• Ocean and Polar Research
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• v.31 no.3
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• pp.247-255
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• 2009

We measured phosphate benthic fluxes and conducted phosphate adsorption experiments in order to find out the effects of adsorption on phosphate benthic fluxes in the intertidal sediments of Keunso Bay during summer and winter. Organic carbon contents showed little variation with season at St. S1, but noticeable changes were observed at St. S2, which were three times higher in winter than in summer. The higher organic carbon contents in winter resulted from the bloom of benthic algae in surface sediments. Pore water phosphate concentrations were much higher in summer than in winter. The higher phosphate concentration in summer was probably due to the faster remineralization rate of organic matter in summer. At St. S1, benthic fluxes of phosphate showed a negative value in summer and a positive value in winter. However, St. S2 had a negative benthic flux both in summer and winter. The negative benthic flux was ascribed to the phosphate adsorption on iron oxides in surface sediments. The equilibrium concentrations of phosphate obtained from the adsorption experiment were three times higher at St. S1 than at St. S2. The relatively high adsorption coefficient and low equilibrium concentration indicated that phosphate was strongly adsorbed on the surface sediments of Keunso Bay. The strong adsorption affinity significantly reduced benthic fluxes of phosphate in the intertidal sediments.

• Asian Journal of Atmospheric Environment
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• v.10 no.2
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• pp.57-66
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• 2016

Wet deposition fluxes of ions at a coastal site in southwestern Japan in the period 1996-2003 were investigated to quantify the respective contributions of cyclone-, stationary front- and typhoon-associated rains. On average, the deposition fluxes of terrigenous-origin ions, nss-$SO_4{^{2-}}$, $NO_3{^-}$, $NH_4{^+}$ and nss-$Ca^{2+}$ were $37.6{\pm}7.3$, $16.3{\pm}4.2$, $19.0{\pm}3.4$ and $9.6{\pm}4.8meq\;m^{-2}yr^{-1}$, and those of $Na^+$ and $Cl^-$, the major ions in sea water, were $97.0{\pm}38.2$ and $115.2{\pm}48.2meq\;m^{-2}yr^{-1}$, respectively. Cyclone-associated rain constituted more than 50% of the fluxes of the terrigenous ions in almost all years. Stationary front-associated rain also contributed significantly, although the contribution was lower than the contribution by Cyclone-associated rain in almost all years. In particular, the wet deposition flux of nitrogen compounds of $NO_3{^-}$ and $NH_4{^+}$, which are important nutrients for micro-bioactivities in sea surface water, was dominated by cyclone-associated rain. Due to the extreme abundance of $Na^+$ and $Cl^-$ in the rainwater of typhoons, the fluxes of $Na^+$ and $Cl^-$ were contributed substantially by typhoons in years with typhoons' passage although cyclones were still the largest contributor to the fluxes. These results indicate the dominance of cyclones in the wet deposition to the East China Sea areas and the necessity to take rain types into account for a more accurate elucidation of the temporal and spatial variation of the wet deposition.

• Ocean and Polar Research
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• v.33 no.spc3
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• pp.385-395
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• 2011

Time-series sediment traps were deployed at 1,000 m water depth of the northwestern subtropical Pacific from July 2009 to June 2010, with the aim of understanding temporal and spatial variations of sinking-particle fluxes. The opening and closing of the traps was synchronized at 18-day periods for 20 events. Total mass fluxes showed distinct seasonal variations with high values for the summer-fall seasons and relatively low values for winter-spring. This seasonal variation at two stations was characterized by a distinct difference in $CaCO_3$ fluxes between the two seasons. The enhanced $CaCO_3$ flux in the summer - fall seasons might be attributed to an increased planktonic foraminiferal flux. Total mass flux at FM10 station was nearly 50% higher than that at FM1 station. The difference in $CaCO_3$ fluxes between two stations contributed nearly 70% of the difference of total mass fluxes. The $CaCO_3$ flux was a major component controlling temporal and spatial variation of sinking - particle fluxes in the western subtropical Pacific Ocean.

