Browse > Article
http://dx.doi.org/10.15230/SCSK.2018.44.3.303

Application of Xanthene Dyes with Fluorescein-Derived Structures for Production of Fluorescent Pigments, and The Analysis of The Optical Properties of The Pigments  

Bae, Su-whan (E10 R & D Center, LG Household & Health Care Ltd.)
Publication Information
Journal of the Society of Cosmetic Scientists of Korea / v.44, no.3, 2018 , pp. 303-316 More about this Journal
Abstract
In this study, I investigated the applicability of fluorescein-derived xanthene dyes to fluorescent pigment and the controllability of the optical properties of manufactured pigments. Eosin Y (D&C Red No.22) and phloxine B (D&C Red No.28) were mainly used as a dye to prepare the pigment. Dyes dissolved in a solvent were poured into a powder dispersed in the solvent, then dried and pulverized to fabricate the pigments. Optical characteristics related with fluorescence of the prepared pigment were measured. The optical properties of pigments were varied depending on the solvent used, content of the dye in the pigment, and the ratio of dyes when more then two dyes were mixed. According to the experiment result, it seems that some of the dyes attached to the powder showed fluorescence while the rest did not contribute to it. From the result of pigment washing experiment to explore the binding (or interaction) strength and characteristics of the powder-dye system constituting the pigment, it seems that there are two or more different interactions existing in the pigment system, one of which is relatively stronger than the solvent-dye interaction.
Keywords
fluorescence; eosin Y; phloxine B; xanthene dye; fluorescent pigment;
Citations & Related Records
연도 인용수 순위
  • Reference
1 A. Gurses, M. Acikyildiz, K. Guneş, and M. S. Gurses, Dyes and pigments, ed. Sanjay K. Sharma, 13, Springer, New York (2016).
2 K. Hunger and W. Herbst, Pigments, organic, Ullmann's Encyclopedia of Industrial Chemistry, 27, 379 (2011).
3 R. M. Christie, Colour chemistry, 12, RSC paperbacks (2001).
4 H. Zollinger, Color chemistry: syntheses, properties, and applications of organic dyes and pigments, 34, John Wiley & Sons, New York (2003).
5 The chemistry of phenols, ed. Zvi Rappoport, 737, John Wiley & Sons, New York (2003).
6 FRET and FLIM techniques, ed. T. W. J. Gadella, 253, Elsevier (2008).
7 New cosmetic science, ed. T. Mitsui, 84, Elsevier (1997).
8 G. R. Jones, D. A. Duddell, D. Murray, R. B. Cundall, and R. Catterall, Eosin Y-macromolecule complexes part 1.-application of exiton theory to the study of the arrangement of eosin Y molecules in polycation-induced eosin Y dimers, J. Chem. Soc., Faraday Trans. 2, 80, 1181 (1984).
9 G. R. Jones, R. B. Cundall, D. Murray, and D. A. Duddell, Eosin Y-macromolecule complexes part 2.-interactions between eosin Y and polycations, a cationic surfactant and proteins, J. Chem. Soc., Faraday Trans. 2, 80, 1201 (1984).
10 M. Chakraborty and A. K. Panda, Spectral behaviour of eosin Y in different solvents and aqueous surfactant media, Spectrochim. Acta A, 81, 458 (2011).   DOI
11 E. D. Owen and Q. Sultana, A study of some intermolecular interactions between organic dye molecules in aqueous solution by fluorescence quenching and difference absorption spectrophotometry, J. appl. Chem. Biotechnol., 22, 1043 (1972).
12 P. M. Marshall, Rules for the visible absorption spectra of halogenated fluorescein dyes, Histochem. J., 7, 299 (1975).   DOI
13 G. R. Fleming, A. W. E. Knight, J. M. Morris, R. J. S. Morrison, and G. W. Robinson, Picosecond fluorescence studies of xanthene dyes, J. Am. Chem. Soc., 99(13), 4306 (1977).   DOI
14 J. Coppeta and C. Rogers, Dual emission laser induced fluorescence for direct planar scalar behavior measurements, Exp. Fluids, 25, 1 (1998).   DOI
15 A. P. Green and A. R. Buckley, Solid state concentration quenching of organic fluorophores in PMMA, Phys. Chem. Chem. Phys., 17, 1435 (2015).   DOI
16 R. F. Kubin and A. N. Fletcher, Fluorescence quantum yields of some rhodamine dyes, J. Luminescence, 27, 455 (1982).   DOI