• Title/Summary/Keyword: Flow-cell

Search Result 3,140, Processing Time 0.029 seconds

Simulation of Direct Methanol Fuel Cells Employing Computational Fluid Dynamics(CFD) (유체 전산모사를 통한 직접 메탄올 연료전지의 시뮬레이션)

  • Kim, Young-Jin;Lee, Tae-Hee;Oh, In-Hwan;Hong, Seong-An;Kim, Huk-Nyun;Ha, Heung-Yong
    • Journal of the Korean Electrochemical Society
    • /
    • v.6 no.1
    • /
    • pp.28-35
    • /
    • 2003
  • A numerical analysis of electrochemical reaction and dynamics of the fluid flow in the channels of a DMFC separator was carried out by using a commercial Computational Fluid Dynamics(CFD) code fluent(ver.6.0). From the simulation work, many valuable informations were obtained in terms of distributions of velocity, pressure, temperature, concentration and current density over the flow field. And it was possible to optimize the flow field structure by using the simulation results. The simulation work using the Cm code was found very helpful in analysing the phenomena occurring in the fuel cell and optimizing the structures of electrodes and flow field.

Metal Foam Flow Field Effect on PEMFC Performance (금속 폼 유로가 고분자전해질 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
    • /
    • v.32 no.4
    • /
    • pp.442-448
    • /
    • 2021
  • Flow field is an important parameter for polymer electrolyte membrane fuel cell (PEMFC) performance to have an effect on the reactant supply, heat and water diffusion, and contact resistance. In this study, PEMFC performance was investigated using Cu foam flow field at the cathode of 25 cm2 unit cell. Polarization curve and electrochemical impedance spectroscopy were performed at different pressure and relative humidity conditions. The Cu foam showed lower cell performance than that of serpentine type due to its high ohmic resistance, but lower activation and concentration loss due to the even reactant distribution of porous structure. Cu foam has the advantage of effective water transport because of its hydrophobicity. However, it showed low membrane hydration at low humidity condition. The metal foam flow field could improve fuel cell performance with a uniform pressure distribution and effective water management, so future research on the properties of metal foam should be conducted to reduce electrical resistance of bipolar plate.

The Properties of Boron-doped Zinc Oxide Film Deposited according to Oxygen Flow Rate

  • Kim, Dong-Hae;Son, Chan-Hee;Yun, Myoung-Soo;Lee, Jin-Young;Jo, Tae-Hoon;Seo, Il-Won;Jo, I-Hyun;Roh, Jun-Hyung;Choi, Eun-Ha;Uhm, Han-Sup;Kwon, Gi-Chung
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.08a
    • /
    • pp.358-358
    • /
    • 2012
  • The application of BZO (Boron-doped Zinc Oxide) films use as the TCO(Transparent Conductive Oxide) material for display and solar cell industries, where the conductivity of the BZO films plays a critical role for improvement of cell performance. Thin BZO films are deposited on glass substrates by using RF sputter system. Then charging flow rates of O2 gas from zero to 10 sccm, thereby controlling the impurity concentration of BZO. BZO deposited on soda lime glass and RF power was 300 W, frequency was 13.56 MHz, and working pressure was $5.0{\times}10-6$ Torr. The Substrate and glass between distance 200 mm. We measured resistivity, conductivity, mobility by hall measurement system. Optical properties measured by photo voltaic device analysis system. We measured surface build according to oxygen flow rate from XPS (X-ray Photoelectron Spectroscopy) system. The profile of the energy distribution of the electrons emitted from BZO films by the Auger neutralization is measured and rescaled so that Auger self-convolution arises, revealing the detail structure of the valence band. It may be observed coefficient ${\gamma}$ of the secondary electron emission from BZO by using ${\gamma}$-FIB (Gamma-Focused Ion Beam) system. We observed the change in electrical conductivity by correlation of the valence band structure. Therefore one of the key issues in BZO films may be the valence band that detail structure dominates performance of solar cell devices. Demonstrating the secondary electron emission by the Auger neutralization of ions is useful for the determination of the characteristics of BZO films for solar cell and display developments.

