• Korean Journal of Materials Research
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• v.32 no.5
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• pp.258-263
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• 2022

Porous ceramics have the advantages of low density, low thermal conductivity, and excellent mechanical properties. Among porous ceramic manufacturing methods, the replica template method allows the easy manufacturing of porous filters with the highest porosity and pores of the desired size, but it also has the disadvantage that the resulting filters have low mechanical strength. To overcome this shortcoming, mullite (3Al₂O₃·2SiO₂) whiskers, which have excellent thermal stability and high mechanical strength, were introduced in porous ceramic structure. The mullite whiskers were synthesized using a composition of Al₂O₃, flyash and MoO₃. The morphologies and crystal structures of the mullite whiskers with MoO₃ contents were investigated in detail. When the porous ceramic with mullite whiskers was fabricated using 20 wt% MoO₃ catalyst the most uniform microstructure was obtained, and the mullite whiskers showed the highest aspect ratio of 47.03. The porosity and compressive strength of the fabricated porous ceramic were 82.12 % and 0.83 MPa, respectively.

• Journal of the Korean GEO-environmental Society
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• v.17 no.4
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• pp.33-37
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• 2016

The hydration process of Controlled Low Strength Material (CLSM) used for backfill is the primary factor to determine the construction period. The objective of this study is to monitor the hydration process of CLSM using the Time Domain Reflectometry (TDR) and to establish the relationship between dielectric constant and compressive strength. The CLSM specimen is composed of cement, flyash, silt, sand, accelerator, and water. The material characteristics of the CLSM including flow, unit weight, compressive strength are investigated. To measure the dielectric constant of the CLSM during the curing time, TDR probe incorporated with a mold and a reflectometer are used. Experimental results show that the dielectric constant remains constant at early stage, and then decreases as the curing time increases. In addition, the dielectric constant is related to the compressive strength in inverse power function. This paper suggests that the TDR technique may be used as a non-destructive testing method in order to estimate the compressive strength of the CLSM mixture under construction.

• Journal of the Korea Concrete Institute
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• v.23 no.2
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• pp.145-150
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• 2011

Presently, mass concrete structures are being built in federal and private projects of civil infrastructures and building structures. The hydration heat of mass concrete structures is the most important factor in the quality of concrete matrix and construction period. Moreover, internal cracks caused by hydration heat degrades durability, water tightness, and strength of concrete. To reduce hydration heat, it is necessary to blend belite cement (${\beta}-C_2S$) with industrial by-products (i.e. granulated slag and fly ash). In this experiment, 14 levels of binary binders and 4 levels of ternary binders were used to understand the effect of different replacement ratio on hydration heat, strength and microstructure (i.e. SEM and XRD) of mortar. Cumulative hydration heat at 28 days for the binary and ternary binders was affected by replacement ratio of fly ash and/or granulated slag. As fly ash content increased, hydration heat decreased. As granulated slag content increased, reduction rate of the hydration heat was lower than when fly ash was used. Especially, the hydration heat of ternary binder blended with 40% flyash and 30% granulated slag showed about 50% of hydration heat from using belite cement (P). The study results showed that the temperature rise of concrete matrix can be decreased by using blended belite binders producing low hydration heat and reasonable strength.

• Journal of the Korean GEO-environmental Society
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• v.16 no.11
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• pp.5-11
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• 2015

The development of Controlled Low Strength Material (CLSM), which is a highly flowable material, has been performed for the application of backfill. The objective of this study is to compare the compressive strength and compressive wave velocity of CLSM according to the curing time. To investigate the characteristics of the CLSM consisting of sand, silt, water, flyash, and CSA cement, uniaxial compression test and flow test were carried out. For the measurement of compressional waves, a cell and a couple of transducers were used. The test results show that the compressive strength increases with the curing time, while the increment of compressive strength decreases with the curing time. In addition, the compressive wave velocity increases with the curing time, and the correlation between the compressive wave velocity and compressive strength is similar to exponential function. This study suggests that the correlation between the compressive wave velocity and compressive strength may be effectively used for the estimation of compressive strength of the CLSM at early curing time.