• Journal of Environmental Science International
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• v.23 no.6
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• pp.1131-1142
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• 2014

In this study, the variations of the carbon dioxide fluxes were investigated with soil temperatures in the grassplot and seasonal variations of carbon dioxide concentrations and fluxes were analysed. Soil temperatures, carbon dioxide concentrations and fluxes were measured on the grassplot in Pukyong National University. Field measurements were carried out 25 times from March in 2010 to March in 2011 with nine points on the grassplot. Seasonal variations of carbon dioxide concentrations and fluxes showed an inverse relation. In summer, carbon dioxide concentrations are lower and carbon dioxide fluxes are higher. In winter, carbon dioxide concentrations are higher and carbon dioxide fluxes are lower. On the grassplot, carbon dioxide emission rate increase when the soil temperature is more than $20^{\circ}C$ and the emission rate decrease when the soil temperatures are less than $10^{\circ}C$. When the accumulated rainfall for five days before measurement day is 20~100 mm, it is showed that the more rainfall, the more carbon dioxide emissions. Carbon dioxide emission rate from the grassplot to the upper atmosphere was increased or decreased by the factors such as soil temperature, growth and wither of grass and rainfall. The results of this study showed that the emission of carbon dioxide in the grassplot is dominantly controlled by seasonal factors (especially soil temperature and rainfall).

• Atmosphere
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• v.24 no.2
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• pp.197-206
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• 2014

The effects of different averaging operators and atmospheric stability on the turbulent fluxes are investigated using the vertical velocity, air temperature, carbon dioxide concentration, and absolute humidity data measured at 10 Hz by a 3-dimensional sonic anemometer and an open-path $CO_2/H_2O$ infrared gas analyzer installed at a height of 18.5 m on the rooftop of the Jungnang KT building located at a typical residential area in Seoul, Korea. For this purpose, 7 different averaging operators including block average, linear regression, and moving averages during 100 s, 300 s, 600 s, 900 s, and 1800 s are considered and the data quality control procedure such as physical limit check and spike removal is also applied. It is found that as the averaging interval becomes shorter, turbulent fluxes computed by the moving average become smaller and the ratios of turbulent fluxes computed by the 100 s moving average to the fluxes by the 1800 s moving average under unstable stability are smaller than those under neutral stability. The turbulent fluxes computed by the linear regression are 85~92% of those computed by the 1800 s moving average and nearly the same as those computed by 900 s moving average, implying that the adequate selection of an averaging operator and its interval will be very important to estimate more accurate turbulent fluxes at urban area.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.17 no.2
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• pp.120-129
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• 2012

We investigated seasonal variation of sediment-water oxygen and inorganic nitrogen fluxes, and denitrification at tidal flat sediments located in the Nakdong River Estuary from July 2005 to September 2006. Net oxygen fluxes, measured with sediment incubations at in situ temperature, varied from -37.0 to $0.5mmol\;O_2\;m^{-2}\;d^{-1}$. Oxygen fluxes into the sediments from the overlying water increased due to the increased water temperature. Denitrification rate ($4{\sim}2732{\mu}mol\;N\;m^{-2}\;d^{-1}$) in this study was higher compared to the other Korean coast measured with the same method. Denitrification showed the same seasonal variation as oxygen fluxes. Denitrification rate based on $^{15}N$-nitrate showed a strong correlation with nitrate flux into the sediments from the overlying water. Denitrification via "water column supplied nitrate ($D_w$)", calculated from Isotope pairing technique, also correlated well with nitrate flux into the sediments. Nitrate from water column seems to account for seasonal variation of denitrification in Nakdong River Estuary. To understand general patterns and trends of biogeochemical processes of sediments in the Nakdong River Estuary, we categorized biogeochemical fluxes measured in this study according to direction and sizes of fluxes. Type 1(high oxygen and inorganic nitrogen fluxes into the sediments and high denitrification) occurred in summer, whereas Type 2(low oxygen and inorganic nitrogen fluxes into the sediments and low denitrification) occurred in rest of the season. Intertidal flat sediments seem to react sensitively to influence of freshwater from the Nakdong River.