  • PDF

Characteristics of Design Parameters on the Regenerative Blower Used for Building Fuel Cell System (건물 연료전지용 재생블로어 설계변수 특성연구)

  • Jang, Choon-Man;Lee, Jong-Sung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.24 no.10
    • /
    • pp.739-744
    • /
    • 2012
  • This paper describes the blower performance used for single-stage high pressure regenerative blower. The blower considered is widely applied to the field of a fuel cell system, a medical equipment and a sewage treatment plant. Flow rate and rotating frequency of a impeller of the blower are considered as design parameters for the proper operation of the blower. Three-dimensional Navier-Stokes equations are introduced to analyze the performance and internal flow of the blower. Relatively good agreement between experimental measurements and numerical simulation is obtained. Throughout a numerical simulation, it is found that small and stable vortical flow generated inside the blade passage is effective to increase pressure and efficiency of the blower. Large local recirculation flow having low velocity in the blade passage obstructs the generation of stable vortical flow, thus increases the pressure loss of the blower. Detailed flow field inside the blower is also analyzed and discussed.

A Numerical Study of a Effect of the Uniform Flow in Horizontal Convection (일반류가 수평대류에 미치는 영향에 관한 수치연구)

  • Lee, Hwa-Woon;Kim, Yoo-Keun;Jung, Woo-Sik
    • Journal of Environmental Science International
    • /
    • v.7 no.3
    • /
    • pp.349-360
    • /
    • 1998
  • Effects of uniform flow on a two-dimensional mesoscale horizontal convection were investigated by using the vorticity and thermodynamic equations. For thins purpose, We simulated properties of a thermal convection m a stably stratified Boussinesq flued caused by partial heating at the center of a lower boundary If we don't consider effects of the uniform flow, the convection takes the form of aidsymmetrlc with respect to the z-alds. But when uniform flow Is strong, velocity field and temperature field consist of a sin91e cell structure which spreads upstream side of the partial heating area. The flow pattern for strong uniform flows takes the form of positive temperatue near the ground and negative temperature perturbation soft over the partial heating area, and downward motion directly over the upwind portion of the partial heating area and upward motion on the downstream side. The downstream edge of the upstream cell Is shifted in the downstream direction with the Increase of uniform flow almost linearly.

  • PDF

Design of Serpentine Flow-field Stimulating Under-rib Convection for Improving the Water Discharge Performance in Polymer Electrolyte fuel cells (고분자전해질 연료전지의 물 배출 성능 향상을 위한 촉매층 공급 대류 촉진 사행성 유동장 설계)

  • Choi, Kap-Seung;Bae, Byeong-Cheol;Park, Ki-Won;Kim, Hyung-Man
    • Journal of the Korean Electrochemical Society
    • /
    • v.15 no.2
    • /
    • pp.74-82
    • /
    • 2012
  • Proton exchange membrane fuel cell performance is changed by the complicated physical phenomenon. In this study, water discharge performance of proton exchange membrane fuel cell were performed numerically to compare serpentine channel flow fields of 5-pass 4-turn serpentine and 25 $cm^2$ reaction surface between with and without sub-channel at the rib. Through the supplement of sub channel flow field, it is shown from the results that water removal characteristic inside channel improves because the flow direction of under-rib convection is changed into the sub channel. Reacting gases supplied from entrance disperse into sub channel flow field and electrochemical reaction occurs uniformly over the reaction surface. The results obtained that total current density distributions become uniform because residence time of reacting gases traveling to sub-channel flow field is longer than to main channel.

Spherical and cylindrical microencapsulation of living cells using microfluidic devices

  • Hong, Joung-Sook;Shin, Su-Jung;Lee, Sang-Hoon;Wong, Edeline;Cooper-White, Justin
    • Korea-Australia Rheology Journal
    • /
    • v.19 no.3
    • /
    • pp.157-164
    • /
    • 2007
  • Microencapsulation of cells within microfluidic devices enables explicit control of the membrane thickness or cell density, resulting in improved viability of the transplanted cells within an aggressive immune system. In this study, living cells (3T3 and L929 fibroblast cells) are encapsulated within a semi-permeable membrane (calcium crosslinked alginate gel) in two different device designs, a flow focusing and a core-annular flow focusing geometry. These two device designs produce a bead and a long microfibre, respectively. For the alginate bead, an alginate aqueous solution incorporating cells flows through a flow focusing channel and an alginate droplet is formed from the balance of interfacial forces and viscous drag forces resulting from the continuous (oil) phase flowing past the alginate solution. It immediately reacts with an adjacent $CaCl_2$ drop that is extruded into the main flow channel by another flow focusing channel downstream of the site of alginate drop creation. Depending on the flow conditions, monodisperse microbeads of sizes ranging from $50-200\;{\mu}m$ can be produced. In the case of the microfibre, the alginate solution with cells is extruded into a continuous phase of $CaCl_2$ solution. The diameter of alginate fibres produced via this technique can be tightly controlled by changing both flow rates. Cell viability in both forms of alginate encapsulant was confirmed by a LIVE/DEAD cell assay for periods of up to 24 hours post encapsulation.

