• Journal of the Korean Society of Safety
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• v.22 no.3 s.81
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• pp.57-64
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• 2007

Recently, the corrosion of concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation and freezing-thawing action to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The small reduction of relative dynamic elastic modulus induced from freezing-thawing increases the chloride ion penetration depths much. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation or freezing-thawing but the future studies for combined environment will assure the precise assessment.

• Journal of the Korea institute for structural maintenance and inspection
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• v.7 no.1
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• pp.139-145
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• 2003

Ternary blended concrete, which contains both fly ash and granulated blast furnace slag, has an initial cost effective and is environment friendly. Furthermore, it has a lot of technical advantages such as the improvement of long term compressive strength, high workability, and the reduction of hydration heat. However, as the use and study on the performance of ternary blended concrete is limited, it is worthwhile studying the actual performance of this technology. This study examined the durability performance of ternary blended concrete, compared to binary blended concrete and ordinary portland concrete. It led to the conclusion that ternary blended concrete is very suitable for submerged members under marine environment. However, it should be noticed that ternary blended concrete becomes weak on carbonation, when it is situated on combined deterioration environment of carbonation and chloride. Therefore, the curing duration of ternary blended concrete should be prolonged in order to enhance the resistance of carbonation.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.39-42
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• 2002

Cloride attack of concrete is one of the important causes of corrosion of reinforcing steel in concrete with carbonation and frost damage. In this paper, the effect of fly-ash on the cloride attack were investigated by varying water binder ratio and fly-ash contents according to the chloride ion penetrationa test. (ASTM C 1202-94) The principal conclusions from this research were as follows: 1) The compressive strength of concrete at large ages, depends more on $C_2$S contents of base cement than fly-ash contents. 2) On the other hand, the chloride ion penetration of concrete at large ages, principally depends on fly-ash contents and the influence of type of base cement is insignificant.

• Journal of Energy Engineering
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• v.26 no.4
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• pp.74-83
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• 2017

Coal-fired power plants supply roughly 50 percent of the nation's electricity but produce a disproportionate share of electric utility-related air pollution. Coal combustion technology can facilitate volume reduction of up to 90%, with the inorganic contaminants being captured in furnace bottom ash and fly ash residues. These disposal coal ash residues are however governed by the potential release of constituent contaminants into the environment. Accelerated carbonation process has been shown to have a potential for improving the chemical stability and leaching behavior of bottom ash residues. The aim of this work was to quantify the volume of $CO_2$ that could be sequestrated with a view to reducing greenhouse gas emissions and stabilize the contaminated heavy metals from bottom ash samples. In this study, we used PC boiler bottom ash, Kanvera reactor (KR) slag and calcined waste lime for measuring chemical analysis and heavy metals leaching tests were performed and also the formation of calcite resulting from accelerated carbonation process was investigated by thermo gravimetric and differential thermal analysis (TG/DTA).

• Journal of the Korea Institute of Building Construction
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• v.3 no.3
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• pp.127-133
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• 2003

Carbonation and drying shrinkage are very important properties of concrete, that can cause concrete to lower its capacity and spall. But the research on them in high strength concrete is very poor. In this study, to estimate influences of W/B, the kind of admixture, the replacement ratio of admixture, fineness of blast furnace and etc. on drying shrinkage and carbonation, we make experiment with 3 levels(28, 35, 55%) of W/B, 3 kinds(blast-furnace slag, fly-ash, silica-fume) of admixture, 3 levels of the replacement ratio, 3 levels(4000, 6000, 8000cm2/g) of fineness of blast-furnace slag and 2 kinds of curing condition. As the results, compressive strength of concrete was decreased, as W/C was increased and the replacement ratio of admixture was increased. Drying shrinkage was increased, as W/B was higher, the replacement ratio of admixture was increased and fineness of blast-furnace slag was decreased. And carbonation was increased, as W/B ratio was higher, the replacement ratio of admixture was increased.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.3
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• pp.198-205
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• 2014

The present paper investigates the leaching property of coal fly ash (FA) using distilled water as solvent and its performance of mineral carbonation. The highest leaching efficiency is obtained at 100 min after leaching begins and the overall leaching efficiencies of Ca and Na via five consecutive leachings were calculated to be 25.37% and 7.40%, respectively. In addition, because $Ca(OH)_2$ produced during the leaching reacts with $SiO_2$ which is the major component of FA, the Pozzolanic reaction may occur and thus reduces leaching efficiency. Total carbonation capacity of FA by absorbing $CO_2$ into FA leachates is 6.08 mg $CO_2/g$ FA and the contribution of alkali substances such as Ca, Na, Mg and K to this value is calculated to be 5.19 mg $CO_2/g$ FA. Carbonation efficiencies of Ca and Na based on leachates are 85.62% and 77.70%, respectively. On the other hand, the ratios of Ca and Na in raw FA to participate in carbonation are calculated to be 9.04% and 5.26%, respectively.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.793-801
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• 2005

