• 한국세라믹학회지
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• 제46권6호
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• pp.627-632
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• 2009

Formaldehyde emissions from the construct was harmful to human. Diatomite, bentonite and zeolite were used as porous materials for fabricating panels. Formaldehyde adsorption and physical characteristics of porous materials were investigated and hydrothermal method was applied to fabricate panels. Formaldehyde adsorption contents of panels with porous materials were higher than that of panel without porous materials. The panels with Cheolwon diatomite and Pohang zeolite showed excellent characteristics of Formaldehyde adsorption. These characteristics were caused by higher surface area and pore volume of porous materials. Formaldehyde adsorption contents were influenced by surface area and pore volume of panels. Correlation coefficient between surface area and Formaldehyde adsorption content of panels was 0.87. The panels with porous materials had higher strength than that without porous materials because of bridging role particles.

• 한국대기환경학회지
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• 제12권3호
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• pp.315-322
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• 1996

Recently, hospital acquired infections have an increase interest as a public problems, which are caused of indoor pollutants in hospital. Microorganisms, ethylene oxide, formaldehyde, and anesthetic gases are main hazardous pollutants in hospital. The possible pathways of the infection are a respiratory channel as well as a blood channel. The blood channel is concerned since these pollutants might be dissolved into the Ringer's solution. The objective of this research was to evaluate the removal efficiencies of adsorption trap for formaldehyde and microorganisms as indoor pollutants which permeated into the Ringer's solution. Dissolved formaldehyde in the solution was increased with the injection dose time. The amount of dissolved formaldehyde was 67.5 $\pm$ 9.5% in Ringer's solution when injection dose time was controlled about 7hrs. An adsorption trap was designed for preventing formaldehyde and microorganisms to be permeated into Ringer's solution. The adsorption trap was packed with 0.4g of active carbon (60/80 mesh) in a sterilized plastic tube (7.79 cm length, 0.46 cm i.d.) and both ends were packed with glass wool. Devised infusion set equipped with the adsorption trap showed 99.9% of removal efficiency for formaldehyde. Microorganism numbers detected on sterilized water for injection and 5% dextrose infusion used in the hospital were 2,695 $\times 10^3$ cells/l and 4,190 $\times 10^3$ cells/l, respectively. Removal efficiency by the adsorption trap was 92.3 $\pm$ 8.5% as for microorgnisms.

• 분석과학
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• 제11권3호
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• pp.174-178
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• 1998

Formaldehyde와 resorcinol을 반응시켜 chelating 수지를 제조하였다. 이 수지는 Pb(II)나 Ni(II)와 같은 전이금속에 대해 높은 흡착능을 나타내었다. Pb(II), Ni(II), Co(II), Fe(II)와 Zn(II)의 흡착과 탈착율을 batch법으로 구하였다. 이 수지의 중요한 특성은 금속 이온과 수지의 수소 이온간의 교환과정이다. 금속이온의 흡착과 탈착의 메카니즘은 수지의 작용기인 수소 이온의 탈착과 금속 이온간의 교환반응으로 생각된다. 이 수지를 이용하여 전이금속을 농축시키고, 다른 이온들로부터 Pb(II)를 분리하는데 적용해 보았다.

• Advances in nano research
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• 제8권1호
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• pp.1-11
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• 2020

In order to develop a new adsorbent for removal of formaldehyde from aqueous solution, surface modification of TiO₂ nanoparticles was performed with 2,4-Dinitrophenylhydrazine (DNPH) that have a strong affinity to the formaldehyde. Sodium dodecyl sulfate (SDS) surfactant was used to improve the DNPH grafting to TiO₂ surface. Modified adsorbents were characterized by SEM, TEM, XRD, EDX and FTIR. Since the COD level in wastewaters including formaldehyde is considerable, it is necessary to determine the COD content of the synthetic wastewater. In order to determine the optimal removal conditions, the effect of contact time (60-210 min), pH (4-10) and adsorbent dosage (0.5-1.5 g/L) on adsorption and COD removal efficiencies were studied, using response surface method. EDX and FTIR analysis confirmed the presence of nitrogen-containing functional groups on the modified TiO₂ surface. The maximum formaldehyde adsorption and COD removal efficiencies by modified TiO₂ were about 15.65 and 7.35% higher than the unmodified nanoparticles respectively. Therefore, the grafting of nano-TiO₂ with DNPH would greatly improve its formaldehyde adsorption efficiency. The optimum conditions determined for a maximum formaldehyde removal of 99.904% and a COD reduction of 94.815% by TiO₂/SDS/DNPH nanocomposites were: adsorbent dosage 1.100 g/L, pH 7.424 and the contact time 183.290 min.

