• Title/Summary/Keyword: Flow properties

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Non-Newtonian Rheological Properties of Poly(vinyl alcohol) hydrogel (Poly(vinyl alcohol) hydrogel의 비 뉴톤 유변학적인 성질)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.323-328
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    • 2009
  • The rheological properties of complex materials such as polymer melts show complicated non-Newtonian flow phenomena when they are subjected to shear flow. These flow properties are controlled by the characteristics of flow units and the interactions among the flow segments. The non-Newtonian flow curves of poly(vinyl alcohol) hydrogel were obtained in various concentrations and temperatures by using a cone-plate rheometer. By applying non-Newtonian flow equation to the flow curves for PVA hydrogel samples, the rheological parameters were obtained. The PVA hydrogel samples are shear thinning under increasing shear rate modes which result in thixotropic behavior.

Experimental analysis on rheological properties for control of concrete extrudability

  • Lee, Hojae;Kim, Jang-Ho Jay;Moon, Jae-Heum;Kim, Won-Woo;Seo, Eun-A
    • Advances in concrete construction
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    • v.9 no.1
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    • pp.93-102
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    • 2020
  • In this study, we examined the relationship among the rheological properties, workability, and extrudability in the construction of concrete structures using additive manufacturing. We altered the component materials (binder type, water-binder (W/B) ratio, sand ratio) to assess their effect on the rheological properties experimentally. The results indicated that the W/B and sand ratios had the largest effect on the rheological properties. In particular, when the sand ratio increased, it indicated that adjusting the sand ratio would facilitate control over the rheological properties. Additionally, we compared the rheological properties with the results of a traditional workability evaluation, namely the table flow test. This indicated the possibility of inferring the rheological properties by using traditional methods. Finally, we evaluated extrusion quantity according to table flow. The extrusion rate was 350 g/s for a flow of 210 mm and 170 g/s for a flow of 130 mm, indicating that extrusion rate increased as flow increased; however, we concluded that a flow standard of approximately 140-160 mm is suitable for controlling the actual extrusion quantity and rate.

Studies on the Flow Properties of Semi-Solid Dosage Forms (I) : Steady Shear Flow Behavior of Toothpastes (반고형제제의 유동특성에 관한 연구 (제1보) : 치약의 정상전단 유동거동)

  • Kim, Jeong-Hwa;Song, Ki-Won;Lee, Jang-Oo;Lee, Chi-Ho
    • Journal of Pharmaceutical Investigation
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    • v.25 no.3
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    • pp.213-221
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    • 1995
  • The steady shear flow properties of six kinds of commercial toothpastes were measured using a concentric cylinder type rheometer. In this paper, the shear rate and temperature dependencies of their flow behavior were investigated and the validity of the Casson and Herschel-Bulkley models was examined. Further, the flow properties over a wide temperature range were quantitatively evaluated by calculating the various material parameters. Main results obtained from this study can be summarized as follows: (1) Toothpastes are plastic fluids with a yield stress and their flow behavior shows shear-thinning characteristics. (2) With increasing temperature, the degree of shear-thinning becomes weaker and the Newtonian flow behavior occurs at a lower shear rate range. (3) The Herschel-Bulkley model is more effective than the Casson model in predicting their flow behavior. (4) As the temperature increases, the yield stress, plastic viscosity and consistency index become smaller, on the contrary, the flow behavior index becomes larger.

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Thixotropic Properties of Polyacrylamide Hydrogels with Various Synthetic Conditions (합성조건에 따른 Polyacrylamide 수화 겔의 흐름변성 성질)

  • Kim, Nam-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.6
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    • pp.447-453
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    • 2006
  • of synthetic conditions and water content on rheological properties of polyacrylamide hydrogels were studied. The non-Newtonian flow curves of polyacrylamide hydrogels were obtained by using a cone-plate rheometer. The rheological parameters were obtained by applying non-Newtonian equation to the flow curves for polyacrylamide hydrogels. The polyacrylamide hydrogels are shear thinning under increasing shear rate modes which result in thixotropic behavior. These flow properties are controlled by the characteristics of flow units and the interaction among the flow segments.

Flow Properties of Doenjang (시판된장의 리올로지(Rheology) 특성에 관한 연구)

  • 양신철;김선화
    • Journal of Applied Tourism Food and Beverage Management and Research
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    • v.13 no.1
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    • pp.55-68
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    • 2002
  • Flow properties of doenjang samples at various total solid contents (30, 32, 34, 36, 38, 40%) were evaluated in this study. Flow properties of doenjang samples was determined by using Haake concentric cylinderical viscometer and Instron testing machine with capillary extrusion viscometer, and consistency index(K), and flow behavior index(n) was also determined from power models, and yield stress was derived form Casson models and vanes methods. Doenjang samples showed shear-thinning (pseudoplastic) fluid with small magnitude of flow behavior index(n) (n=0.30-0.55). Casson yield stress was from 2.11 to 64.02(Pa). Vane yield stress was more effective than casson yield stress in property of reactivation. Apparent viscosity was decreased with the increase in temperature and activation energy was in the range of 6.58 to 10.70 kJ/mole. From the capillary extrusion method, K and n was increased with the increase in solid content with good correlation with. The result revealed that capillary extrusion method is useful for measuring the flow properties of doenjang.

