• Journal of The Korean Society of Agricultural Engineers
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• v.46 no.3
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• pp.57-63
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• 2004

This study was performed to evaluate the engineering properties of cement mortar brick with loess and fly ash. The unit weight was in the range of $2,068{\sim}2,137\;kgf/m^{3}$ and $1,899{\sim}2,045\;kgf/m^{3}$ in water and dry curing, respectively It was decreased with increasing the loess content. The absorption ratio was in the range of $5.2{\sim}13.1%$ and $8.5{\sim}13.2%$ in water and dry curing, respectively. The compressive strength was decreased with increasing the loess content. The compressive strength of the 193 $kgf/m^{2}$ in water and 188 $kgf/m^{2}$ in dry curing at the curing age 28 days of the binder volume ratio 35% was exceeded in 163 $kgf/m^{2}$ of standard compressive strength about cement bricks. The carbonation depth was in the range of $0.9{\sim}1.4$ mm, $1.2{\sim}3.6$ mm, $1.4{\sim}6.7$ mm and $2.4{\sim}12.5$ mm in dry curing of curing age 14days, 28days, 90days and 360days, respectively.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.580-583
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• 2004

Due to the tendency of increase in demolished-concrete produced by alteration and deterioration of concrete structures, recycling of those demolished-concrete is necessary to solve the exhaustion of natural aggregate, in order to save resources and protect environment. In this an experimental study herein, the Chlorine-ion and Carbonation resistance of the recycled aggregate concrete was investigated. Coarse aggregate was replaced with $100\%$ of the recycled aggregate and cement and fine recycled aggregate was replaced with various amount. It was shown that the concrete can obtain resistance of chlorine-ion, when fly ash replaced with up to $30\%$ of cement.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.1
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• pp.61-68
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• 2008

A new cementitious material has been developed, called alkali-activated fly ash cement(AAFC), which is used to produce AAFC-concrete for construction. The effect of acid attack, sodium chloride solution, carbonation, freeze-thaw cycling, and SEM, XRD analysis of the AAFC-concrete prepared using alkali-activated fly ash cement and OPC-concrete were experimentally investigated. It was found that the acid resistance of AAFC-concrete(35 MPa) prepared from alkali-activated fly ash at 85$^{\circ}C$ for 24 hrs is far better than OPC-concrete(35 MPa). Also, the AAFC-concrete(35 MPa) had a similar resistance of OPC-concrete(35 MPa) to attack, such as sodium chloride solution, carbonation and freeze-thaw cycling.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.122-131
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• 2001

Pakistan being the 6$^{th}$ largest sugar producer has over 75 sugar mills with annual production capacity of about 2.4 million tons during 1996-97. The contribution of Sindh with 27 sugar mills is recorded over 50% of the total sugar production. The majority of the mills in Pakistan use the Defecation-Remelt-Phosphitation (DRP; 24 mills), Defecation-Remelt-Carbonation (DRC; 21 mills) and Defecation-Remelt Carbonation and Sulphitation (DRCS; 11 mills) process. Seven of the 75 sugar mills in Pakistan also produce industrial alcohol from molasses, a by- product of sugar manufacturing process. These sugar industries also produce fly ash, which have been found to contain unburned carbon and reach as far as four-kilo meter area with the wind direction, threatening the community health of people living around, besides posing other aesthetic problems. The untreated wastewater, in many cases, finds its way to open surface drains causing serious threat to livestock, flora and fauna. One study showed that fly ash emitted from the chimneys contain particle size ranging from 38 ${\mu}{\textrm}{m}$ to 1000 ${\mu}{\textrm}{m}$. About 50 per cent of each fly ash samples were above 300 ${\mu}{\textrm}{m}$ in size and were mostly unburned Carbon particles, which produced 85% weight loss on burning in air atmosphere at 1000${\mu}{\textrm}{m}$. This fly ash (mostly carbon) was the main cause of many health and aesthetic problems in the sugar mill vicinity. The environmental challenge for the local sugar mills is associated with liquid waste gaseous emission and solid waste. This paper discusses various waste recycling technologies and practices in sugar industries of Pakistan. The application of EM technology and Biogas technology has proved very successful in reusing the sugar industry wastewater and mud, which otherwise were going waste.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.152-160
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• 2013

The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.271-273
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• 2012

This paper is to investigate the effect of waste cooking oil(WCO) on carbonation resistance of high volume fly ash and blast furnace slag concrete. WCO and paint were applied for carbonation resistance materials. As expected, the application of WCO to the concrete help it reduce carbonation depth remarkably, regardless of mixture types. This may be due to the fact that WCO makes the capillary pore block by activating saponification. It is found that the degree of carbonation reduce due to WCO is much higher than the case by Paint.

• Journal of the Korea Concrete Institute
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• v.15 no.6
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• pp.829-839
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• 2003

Recently, the corrosion of reinforced concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation but the future studies for combined environment will assure the precise assessment.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.18-23
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• 2016

The development of a binder system with a lower carbon footprint as an alternative to Portland cement has been intensely researched. In the present study, alkali-activated fly ash exposed to carbon dioxide at an early age was characterized in compressive strength tests and by MIP, XRD and FT-IR analyses. The compressive strength of carbonated specimens experienced a dramatic increase in comparison to uncarbonated specimens. The microstructural densification of the carbonated specimens was evidenced by MIP. The XRD pattern showed peaks assigned to nahcolite, indicating that the pH was lower in the carbonated specimens. Under the carbon dioxide-rich environment, the aluminosilicate gel reached a more Si-rich state, which improved the mechanical properties of the alkali-activated fly ash.

• Resources Recycling
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• v.24 no.1
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• pp.28-34
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• 2015

Generally, when using copper slag mixed into the concrete, due to higher weight of copper slag, a reduction in the compressive strength and durability of the hardened concrete to increased bleeding is caused. In this study, hence copper slag, a kind of by-product was used as an alternative to the fine aggregate, it was carried out in combination with the use of fly ash in eliminating disadvantage and recycling aspects. As a result of this study, the mixing of fly ash is decreased in the 50% of bleeding, 5% of drying shrinkage, 30% of carbonation test and improvement of 10% of compressive strength than that of copper slag only at most.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.11a
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• pp.83-84
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• 2018

As the concentration of greenhouse gases in the atmosphere increases, the reduction of CO2 is gaining worldwide attention. In the construction industry, cement replacement materials such as fly ash and blast furnace slag were investigated to reduce CO2 emissions in cement production process. Precast concrete is used in the field after manufacturing in the factory in the form of pipes and bricks because of shortening construction period and cutting construction cost. According to the results of previous research, it is known that early CO2 curing in concrete using OPC or fly ash has an initial strength enhancement effect and can be used for precast concrete production. Therefore, the purpose of this study is to evaluate the strength improvement effect by confirming the initial strength improvement effect when blast furnace slag is mixed.