• Proceedings of the KSRS Conference
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• 2005.10a
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• pp.415-417
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• 2005

In order to retrieve the latent and sensible heat fluxes, high-resolution airborne imageries with visible, near infrared, and thermal infrared bands and ground-base meteorology measurements are utilized in this paper. The retrieval scheme is based on the balance of surface energy budget and momentum equations. There are three basic surface parameters including surface albedo $(\alpha)$, normalized difference vegetation index (NOVI) and surface kinetic temperature (TO). Lowtran 7 code is used to correct the atmosphere effect. The imageries were taken on 28 April and 5 May 2003. From the scattering plot of data set, we observed the extreme dry and wet pixels to derive the fitting of dry and wet controlled lines, respectively. Then the sensible heat and latent heat fluxes are derived from through a partitioning factor A. The retrieved latent and sensible heat fluxes are compared with in situ measurements, including eddy correlation and porometer measurements. It is shown that the retrieved fluxes from our scheme match with the measurements better than those derived from the S-SEBI model.

• Proceedings of the Korean Environmental Health Society Conference
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• 2003.06a
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• pp.76-85
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• 2003

Mass and elemental dry deposition fluxes and ambient particle size distributions were measured using dry deposition plates and a cascade impactor, from March to November 1998 in Seoul, Korea. During the spring sampling period several yellow sand events characterized by long range transport from China and Mongolia impacted the area. During these events the mass fluxes were statistically the same as during springtime non-yellow-sand events. However, most elemental fluxes were higher. In general, the flux ratios of both crustal (Al, Ca, Mn) and anthropogenic elements (Ni, Pb) to total mass measured during the daytime yellow-sand events were substantially higher than those measured in spring daytime during non-yellow-sand time periods. During all seasons the average measured daytime fluxes were about two times higher than at nighttime. The flux of primarily anthropogenic metals (Cu, Ni, Pb, Zn) and Mn was on average one to two orders of magnitude lower than the flux of the crustal metals Al and Ca. As is typically found two modes, fine (0.1∼l.0 $\mu\textrm{m}$) and coarse (1.0∼10.0 $\mu\textrm{m}$) were present in the measured size distributions (<10 $\mu\textrm{m}$). The particles in the coarse mode constitute a major portion of the measured mass size distribution during the yellow-sand events possibly due to the long-range transport of those particles from China.

• Particle and aerosol research
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• v.5 no.4
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• pp.179-188
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• 2009

The dry deposition fluxes of particulate polychlorinated biphenyls (PCBs) were measured along with their mass size distributions at Seoul and Incheon in fall in 1999. The dry deposition fluxes of PCBs were in the range of $16.7{\sim}62.2ng/m^2/day$. The ambient concentrations of particulate PCBs were in the range of 0.07 to $0.20ng/m^3$. Generally, the mass size distribution of particulate PCBs shows bi-modal distribution. The mass fraction of PCBs in the fine particle fraction ($D_p<2.1 {\mu}m$) was over than 55% of the total PCBs concentrations. It was found that Seoul and Incheon were not the major source of PCBs emissions in Korea. Based on the comparison with the measurement data in summer, 1999, it is likely that both the dry deposition fluxes and ambient particulate PCBs concentrations were not site-specific.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.114-116
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• 2005

Natural attenuation has been actively studied and often selected as final clean-up process in remediation of contaminated ground-water and soil for the last decade. Accordingly, understanding of natural processes affecting the fate and transport of contaminants in the subsurface becomes important for a success of implementation of the natural remediation strategy, Contaminant advection and diffusion processes in the unsaturated zone are naturally related to environmental changes in the atmosphere. The atmospheric pressure changes affecting the transport of contaminants in the subsurface are investigated in this study. Moisture content, trichloroethylene (TCE) concentration, temperature, and pressure variations in the subsurface were measured for the July, August, November, and December 2001 at Picatinny Arsenal, New Jersey. These data were used for a one-phase flow and one-component transport model in simulating the soil-gas flow and accordingly the TCE transport in the subsurface in accordance with the atmosphere pressure variations at the surface. The soil-gas velocities during the sampling periods varied with a magnitude of $10^{-6}\;to\;10^{-7}\;m\;s^{-1}$ at land surface. The TCE advection fluxes at land surface were several orders of magnitude smaller than the TCE diffusion fluxes. A sensitivy analysis indicated that advection fluxes were more sensitive to changes in geo-environmental conditions compared to diffusion fluxes. Of all the parameters investigated in this study, moisture content has the most significant effect on TCE advection and diffusion fluxes.