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Microstructure and Mechanical Properties of Hot-Stamped 3.2t Boron Steels according to Water Flow Rate in Direct Water Quenching Process (3.2t 보론강 판재 직수냉각 핫스탬핑시 냉각수 유량에 따른 미세조직 및 기계적 특성)

  • Park, Hyeon Tae;Kwon, Eui Pyo;Im, Ik Tae
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.693-700
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    • 2020
  • Direct water quenching technique can be used in hot stamping process to obtain higher cooling rate compared to that of the normal die cooling method. In the direct water quenching process, setting proper water flow rate in consideration of material thickness and the size of the area directly cooled in the component is important to ensure uniform microstructure and mechanical properties. In this study, to derive proper water flow rate conditions that can achieve uniform microstructure and mechanical properties, microstructure and hardness distribution in various water flow rate conditions are measured for 3.2 mm thick boron steel sheet. Hardness distribution is uniform under the flow condition of 1.5 L/min or higher. However, due to the lower cooling rate in that area, the lower flow conditions result in a drastic decrease in hardness in some areas in the hot-stamped part, resulting in low martensite fraction. From these results, it is found that the selection of proper water flow rate is an important factor in hot stamping with direct water quenching process to ensure uniform mechanical properties.

A study on the Water Retention of Coating Colors(IV)-Synthesis of Alkali Sensitive Water Retention and Rheology Modifiers- (도공액의 보수성에 관한연구(제4보)- 알칼리 반응형 보수.유동성 개량제의 합성 -)

  • 이용규;엄기용
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.3
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    • pp.17-25
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    • 1997
  • Natural water-soluble polymers such as starch, casein and carboxy methyl cellulose(CMC) have been limited in their uses. However, the proper water retention of coating colors can not be obtained without addition of these polymers. Furthermore, the coating runnability and the physical properties of coated paper were not also satisfied. Therefore, the objective of this study was to synthesize the water retention and flow modifiers which can improve the water retention and flow properties of coating colors. We have measured physical properties of flow modifiers and coating colors which included flow modifiers. The viscosity of flow modifiers was very low at acid pH, and rapidly increased at about pH 7, and gradually reached to equilibrium at alkali pH. Such an increase comes from the molecular weight of flow modifiers and the amount of acrylic and methacrylic acids. The viscosity of coating color containing the flow modifiers was lower than that containing CMC. However, both of them had little difference in water retention. The water-phase viscosity of synthetic modifier containing coating color was either higher or similar compared to that of CMC containing coating color. The high shear viscosity of coating colors was low. Therefore, it can be concluded that the synthetic flow modifiers are very useful for improvement of flow properties and water retentions.

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Properties of Nitrogen and Aluminum Codoped ZnO Thin Films Grown by Radio-frequency Magnetron Sputtering (라디오파 마그네트론 스퍼터링으로 성장한 질소와 알루미늄 도핑된 ZnO 박막의 특성)

  • Cho, Shin-Ho;Cho, Seon-Woog
    • Journal of the Korean institute of surface engineering
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    • v.41 no.4
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    • pp.129-133
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    • 2008
  • Nitrogen and aluminum codoped ZnO(NAZO) thin films were grown on glass substrates with changing the nitrogen flow ratio by radio-frequency magnetron sputtering. The structural, optical, and electrical properties of the NAZO films were investigated. The surface morphologies and the structural properties of the thin films were analyzed by using the X-ray diffraction and scanning electron microscopy. The NAZO thin film, deposited at nitrogen flow ratio of 0%, showed a strongly c-axis preferred orientation and the lowest resistivity of $3.2{\times}10^{-3}{\Omega}cm$. The intensity of ZnO(002) diffraction peak was decreased gradually with increasing the nitrogen flow ratio. The optical properties of the films were measured by UV-VIS spectrophotometer and the optical transmittances for all the samples were found to be an average 90% in the visible range. Based on the transmittance value, the optical bandgap energy for the NAZO thin film deposited at nitrogen flow ratio of 0% was determined to be 3.46 eV. As for the electrical properties, the carrier concentration and the hall mobility were decreased, but the electrical resistivity was increased as the nitrogen flow ratio was increased.

Time-dependent Flow Properties of Commercial Kochujang (Hot Pepper-Soybean Paste)

  • Choi, Su-Jin;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • v.14 no.3
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    • pp.413-415
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    • 2005
  • Time-dependent flow properties of commercial kochujang (hot pepper-soybean paste) were evaluated at various shear rates (5, 15, 25, and $35\;sec^{-1}$) and temperatures (5, 15, and $25^{\circ}C$). Flow properties of all samples showed thixotropic behaviors, which were qualitatively evaluated and quantitatively described by the Weltman, Hahn, and Figoni and Shoemaker models. Time-dependent flow properties of kochujang were found to vary over the range of the shear rate and temperature investigated. Time-dependent models of Weltman and Hahn were suitable ($R^2=0.923-0.987$) for commercial kochujang.

Plotting of 13 Kinds of Properties on Temperature-Entropy Chart of Air (공기의 온도-엔트로피 선도 상에서 13 종류의 물성치 작도)

  • Kim, Deok-Jin;Kim, Duck-Bong
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.1191-1196
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    • 2009
  • The T-s chart of air displays graphically the thermophysical properties, so it is very conveniently used in various thermal systems. In previous study, the software analyzing 31 kinds of values in water system and 32 kinds of values in air-conditioning system were developed. In this study, the software drawing 13 kinds of quantity of state on air properties as ideal gas and analyzing 25 kinds of values in any air system was developed. The 13 kinds of quantity of state on air properties are temperature, pressure, specific volume, specific internal energy, specific enthalpy, specific entropy, specific exergy, exergy ratio, density, isobaric specific heat, isochoric specific heat, ratio of specific heat, and velocity of sound, and the 25 kinds of values including 13 kinds are mass flow rate, volume flow rate, internal energy flow rate, enthalpy flow rate, entropy flow rate, exergy flow rate, heat flow rate, power output, power efficiency, reversible work, lost work, and relative humidity. The developed software can draw any range of chart and analysis any state or process on air system. Also, this supports various document-editing functions such as power point. We wish to this chart is a help to design, analysis, and education in air system field.

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