• Title/Summary/Keyword: Fluorescent properties

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Synthesis, Crystal Structures and Properties of Two 3D CdII and ZnII Complexes with a 3-Fold Interpenetrating Feature

  • Lin, Hongyan;Sui, Fangfang;Liu, Peng;Wang, Xiuli;Liu, Guocheng
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2138-2142
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    • 2013
  • Two new 3D coordination complexes [Cd(3-bpcd)(pht)] (1) and [Zn(3-bpcd)(pht)] (2) [3-bpcd = N,N'-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, $H_2pht$ = phthalic acid] have been hydrothermally synthesized. X-ray diffraction analysis reveals that the complexes 1 and 2 represent a 4-connected diamondoid topology with a 3-fold interpenetrating feature. Moreover, the fluorescent properties of complexes 1 and 2 are studied.

A photoswitch from conjugative aromatic polymers

  • Kwon, Tae-Chang;Kim, Yong-Jung;Kim, Yu-Na;Lee, Hyo-Jin;Rameshbabu Krishnamurthy;Sarwade Bhimrao D.;Kim, Eun-Kyoung
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.174-174
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    • 2006
  • By condensing two different functional monomers, highly fluorescent aromatic polymers were prepared to produce a conjugated- conjugated spacer-type copolymer or conjugated-non-conjugated spacer-type copolymer. As synthesized polymers were soluble in an organic solvent and showed significantly enhanced optical properties compared to its monomer. Variation in the monomer composition afforded polymers having multifunctionaility such as photochromic-fluorescent polymers. Transparent thin films of the polymer as a solid medium were prepared using spin coating method and fabricated as a photoswitch, which showed photo-induced conductivity switching properties depending on the core monomeric unit in the polymers.

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A Study of The Novel External Electrode Fluorescent Lamp For High Optical Efficiency

  • Yoon, Ji-Su;Jung, Kyu-Bong;Kim, Hyung-Dong;Kang, Jae-Kyung;Kim, Jae-Bum;Jeong, Byoung-Koan;Ahn, Byung-Chul;Yeo, Sang-Deog
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1412-1414
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    • 2006
  • We study on the Electro Optical Properties of the EEFL (External Electrode Fluorescent Lamp) Backlight system is based on the lamp type characteristics and diameter of the lamp tube under the equal manufacturing of the lamps. In this contribution, through the analysis of the different lamp type and diameter of the lamp tube gain the effective luminance and reduce the lamp voltage from aspect in the electro optical properties with EEFL and LCD backlight system.

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Properties of Xe plasma flat fluorescent lamp by screen printing

  • Lee, Yang-Kyu;Kang, Jong-Hyun;Yoon, Seung-Il;Kim, Tae-Kwon;Bae, Sung-Jo;Oh, Myung-Hoon;Lee, Dong-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1386-1389
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    • 2006
  • In this study, a plasma flat fluorescent lamp having a new structure was fabricated by screen printing technique. Coplanar types of silver electrodes with a dielectric layer were screen-printed on a rear glass plate, and then fired at $550^{\circ}C$ and $580^{\circ}C$, respectively. Phosphor was spin-coated on the dielectric layer with firing at $490^{\circ}C$. Several types of lamps were designed and its properties wee investigated with electrode shape, gas pressure, etc.

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Molecular Design of New Organic Electroluminescence Materials: DCM Derivatives

  • Seong, See-Yearl;Park, Sung-Soo;Seo, Jeong-In;No, Kyoung-Tai;Hong, Jong-In;Park, Su-Jin;Choi, Seung-Hoon;Lee, Han-Yong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.178-180
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    • 2003
  • We performed semiempirical (AMl and ZINDO) and ab initio (HF and DFT) calculations, to investigate molecular structures and optical properties of DCM and its derivatives. DCM and its derivatives are used as a red fluorescent dopant of the organic electroluminescent host materials, $Alq_3$. We have studied the relationship between the molecular structure and the optical properties of these molecules for the improvement of EL efficiencies. Wavelength at the absorption maximum was found to be red-shifted when the molecule is substituted with both strong electron donating and withdrawing functional groups. A new red fluorescent dye was predicted by QSPR study based on calculations and experimental data.

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Synthesis and Optical Properties of Ca1-xSrxS:Mn Phosphors (Ca1-xSrxS:Mn 형광체의 합성과 광 특성)

  • Sung, Hye-Jin;Huh, Young-Duk
    • Korean Journal of Materials Research
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    • v.17 no.3
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    • pp.137-141
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    • 2007
  • A series of $Ca_{1-x}Sr_{x}S:Mn$ phosphors were synthesized by solid-state reactions. The emission peaks of $Ca_{1-x}Sr_{x}S:Mn$ is blue shifted front 605 to 570 nm with increasing Sr content. Since $Ca_{1-x}Sr_{x}S:Mn$. Mn phosphors exhibit strong absorption in region of 254 nm, the emission wavelength of a fluorescent lamp, these phosphors can be used as wavelength tunable emitting phosphors from reddish orange to yellow. We investigated the optical and structural properties of $Ca_{1-x}Sr_{x}S:Mn$ phosphors.

