about 1,000 ($L/m^2-hr$), which is 20 times higher compared to the results in literature. It is likely that combined pretreatment using coagulant and activated carbon was the most effective to resolve membrane fouling problems. Moreover, the continuous operations could be successful by applying this pretreatment method.

Studies on Membrane Fouling Monitoring by Fluorescence Nano Particle and Fluorescent Spectrometry (형광 나노 입자 및 형광 분광 분석을 이용한 막오염 측정법 연구)

  • Seo, Mi-Rae;Nam, Mi-Yeon;Kim, Beom-Sik;Nam, Seung-Eun;Kim, In-Chul;Park, You-In
    • Membrane Journal
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    • v.21 no.2
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    • pp.163-170
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    • 2011
  • Membrane fouling control in water treatment may be the main obstacle for wider implementation and lower cost. A novel fluorescent spectroscope sensor device for membrane fouling integrity monitoring has been developed and evaluated in this study. PSf membranes for water treatment has been fabricated with three types of organic fluorescent materials, OB, FP, KCB. The fluorescent signal from membrane surface was analyzed throughout the filtration process. It was found that the fluorescent signal due to the membrane fouling decreased and the developed device is reliable for membrane fouling monitoring.

The Evaluation of Fouling Mechanism on Cross Flow Precoagulation-UF Process (십자형 응집-UF 막분리 공정 적용시 전처리 응집조건에 따른 막오염 메카니즘 규명)

  • Jung, Chul-Woo;Son, Hee-Jong
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.639-645
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    • 2008
  • The objectives of this research are to (1) observe changes in particle size distribution due to formation of microflocs during coagulation process (2) identify the membrane fouling potential on cross flow system (3) investigate the mechanism of membrane fouling. The rate of flux decline for the hydrophobic membrane was significantly greater than for the hydrophilic membrane, regardless of pretreatment conditions. The pretreatment of the raw water significantly reduced the fouling of the UF membrane. Also, the rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane. That is, during the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation not only improved dissolved organics removal efficiency but also flux recovery efficiency.

Surface Characteristics of Fouling Resistant Low-Pressure RO Membranes (상업용 내오염성 저압 RO막의 표면 특성 분석)

  • Hong, Seungkwan;Taylor, James;Norberg, David;Lee, Jinwoo;Park, Chanhyuk;Kim, Hana
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.1-6
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    • 2006
  • In this study, five commercially available fouling resistant low-pressure RO membranes were investigated for the treatment of seasonally brackish surface water with high organic content (${\approx}24mg/L$). The membranes investigated are LFC-1 (Hydranautics), X20 (Trisep), BW30FR1 (FilmTec), SG (Osmonics), and BE-FR (Saehan). The results of surface characterization revealed that each of these membranes has one or two unique surface characteristics to minimize the adherence of the fouling materials to the membrane. Specifically, the LFC1 membrane features a neutral or low negative surface to minimize electrostatic interactions with charged foulants. The X20, on the other hand, shows a highly negatively charged surface, and thus, is expected to perform well with feed waters containing negatively charged organics and colloids. The BW30FR1 exhibits a relatively neutral and hydrophilic surface, which could be beneficial for lessening organic and/or biofouling. The SG membrane has a smooth surface that makes it quite resistant to fouling, particularly for colloidal deposition. Lastly, BE-FR membrane demonstrated a medium surface charge and a slightly higher hydrophobicity. In the pilot study, all of the four membranes experienced a gradual increase in MTC (water mass transfer coefficient or specific flux) over time, indicating no fouling occurred during the pilot study. The deterioration of permeate water quality such as TDS was also observed over time, suggesting that the integrity of the membranes was compromised by the monochloramine used for biofouling control.

Anti-fouling Properties of Functional Coating according to the Film Thickness and its Application to the Insulators for Electrical Railway (코팅막의 두께에 따른 기능성 코팅의 내오염 특성 분석 및 전기철도용 애자로의 활용)

  • Shan, Bowen;Kang, Hyunil;Choi, Wonseok;Kim, Jung Hyun
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.66 no.2
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    • pp.94-97
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    • 2017
  • A method of improving the anti-fouling characteristics of porcelain insulators was proposed in this study. Functional coating was performed as a method of reducing the surface contamination of the porcelain insulators. The functional coating was applied on a ceramic substrate, which has the same material as the porcelain insulators. After coating the ceramic substrate 2, 3, 4, and 5 times alternately in the horizontal and vertical directions, the surface characteristics according to the thickness of the coating film were analyzed. The optimal process was selected to coat the surfaces of the post insulators and long rod insulators, which are the representative porcelain insulators. After coating, heat treatment was performed for 1 hour at $200^{\circ}C$ in a furnace to secure the durability of the coating film. Compared to the uncoated insulators, the insulators with the functional coating showed significantly improved anti-fouling characteristics as well as excellent adhesion to the coated insulator surface.

Enhancement of hydrophilicity and anti-fouling property of polysulfone membrane using amphiphilic nanocellulose as hydrophilic modifier

  • Yang, Xue;Liu, Lifang;Jiang, Shuai
    • Membrane and Water Treatment
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    • v.10 no.6
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    • pp.461-469
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    • 2019
  • In the present work, we present a new effective hydrophilicity modifier for polysulfone (PSf) membrane. Firstly, amphiphilic nanocellulose (ANC) with different substitution degrees (SD) was synthesized by esterification reaction with nanocellulose (NC) and dodecyl succinic anhydride (DDSA). The SD and morphology of ANC were characterized by titration method and transmission electron microscopy (TEM). Then, the polysulfone (PSf)/ANC blend membranes were prepared via an immersion phase inversion method. The influence of SD on the morphology, structure and performances of PSf/ANC blend membrane were carefully investigated by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), mechanical property test, contact angle measuring instrument and filtration experiment. The results showed that the mechanical property, hydrophilicity and anti-fouling property of all the PSf/ANC blend membranes were higher than those of pure PSf membrane and PSf/NC membrane, and the membrane properties were increased with the increasing of SD values. As ANC-4 has the highest SD value, PSf/ANC-4 membrane exhibited the optimal membrane properties. In conclusion, the prepared ANC can be used as an additive to improve the hydrophilicity and anti-fouling properties of polysulfone (PSf) membrane.