• 제목/요약/키워드: Fluorescent properties

검색결과 311건 처리시간 0.025초

새로운 로다민 B 페노시아진 유도체의 합성과 형광 특성 (Synthesis and Fluorescent Properties of New Rhodamine B Containing Phenothiazine Moiety)

  • 손문수;장승현
    • 한국환경과학회지
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    • 제24권7호
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    • pp.955-960
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    • 2015
  • A colorimetric chemosensors $Sn^{2+}$ have been designed and synthesized by three steps. The spirolactam ring-opening process of rhodamine B is one of the most useful mechanisms for controlling fluorescence properties. Herein, new fluorescent chemosensors 1 and 2 based on rhodamine B containing phenothiazine derivertive were synthesized. They exhibit selective fluorescence enhancement behaviour in the presence of $Sn^{2+}$ ion. Complexation between these compounds and the metal cations were confirmed through continuous variation method. It is observed that compounds 1, 2, and $Sn^{2+}$ ion are complexed by 1:1 formation. Especially the proposed compounds 1 and 2 exhibit quick, simple and facile synthetic route.

Ar 가스 압력과 RF 전력변화에 따른 유도결합형ㆍ플라즈마 E-H모드 변환의 광학적 특성 (Optical E-H Transition Properties of Inductively Coupled Plasma with Ar Gas Pressure and RF Pourer)

  • 허인성;조주웅;이영환;김광수;최용성;박대희
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권1호
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    • pp.20-23
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    • 2004
  • In this paper, the emission properties of electrodeless fluorescent lamp were discussed using the inductively coupled plasma. To transmit the electromagnetic energy into the chamber, a RF power of 13.56 [MHz] was applied to the antenna and considering the Ar gas pressure and the RF electric power change, the emission spectrum, Ar I line, luminance were investigated. At this time, the input parameter for ICP RF plasma, Ar gas pressure and RF power were applied in the range of 10∼60 [mTorr], 10∼300 [W], respectively. From emission intensity and lumnance intensity results, the mode transition from E-mode to H-mode was observed. This implies that this method can be used to find an optimal RF power for efficient light illumination in an electrodeless fluorescent lamp.

Study on the Luminance Properties of Optical Films for Flat-lamp Backlight Applications

  • Yu, Mi-Yeon;Park, Ji-Hee;Ko, Jae-Hyeon
    • Journal of the Optical Society of Korea
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    • 제12권3호
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    • pp.174-177
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    • 2008
  • The luminance properties of FFL(Flat Fluorescent Lamp) backlights have been investigated in detail for the first time. The on-axis luminance gain as well as viewing-angle characteristics on various combinations of optical films were obtained from FFL backlight and compared to the results of conventional CCFL(cold-cathode fluorescent lamps) backlights. It was found that the on-axis luminance gains achieved by using optical films in the FFL backlight were lower than those in the CCFL backlight indicating that the recycling processes occurring between optical films and light sources/reflection sheet are not so effective in the FFL backlight due to the much larger area of, and thus higher absorption probability of the FFL. This result suggests that new optical films should be developed for FFL backlight and other flat-lamp backlight technologies.

환형 무전극 램프의 광학적, 전자계적 특성 (Optical and Electromagnetic Distribution of Ring-shaped Electrodeless Fluorescent Lamps)

  • 조주웅;이성진;최용성;김용갑;박대희
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2003년도 학술대회논문집
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    • pp.161-163
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    • 2003
  • Ring-shaped electrodeless fluorescent lamp is removed the internal electrodes and heating filaments that are a light-limiting factor of conventional fluorescent lamps. The ring-shaped electrodeless lamp is intended as a high efficacy replacement for the incandescent reflector lamp in many applications. In this paper, maxwell 3D finite element analysis program (Ansoft) was used to obtain electromagnetic properties associated with the coil and nearby structures. The electromagnetic emitting properties were presented by 3D simulation software operated at 250[㎑]and some specific conditions. The optical measurement measured luminance and a temperature and an optical spectrum distribution for 10 minutes in a one minute interval at the same time.

