• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.97-100
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• 2007

A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_2$ - free hydrogen . The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane and propane mixture decomposition reaction was carried out at the temperature range of 850 - 900 $^{\circ}C$, methane and propane mixture gas velocity of 1.0 $U_{mf}$ ${\sim}$ 3.0 $U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by TEM image.

• 한국환경보건학회지
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• 제24권2호
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• pp.57-67
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• 1998

The characteristics of anaerobic degradation of phenol were studied in a fluidized bed reactor using a granular activated carbon as media. Increasing the phenol loading rate with variation of feed concentration was considered as an experimental variable. In the present anaerobic fluidized-bed reactor, the removal efficiency of phenol and COD was maintained about 93-99% and 91-96%, respectively, up to 3.6 kg-phenol/$m^3\cdot d$ of the phenol loading rate, but it was abruptly decreased under 5.0 kg-phenol/$m^3\cdot d$. The volumetric production of biogas per removed phenol was decreased linearly between 0.80-1.27 m$^3$ gas/kg-phenol (0.35-0.56 m$^3$-gas/kg-COD), increasing the phenol loading rate, and the methane content of biogas was 55-60% as similar to that estimated theoretically up to 3.6 kg-phenol/$m^3\cdot d$. But the production rate and methane content of biogas were suddenly decreased at the loading rate of 5.0 kg-phenol/$m^3\cdot d$. Therefore, the anaerobically biodegradable phenol loading rate of the present reactor was 3.6 kg-phenol/$m^3\cdot$ d in order to accomplish over 90% of the removal efficiency.

• 한국산학기술학회논문지
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• 제9권2호
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• pp.487-492
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• 2008

본 논문은 유동층반응기에서 메탄 열분해에 의한 수소 생산과 탄소 생성에 대한 연구를 수행하였다. 환경에 대한 영향을 최소화한 상태에서 one-step에 의한 메탄의 전환반응을 메탄 분해촉매활성에 영향을 미치는 인자에 대하여 연구하였다. 측정된 압력요동특성치의 해석을 통하여 유동층 열분해촉매의 유동화현상을 측정하였으며, 유동화특성에 따른 메탄열분해능을 측정하였다. 메탄의 분해능는 생성되는 수소의 농도로부터 측정하였다. 유동층의 특성인 층내 입자 이동성, U-Umf, 마모, 비산유출, 유동화가스의 효율밀도에 따른 분해효율에 미치는 영향을 고찰하였다.

• 한국세라믹학회지
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• 제54권2호
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• pp.128-136
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• 2017

Fly ash from a circulating fluidized bed combustion boiler (CFBC fly ash) is very different in mineralogical composition, chemical composition, and morphology from coal ash from traditional pulverized fuel firing because of many differences in their combustion processes. The main minerals of CFBC fly ash are lime and anhydrous gypsum; however, due to the fuel type, the strength development of CFBC fly ash is affected by minor components of active $SiO_2$ and $Al_2O_3$. The initial hydration product of the circulating fluidized bed combustion fly ash (B CFBC ash) using petro coke as a fuel is Portlandite which becomes gypsum after 7 days. Due to the structural features of the portlandite and gypsum, the self-cementitious strength of B CFBC ash was low. While the hydration products of the circulating fluidized bed combustion fly ash (A CFBC ash) using bituminous coal as a fuel were initially portlandite and ettringite, after 7 days the hydration products were gypsum and C-S-H. Due to the structural features of ettringite and C-S-H, A CFBC ash showed a certain degree of self-cementitious strength.

• 상하수도학회지
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• 제18권2호
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• pp.181-187
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• 2004

The purpose of this study is to investigate the biofilm reactors capable of doing high efficiency treatment. Vertical fluidized bed biofilm reactor(VFBBR) and spiral fluidized bed biofilm reactor(SFBBR) was used for their performence in biodegradation of artificial sewage. The factors influencing the efficiency of those reactors were compared with difference of physical condition. They had same size but different structure to gain access of its unique characteristics. When recycle solution with flow rate of 22 mL/min and artificial sewage with flow rate of 2~10 mL/min were fed into two reactors in aerobic state, the average $COD_{cr}$, removal rate for biodegradation of SFBBR was greater than VFBBR. After reactor feed sewage was constantly maintained as flow rate of 4 mL/min and the recycle solution were changed to 10~32 mL/min respectively, the average $COD_{cr}$ removal rate of artificial sewage in SFBBR was greater than VFBBR. In this experiment for addition of support media into two reactors SFBBR was 4.1% excellent than VFBBR. Above all, SFBBR excelled VFBBR in boidegradation of organic matter in sewage.