• Journal of the Korea Concrete Institute
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• v.19 no.5
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• pp.623-630
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• 2007

Grouting materials are used for the unification of superstructural and substructural body like bridge seat (shoe) or machinery pedestal and e.t.c by filling their intercalary voids. Accordingly, grouting materials have been developed and used mainly with products of high strength because those materials are constructed specially in a part receiving large or impact load. In this situation, the structural body constructed by grouting materials with high stiffness-centered (caused by high strength) products is apt to cause brittle failure when receiving over a limit stress and to cause cracks according to cumulative fatigue by continuous and cyclic load. In addition, grouting materials are apt to cause cracks by using too much rapid hardening agents that give rise to high heat of hydration to maintain high strength at early age. In this study, to overcome these problems, cement type grouting materials including powder of waste tire and resin as elastic materials which aim to be more stable construction and to be improvement of mother-body's unification are developed and endowed with properties of high toughness and high durability add to existing properties of high flowability, non-shrinkage and high strength. Besides, this study contribute to of for green construction materials for being possible recycling industrial waste like waste tire and flyash. On the whole, seven type mixing conditions are tested and investigated to choose the best mixing condition.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.8
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• pp.547-553
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• 2013

This paper investigates the effect of coal-fired fly ash on dry $CO_2$ sorbents as the supports and additives. For this purpose, various kinds of dry sorbent were manufactured by mixing fly-ash, the primary $CO_2$ absorption components (NaOH and CaO) and water with their different combination. Thereafter, their $CO_2$ absorption performance and the property were analyzed. As a result, variation of absorption efficiency and temperature as well as $CO_2$ desorption of the sorbents are confirmed, which may be primarily ascribed to fly-ash addition to the sorbents. Particularly, fly-ash effect is strongly measured in the sorbent manufactured by mixing all four components (named WNCF sorbents). Absorption efficiency of WNCF sorbents at $550^{\circ}C$ is 35.6% higher than that of flyash free sorbent and desorption is solely observed in WNCF sorbents. Fly-ash in WNCF sorbents leads to increase the dispersity of $CO_2$ absorption components and decrease their particle size in the sorbents. In addition, fly-ash is used as the supports and pozzolanic reaction is hindered by NaOH in WNCF sorbent. Furthermore, $CO_2$ desorption from the sorbents may be due to fly-ash. The interaction between fly-ash and $CO_2$ absorption components substantially attenuate the strength between captured $CO_2$ in CaO and NaOH.

• Journal of the Korean GEO-environmental Society
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• v.14 no.10
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• pp.49-57
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• 2013

Recently, recycling of the industrial by-products has been an important issue of the Yeosu bay, where large industrial complex is located. Major industrial by-products which are produced from Yeosu industrial complex area are phosphogypsum and flyash, which are about 82% and 10% of the 1.6 million tons industrial by-products. Moreover since the Yeosu industrial complex is located at seaside, phosphogypsum has been pointed as cause of serious environmental contaminant from the regional society. Therefore recycling study can't be delayed anymore. In this paper, artificial aggregate was manufactured by non-sintering process from industrial byproducts - e.g., phosphogypsum and slag - as a geotechnical drainage material. To show the feasibility of the artificial aggregate as a geotechnical drainage material, geotechnical experiments including particle size analysis, permeability test, and large scale direct shear test were carried out. Test results show that the permeability of the artificial aggregates range from $6.94{\times}10^{-1}cm/sec$ to $8.86{\times}10^{-1}cm/sec$, which is much larger value than those are required for the drainage material from the construction specification in Korea, and the friction angle of the artificial aggregate is as large as that of sand in water immersion conditions. From the test results, it was concluded that artificial aggregate made from industrial by-products can be used successfully as a geotechnical drainage material.

• Journal of the Korean Geosynthetics Society
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• v.20 no.1
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• pp.35-44
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• 2021

This research studies the stabilization method for improved soil sloped through the on-site application of Paper Flyash ground stabilizers. The target strength required for improved soil is 500 kPa, and the compressive strength for the slope surface needs to be less than 1,000 kPa after the improvement in order to plant vegetation. To meet this condition, we mixed soil from the site and the ground stabilization material, which is the main material for surface improvement material, performed mixing design and conducted various tests including strength test, permeability test and plantation test. After analyzing the results of the compression test on improved soil slope, we proposed soil constants for the improved soil. In order to evaluate the applicability of the improved soil on the slope, the site construction was carried out on the collapsed slope and the reinforcement evaluation of the surface of the improvement soil was conducted. The stability was not secured before the reinforcement, but the test shows after the reinforcement with improved soil, the safety rate is secured up to 48 hours during the raining period. In addition, the compressive strength of the improved soil at the site was secured at more than 200 kPa adhesion as planned, and the soil hardness test result was also found to be within the specified value of 18-23 mm, which increased the resistance to rainfall and ability to grow plant on the surface for improved soil.