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Acid-Base and Spectroscopic Properties of 1,4-Benzodiazepines in Sodium Dodecyl Sulfate Micellar Solutions

  • Joon Woo Park;Hye Sung Cho
    • Bulletin of the Korean Chemical Society
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    • 제11권1호
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    • pp.54-58
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    • 1990
  • Acid-base equilibria and spectroscopic properties of diazepam and chlorodiazepoxide were investigated in sodium dodecyl sulfate (SDS) micellar solutions as functions of pH. The results were compared with the behaviors in homogeneous aqueous media. The presence of SDS increased the $pK_a$ of chlorodiazepoxide to 6.3 from 4.7, while it has little effect on the $pK_a$ of diazepam. The acidic protonated form of diazepam was moderately fluorescent when the solution was excited at 350 nm, and emissnion intensity of the species was enhanced about 5 fold by the presence of SDS. On the other hand, the acidic solution of chlorodiazepoxide was non-fluorescent, but the neutral solution of the compound was fluorescent upon excitation at 350 nm. The emission peak of the neutral chlorodiazepoxide shifted to shorter wavelength region without significant change in the emission intensity upon the addition of SDS. Procedures for assay of the individual drugs from their mixture by the use of SDS micelle were discussed.

EEFL의 주파수 변화에 따른 전기적 특성과 휘도특성 (Luminance Properties and Electrical Properties by Applied Frequency of External Electrode Fluorescent Lamp(EEFL))

  • 이성진;이종찬;박노준;박대희
    • 전기학회논문지
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    • 제56권2호
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    • pp.355-360
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    • 2007
  • The recent TFT-LCD Trend that is done large size gradually. As size of monitor great, though problem happens, it is that consumer's request which it makes monitor combined TV function. Monitor and TV are no difference externally greatly, but define difference happens as for backlight. An external electrode fluorescent lamp (EEFL) has an advantage of a long lifetime in the early stages of the study on plasma discharge, interest in the lamp continues. Researches on the operation of external electrode fluorescent lamps have focused mainly on its use of a type of high frequency (MHz). By performing high Luminance using a square wave operation method with the low frequency below 100kHz, which is applied to a narrowed tube type lamp that has several mm of lamp diameter, EEFL presented the possibility of using it as a light source for back-lights. However, because EEFL generates plasma using wall charges, which considers the impedance characteristics of glass based on the structural principle in discharge, it can be significantly affected by frequency. Thus, this study verified the change in the characteristics of electromagnetic fields according to the change in frequency through a Maxwell electromagnetic field simulation and examined the relationship between the change in the EEFL frequency and Luminance by measuring the optical characteristics.

28W(T5) 형광등 구동용 압전트랜스포머의 전기적 특성 (Electrical Characteristics of Piezoelectric Transformer for Driving A 28W Fluorescent Lamp)

  • 류주현;황상모;윤광희;김종선;박창엽
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.847-851
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    • 2000
  • In this study, contour-vibration-mode Pb($Ni_{1/2}$,$W_{1/2}$)$O_3$-Pb(Zr,Ti)$O_3$ piezoelectric transformers for driving a 28W(T5) fluorescent lamp were fabricated to the modified filter structure with ring and dot electrodes which has been developed for application in 455kHz AM radios. The piezoelectric transformers were fabricated to the size of $31.5$\times$31.5$\times$2.5$mm^3$ with the variations of ring/dot electrode area ratio. Driving of piezoelectric transformer was carried out with input region for the ring electrode and output region for the dot electrode. The electrical properties and characteristic temperature rises caused by the vibration were measured at various load resistances. A 28 W fluorescent lamp, T5, was successfully driven by the fabricated transformer. The transformer with ring/dot electrode area ratio of 1.83 exhibited the best properties in terms of output power, efficiency and characteristic temperature rise, 30.95 W, 97.57% and8.3$^{\circ}C$ respectively.