• 한국세라믹학회지
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• 제54권5호
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• pp.380-387
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• 2017

In this study, unstable CaO was converted into a stable Ca compound by using carbonation in a circulating fluidized bed boiler of fly ash to confirm material usability as cement admixture; also undertaken was carbonation test and mortar to examine chemical and physical change by measuring absorption rate and compressive strength. To investigate the chemical properties of circulating fluidized bed boiler fly ash, XRD and TG-DTA were used to determine how the properties of the reaction product change quantitatively during carbonation. In order to stabilize CaO, carbonation of CaO is considered to be the most desirable process. This is because $CaCO_3$, which is a Ca compound, was produced by carbonate reaction of unstable CaO, and decrease of the absorption rate and improvement of the compressive strength were observed when the carbonated fly ash was replaced with cement.

• Korean Chemical Engineering Research
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• 제43권2호
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• pp.278-285
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• 2005

연속식 유동층 반응기에서 흡착제인 천연망간광석을 이용한 탈황반응과, grain model과 two-phase 이론에 근거한 탈황 모사를 연구하였다. 입자 내의 기공 구조변화를 고려한 grain model을 통하여 탈황 반응시간, 천연망간광석의 입자 크기, 기공 내에서 $SO_2$의 확산속도에 대한 영향을 고찰한 결과, 입자의 기공 내에서 $SO_2$ 가스 확산이 탈황 반응의 가장 중요한 요소로 나타났다. 또한, 연속식 유동층 반응기에서 흡착제인 천연망간광석을 이용한 탈황반응 실험결과는 grain model과 two-phase 이론과 잘 일치하였으며, 탈황 결과를 잘 예측할 수 있었다.

• 한국수소및신에너지학회논문집
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• 제27권5호
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• pp.581-588
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• 2016

To compare reduction reactivity of oxygen carrier particles, $CH_4$ combustion characteristics were measured and investigated in a bubbling fluidized bed reactor with increasing $CH_4$ concentration from 10 to 100 %. Among five oxygen carriers (OC-1, OC-2, SDN70, C14, C28), OC-1, OC-2, SDN70 particles were selected as better oxygen carriers from the viewpoints of fuel conversion and $CO_2$ selectivity. However, some oxygen carriers showed lower fuel conversion and $CO_2$ selectivity even though they have high oxygen transfer capacity. Therefore, we could conclude that not only TGA tests to measure the oxygen transfer capacity but also fluidized bed tests to analyze exhaust gas concentration should be performed to select better oxygen carrier without misunderstanding of carriers reactivity.

• 한국주조공학회지
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• 제12권6호
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• pp.471-479
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• 1992

For the last 2 decades, the bonding materials for the foundry sand and the foundry equipments with high performance have been developed and employed in the foundry shops. In those periods, the furan resins hardened in higher temperature have been replaced with the self-hardened ones in the room temperature. Simultaneously the various reclamation methods of the self-hardened furan resin sand have been developed in order to get the clean working environments, the reduction of solid wastes and the lower of production cost in the foundry. In this experimental study, the combustion reclamation method using the fluidized bed among the various methods was studied in order to reduce the L.O.I. and /or $N_2$ gas due to the deposition of the furan resins and the hardeners. Comparing the results of this experimental combustion reclamation method with those of the employed pneumatic method, the Surface Stability Index of the specimen made by combustion method is 30% higher than that of the latter one and L.O.I. decreases about 30%. The reclamation temperature of 650$^{\circ}C$ in this experimental fluidized bed would be recommended in the viewpoints of the reclamation period, the fuel consumption and the residual quantity of the furan resin. The formula determining the minimum fluidizing velocities according to the temperatures in the fluidized bed has been obtained.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.85-88
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• 2006

A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2$-free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The propane decomposition rate used carbon black N33O as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600{\sim}800^{\circ}C$, paropane gas velocity of $1.0 U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The carbon which was by-product of methane decomposition reaction was deposited on the catalyst surface that was observed by SEM. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.