• 공업화학
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• 제33권6호
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• pp.624-629
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• 2022

포름알데하이드는 호흡기 및 피부 질환을 일으키는 등 인체에 유해한 실내 환경 오염물질로 알려져 있다. 본 연구에서는 활성탄소섬유 표면에 질소 작용기를 도입하기 위하여 질소 플라즈마 처리를 하였고, 질소 작용기 함유 활성탄소섬유에 대한 포름알데하이드 흡착 특성을 고찰하였다. 주입되는 질소 가스의 유량이 증가함에 따라 활성탄소섬유 표면에 도입되는 질소 작용기의 함량이 약 7% 정도 증가하였으며, 존재하는 질소 작용기의 종류별 비율도 유사하였다. 또한 플라즈마 처리에 의한 식각 효과로 인하여 활성탄소섬유 표면에 초미세기공이 증가하였다. 이에 따라 표면 개질된 활성탄소섬유의 포름알데하이드 흡착 효율도 증가하였다. 그러나, 질소 유량이 120 sccm 이상인 조건에서는 활성탄소섬유 표면이 과도하게 식각되어, 비표면적이 감소하고 포름알데하이드 흡착 능력이 오히려 저하되었다. 따라서, 질소 플라즈마 처리된 활성탄소섬유의 포름알데하이드 흡착은 도입된 질소 작용기의 함량이 주요 요인이지만, 이와 함께 적합한 기공 구조를 가질 때 포름알데하이드의 흡착 효율이 향상됨을 알 수 있었다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 봄 학술논문 발표대회
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• pp.29-30
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• 2020

As the modern society enters, the building becomes sealed and the public's interest in the environment increases, so the interest in indoor air pollution increases and the environmental pollution is raised as an important issue not only outdoors but also indoors. In addition, the emergence of sick house syndrome (SHS) has increased the interest in formaldehyde and is a cause of deteriorating indoor air quality. Accordingly, this study prepared a functional paint by incorporating a photocatalyst in an aqueous paint, and conducted formaldehyde adsorption experiments and functional evaluation. As a result of the experiment, as the photocatalyst was added, the formaldehyde adsorption performance tended to increase. In addition, as a result of measuring the impact resistance and alkali resistance according to the KS standard, there is no difference in residual cracks and cracks between the water-based paint without the photocatalyst and the water-based paint with the photocatalyst added. Therefore, it is considered that the water-based paint added with a photocatalyst can improve the indoor air quality by adsorbing formaldehyde and can be used as a functional paint because the functionality is not different from that of a general water-based paint.

• 공업화학
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• 제27권1호
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• pp.62-67
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• 2016

본 연구에서는 정수슬러지를 원료로 사용하여 펠렛형 흡착제를 제조하고 질소흡착법, XRD, XRF 및 암모니아 승온탈착법 등을 사용하여 물리 화학적 특성을 분석하였다. 정수슬러지 유래 펠렛형 흡착제와 첨착활성탄의 암모니아 및 포름알데히드 기체의 흡착 성능을 비교하였다. 정수슬러지로부터 제조된 펠렛형 흡착제는 첨착활성탄보다 표면적과 기공부피는 훨씬 작지만 암모니아를 훨씬 더 많이 흡착할 수 있었다. 이는 정수슬러지로부터 제조된 펠렛형 흡착제 표면에 산점이 훨씬 더 많이 분포해 있어서 화학흡착에 의해 암모니아를 흡착하기 때문이다. 반면에, 산성가스인 포름알데히드 가스 흡착의 경우는 넓은 표면적과 발달된 기공으로 인하여 첨착활성탄의 흡착성능이 정수슬러지로부터 제조된 펠렛형 흡착제에 비해 훨씬 우수하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 가을 학술논문 발표대회
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• pp.48-49
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• 2020

Recently, as people's interest in environmental pollution increases, interest in indoor air pollution as well as outdoors is increasing. Accordingly, this study prepares functional paints by mixing powder activated carbon, which is a porous material, into aqueous paints, and examines the adsorption performance of volatile organic compounds (VOCs) and formaldehyde (HCHO). As a result of the experiment, the concentration of volatile organic compounds (VOCs) and formaldehyde (HCHO) tended to decrease as powder activated carbon was incorporated. It is believed that physical adsorption was achieved by the micropores of powdered activated carbon. However, in the adsorption test method, it is judged that the concentration was affected by the inflow of outside air as the chamber cover was opened to put the test object in the empty chamber where a certain concentration was maintained.

• 공업화학
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• 제23권1호
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• pp.42-46
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• 2012

본 연구에서는 메조기공 탄소(CMK-3)를 KOH로 활성화 하여 실내공기 오염물질인 포름알데히드 흡착에 사용하였다. 활성화는 KOH 처리한 CMK-3를 $700^{\circ}C$의 반응기에서 질소분위기로 수행하였다. 활성화된 시료의 특성은 BET, XRD, XPS, FT-IR을 통해 분석하였다. 포름알데히드의 흡착능은 활성화에 의해 향상되었으며, 이는 활성화에 의해 메조기공 탄소의 산소작용기와 질소 작용기의 생성에 기인하는 것으로 판단된다.

• Carbon letters
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• 제8권1호
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• pp.17-24
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• 2007

Microporous carbons with narrow pore size distribution have been successfully synthesized by using hydrolyzed and calcined silica as templates and phenol formaldehyde (pf) resin as carbon precursor. Phenol formaldehyde-silica micro composites were prepared by solution route. Subsesequently, silica templates were removed by HF leaching. Resulting carbons were steam activated. The porous carbons were characterized by nitrogen adsorption-desorption isotherm, SEM, FTIR analysis, iodine adsorption, thermogravimetry analysis, etc. Adsorption isotherms show that the porous carbon prepared from calcined silica as templates are microporous with 88% pores of size <2 nm porosity and are of type I isotherm, while porous carbon prepared by using hydrolyzed silica are microporous with 89% microporosity, shows hysteresis loop at high relative pressure indicating the presence of some mesoporosity in samples. The microporosity in porous carbon materials has a bearing on the nature of silica templates used for pore formation.