Prognostic Significance of Peripheral Blood Flow Cytometry Parameters in Patients with Non-Metastatic Breast Cancer

  • Engin, Huseyin;Bilir, Cemil;Tekin, Ishak Ozel
    • Asian Pacific Journal of Cancer Prevention
    • /
    • v.14 no.12
    • /
    • pp.7645-7649
    • /
    • 2013
  • Background: Immune functions and their relation to prognosis in breast cancer patients have become areas of great interest in recent years. Correlations between survival outcomes and peripheral blood flow cytometry parameters are therefore of interest. Here we focused on patients with non-metastatic breast cancer (BC). Materials and Methods: A total of 29 patients with pathological confirmed breast carcinoma and flow cytometry data were assessed for overall survival (OS) and progression free survival (PFS). Results: The median age of the patients was 54 years (range, 29-83). Multivariate analysis revealed that OS was significantly associated with absolute cytotoxic T cell count (95%CI, coef 2.26, p=0.035), tumor size (95%CI, coef -14.5, p 0.004), chemotherapy (95%CI, coef 12.9, p 0.0001), MFI of CD4 (95%CI, coef -5.1, P 0.04), MFI of HLA DR (95%CI, coef -5.9, p 0.008) and tumor grade (95%CI, coef -13, P 0.049) with R-Sq(adj)=67%. Similar findings were obtained for PFS. Conclusions: OS and PFS were significantly associated with tumor grade, tumor size, chemotherapy, MFI of CD4, HLA DR and absolute cytotoxic T cell count. The study revealed that MFI of basic CD markers and absolute cytotoxic T cell number may be a prognostic factors in women with non-metastatic BC.

The Effect of a Bypass Flow Penetrating through a Gas Diffusion Layer on Performance of a PEM Fuel Cell (가스확산층을 통과하는 반응가스 우회유동이 고분자 연로전지의 성능에 미치는 영향)

  • Cho, Choong-Won;Ahn, Eun-Jin;Lee, Seung-Bo;Lee, Won-Yong
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.11a
    • /
    • pp.147-151
    • /
    • 2007
  • A serpentine channel geometry often used in a polymer electrolyte membrane fuel cell has a strong pressure gradient between adjacent channels in specific regions. The pressure gradient helps some amount of reactant gas penetrate through a gas diffusion layer(GDL). As a result, the overall serpentine flow structure is slightly different from intention of a designer. The purpose of this paper is to examine the effect of serpentine flow structure on current density distribution. By using a commercial code, STAR-CD, a numerical simulation is performed to analyze the fuel cell with relatively high aspect ratio active area. To increase the accuracy of the numerical simulation, GDL permeabilities are measured with various compression conditions. Three-dimensional flow field and current density distribution are calculated. For the verification of the numerical simulation results, water condensation process in the cathode channel is observed through a transparent bipolar plate. The result of this study shows that the region of relatively low current density corresponds to that of dropwise condensation in cathode channels.

  • PDF

A Study on Grid Adaptation by Poisson Equation (푸아송 방정식을 이용한 격자 적응에 대한 연구)

  • 맹주성;문영준;김종태
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.17 no.1
    • /
    • pp.182-189
    • /
    • 1993
  • To improve the resolution of complex flow field features, grid adaptation scheme of Anderson has been revised, which was based on the Poisson grid generator of Thompson. Anderson's original scheme adapts the grid to solution automatically, but if flow field is more or less complex, then the adaptivity is weak. So the technique of using threshold which is used in unstructured grid system is adopted. The regions of large variation in the solution are marked by marking function which has the property of total variation of the solution, and these regions have same values of weight but other regions are neglected. This updated method captures shocks clearly and sharpy. Four examples are demonstrated, (1) Hypersonic flow past a blunt body, (2) High speed inlet analysis, (3) Supersonic flow of M=1.4 over a 4% biconvex airfoil in a channel, (4) Hypersonic shock-on-shock interaction at M=8.03.