This study investigates fundamental properties of recycled aggregate concrete which incorporated 100% recycled coarse aggregate and various amount of recycled fine aggregate. In addition, for the purpose of the improvement of long term strength and durability, a part of cement was replaced with fly ash. Compressive strength and resistance to chloride ion penetration and carbonation were investigated. When the coarse aggregate was completely replaced with the recycled the replacement ratio of the fine aggregate with the recycled was recommended to be limited below 60% in the consideration of strength. The strength of the steam-cured specimen was very comparable to the wet-cured at 28 days. As fly ash content increased the resistance to chloride ion penetration was increased. The chloride ion penetrability based on the charge passed was found to be low at 21 days and very low at 56 days, respectively. Carbonation depth and carbonation velocity coefficient increased as the fly ash content increased and the relationship between the carbonation depth and recycled fine aggregate replacement ratio was not clear. Up to 28days, however, the measured carbonation depth was mostly less than 10mm which could be considered as low.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.339-344
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• 1997

During recent years the durability of concrete structures has attracted considerable interest in concrete practice, material research and long-term deformation. To preserve the brittleness of concrete as well as energy absorption and impact resistance, amount of fiber usage has greatly increased year to year in the field of public works. When fly ash, fine powder, mixed into concrete, it condensed the void of concrete structure. Expecially, there's a great effect for strength improvement of concrete by initial pozzolanic reactions. Pozzolan reaction, between cement particle and fly ash, can elaborate the micro structure of matrix. So it was able to improve the effect of fiber reinforced by increased adhesion between cement paste and steel fiber. And so, in this paper, we dealt SFRC for the purpose of efficiently using of industrial by-products and its economical manufacturing. Also we performed the test for durability such as chemical resistance, freeze-thaw resistance and accelerated carbonation of SFRC using fly ash.

• Journal of the Society of Disaster Information
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• v.10 no.4
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• pp.566-571
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• 2014

Recently, with concentrated social and engineering interests on durability, diversified subsequent researches have been progressed. The Chloride-induced corrosion, carbonation, freeze-thaw etc, deterioration factors of concrete act to concrete not privately but complexly, Fly ash is most frequently used admixture which is using a reduction method of deterioration. And the fly ash effects on improvement of durability with enhancement of fluidity, decrease of crack with reduction of hydration heat, promotion of long-age strength and have a economic advantage which replaces cement as a binding material. But, fly ash have different qualities and occasionally reduce the durability and strength by adhesion of AE admixture with unburned carbon powder etc. In this study, the experiments will take about various replacement ratio of fly ash concrete, and will analyze, consider the results, after these will verify applicability and validity as admixture and binding material.

• Journal of the Korea Institute of Building Construction
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• v.8 no.4
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• pp.79-85
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• 2008

The purpose of this study is to evaluate the mix design of pH reducing cement concrete which can be used for environment-friendly concrete. Cement pastes and concretes are prepared with water-binder ratios and various admixtures such as blast-furnace slag, fly ash and recycled cement, and tested for compressive strength and pH. pH is measured through pore solution expressed from hydrated cement paste by special apparatus. From the test results, regardless of water-binder ratio, The pH of expressed pore solution from hydrated cement paste which is made of ordinary portland cement with blast-furnace slag, fly ash is decreased with increasing of admixtures content, and compressive strength is also slightly improved. The compressive strength of cement paste made of recycled cement which is burnt at $1000^{\circ}C$, for 2 hours is considerably increased compared with that of none-burnt recycled cement due to restoration of hydraulic property, but pH is a little higher. Porous concrete with ordinary portland cement has high pH in the range of 12.22 to 12.59, however, that is reduced to the range of 8.95 to 10.39 by carbonation at the surface of porous concrete. The pH reduction of porous concrete is possible by various admixture addition, however their degrees are very slight. Therefore, to reduce the pH considerably, carbonation method of porous concrete is better in pH reduction methods for plant survival condition of pH of 9.0 or less. In this study, it is apparent that pH for the environment-friendly porous concrete products used in the construction field can be suppressed by this carbonation method and various admixtures addition.