Study on Analysis of Characteristics of Illuminance and Luminance Distribution of LED Luminaires (LED 조명기구의 조도.휘도분포 특성 분석에 관한 연구)

  • Lee, Jin-Sook;Kim, Won-Do;Kim, Byoung-Soo;Han, Won-Tak
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.9
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    • pp.1-7
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    • 2008
  • This study is intended to compare physical properties of fluorescent luminaires with ones of LED luminaires so as to analyze fundamental characteristics of LED luminaires. For this, a comparative analysis of uniformity ratio of illuminance and luminance distribution of these two luminaires was made, and materials for applying LED luminaires to interior construction space were prepared. This study was carried out in four stages. First, a theoretical review on LED illumination light source was made compared with the existing luminaires. Second, a mock-up to control experimental variables to meet the objective of this study was manufactured. Third uniformity ratio of illuminance and luminance distribution of each luminaire were measured by using the mock-up. Fourth, a comparative analysis of uniformity ratio of illuminance and characteristics of luminance distribution of the existing fluorescent luminaires and LED ones was made. As a result of the study, the uniformity ratio of illuminance of LED luminaires, 0.559, was higher than one of the existing fluorescent luminaires, 0.522. Namely, it was shown that illuminance distribution of LED luminaires was uniform and global diffuse was good. As a result of measuring luminance distribution, it was found that luminance distribution of LED luminaires was more uniform than one of the existing fluorescent luminaires. The maximum luminance of fluorescent luminaires and LED luminaires over the wall was $180.6[cd/m^2]$ and $155.26[cd/m^2]$ respectively. Namely, the maximum luminance of fluorescent luminaires was higher than one of LED luminaires. The average luminance of fluorescent luminaires and LED luminaires was $44.32[cd/m^2]$ and $58.65[cd/m^2]$. Like this, the average luminance of LED luminaires was higher than one of fluorescent luminaires. Considering these results, it's thought that LED luminaires can give a person in the room a more comfortable working environment than fluorescent luminaires.

Application of Xanthene Dyes with Fluorescein-Derived Structures for Production of Fluorescent Pigments, and The Analysis of The Optical Properties of The Pigments (플루오레세인 유도체를 갖는 잔틴계 염료의 형광안료 제조로의 응용 및 제조된 안료의 광학 특성 분석)

  • Bae, Su-whan
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.3
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    • pp.303-316
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    • 2018
  • In this study, I investigated the applicability of fluorescein-derived xanthene dyes to fluorescent pigment and the controllability of the optical properties of manufactured pigments. Eosin Y (D&C Red No.22) and phloxine B (D&C Red No.28) were mainly used as a dye to prepare the pigment. Dyes dissolved in a solvent were poured into a powder dispersed in the solvent, then dried and pulverized to fabricate the pigments. Optical characteristics related with fluorescence of the prepared pigment were measured. The optical properties of pigments were varied depending on the solvent used, content of the dye in the pigment, and the ratio of dyes when more then two dyes were mixed. According to the experiment result, it seems that some of the dyes attached to the powder showed fluorescence while the rest did not contribute to it. From the result of pigment washing experiment to explore the binding (or interaction) strength and characteristics of the powder-dye system constituting the pigment, it seems that there are two or more different interactions existing in the pigment system, one of which is relatively stronger than the solvent-dye interaction.

Catalytic and Structural Properties of Pyridoxal Kinase

  • Cho, Jung-Jong;Kim, Se-Kwon;Kim, Young-Tae
    • BMB Reports
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    • v.30 no.2
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    • pp.125-131
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    • 1997
  • This work reports studies of the catalytic and structural properties of pyridoxal kinase (ATP: pyridoxal 5' -phosphotransferase, EC. 2.7.1.35), Pyridoxal kinase catalyzes the phosphorylation of vitamin $B_6$ (pyridoxal, pyridoxamine, pyridoxine) using ATP-Zn as a phosphoryl donor. The enzyme purified from brain tissues is made up of two identical subunits of 40 kDa each. Native enzyme was inhibited by a substrate analogue, pyridoxal-oxime. Limited chymotrypsin digestion of pyridoxal kinase yields two fragments of 24 and 16 kDa with concomitant loss of catalytic activity. These fragments were isolated by DEAE ion exchange chromatography and used for binding studies with fluorescent ATP and pyridoxal analogues. The spectroscopic properties of both fluorescent pyridoxal analogue and Anthraniloyl ATP (Ant-ATP) bound to the 24 kDa fragment are indistinguishable from those of both pyridoxal analogue and Ant-ATP bound to the native pyridoxal kinase, respectively. The small 16 kDa fragment, generated by proteolytic cleavage of the kinase, does not bind any of the substrate analogues. Binding characteristics of Ant-ATP were extensively studied by measuring the changes in fluorescence spectra at various conditions. From the results presented herein, it is postulated that the structural domain associated with catalytic activity comprises approximately one-half of the molecular mass of pyridoxal kinase (24 kDa). whereas the remaining portion (16 kDa) of the enzyme contains a regulatory binding domain.

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