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환형 무전극 형광램프 구동을 위한 전기적, 자기적 특성 분석 (A study on Electrical and Electromagnetic Properties for Driving the Ring-shaped electrodeless fluorescent lamp)

  • 조주웅;이영환;남중희;최용성;김용갑;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집 방전 플라즈마 유기절연재료 초전도 자성체연구회
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    • pp.69-72
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    • 2004
  • In recent, there have been several developments in lamp technology that promise savings in electrical power consumption and improved quality of the lighting space. Above all, the advantage of ring-shaped electrodeless fluorescent lamp is the removal of internal electrodes and heating filaments that are a light-limiting factor of conventional fluorescent lamps. The ring-shaped electrodeless lamp is intended as a high efficacy replacement for the incandescent reflector lamp in many applications. Therefore, the life time of ring-shaped electrodeless fluorescent lamps is substantially higher than that of conventional fluorescent lamps and last up to 60,000 hours. In this paper, we present measurement results of electrical characteristics of a ring-shaped electrodeless fluorescent lamp as a function of frequency and number of coil turns using a highly permeable Mn-Zn ferrite. It is found that the impedance are increased while the quality factor decreases as frequency increases.

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전기천공시스템에서 Propidium Iodide와 Yo-Pro-1의 농도에 따른 세포 생존율과 전달효율 평가 (Evaluation of Cell Viability and Delivery Efficiency in Electroporation System According to the Concentrations of Propidium Iodide and Yo-Pro-1)

  • 배서준;임도진
    • Korean Chemical Engineering Research
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    • 제57권6호
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    • pp.898-906
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    • 2019
  • 본 연구에서는 전기천공시스템에서 형광 염료를 사용한 세포 생존율 평가와 형광 염료를 전달 물질로 하여 세포 내부로의 전달 효율 평가를 통해 세포의 생존율과 전달 물질의 전달 효율 평가에 사용하기 적합한 형광 염료의 선정 및 사용에 적절한 농도에 대한 가이드라인을 제시 할 수 있는 기초 연구를 수행하였다. 형광 염료로는 Propidium Iodide와 Yo-Pro-1을 사용하였다. Propidium Iodide과 Yo-Pro-1을 사용한 세포 생존율 평가와 전달 효율의 평가에서 각 형광염료의 유세포 분석 히스토그램의 모양은 형광 염료의 종류와 사용한 농도에 따라 다른 것을 확인하였다. 이는 사용하는 형광 염료의 특성과 연관이 있는 것으로 이 결과를 통해 세포 분석에 사용하는 형광 염료의 특성에 따라 분석 결과가 달라지는 것을 알 수 있었다. 형광 염료 자체가 세포 생존률에 미치는 영향은 크지 않음을 확인하였다. 또한 두 종류 이상의 형광 염료를 사용하여 분석을 하는 경우 발생할 수 있는 형광 신호 간의 간섭 영향을 확인하였다. 간섭의 영향은 Yo-Pro-1의 농도가 높을수록 큰 것으로 확인되었으며 Propidium Iodide의 농도는 형광 신호의 간섭에 큰 영향을 미치지 않음을 확인하였다. 본 연구를 통해 형광 염료의 종류와 농도에 따라 세포 생존율 평가와 전달 효율의 평가 결과가 영향을 받는 것을 확인했으며 이는 형광 염료의 특성과 연관이 있는 것으로 판단된다. 또한, 본 연구 결과를 토대로 세포 생존율 평가와 전달 효율 평가에 적절한 형광 염료의 선정과 사용에 적절한 농도를 제시하였다.

둥근형 무전극 형광램프의 자계 분포 특성 (Magnetic Field Distribution Characteristics of Ring-Shaped Electrodeless Fluorescent Lamp)

  • 최용성;조재철;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 광주전남지부
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    • pp.53-57
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    • 2006
  • In this paper, maxwell 3D finite element analysis program (Ansoft) was used to obtain electromagnetic properties associated with the coil and nearby structures. The electromagnetic emitting properties were presented by 3D simulation software operated at 250 kHz and some specific conditions. The electromagnetic field in the ferrite core was shown to be high and symmetric. An LS-100 luminance meter and a Darsa-2000 spectrum analyzer were used in the experiment. According to data on the lamp tested using high magnetic field ferrite, the optical and thermal wave fields were shown to be high around the ring-shaped electrodeless fluorescent lamp. The optical or light field was high at the center of the bulb rather than around the ferrite core. The light conditions of the bulb were assumed to be complex, depending on the condition of the filler gas, the volume of the bulb, and the frequency of the inverter. Our results have shown coupling between the gas plasma and the field of the light emitted to be nonlinear.

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