• Resources Recycling
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• v.16 no.1 s.75
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• pp.54-58
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• 2007

In the continuous flow reductive treatment for recovery of silver from actual photographic wastewater, the effects of electrolysis time, applied potential, and the concentration of silver ion on the process have been examined. The efficiency of silver recovery for diluted photographic wastewater was increased with applied potential and reached its maximum at 6 V. However, the recovery of silver was shown to be decreased with potential above this. When the wastewater was undiluted, the efficiency of silver recovery was observed to rise as the applied potential became lower under the experimental conditions.

• Journal of the Korean Society of Safety
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• v.14 no.4
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• pp.114-119
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• 1999

When NaOCl was generated and put into sea-water cooling machine in order to overcome the biological hindrances against sea-water cooling machine, it was converted into metallic ion, particularly Ca and Mg, as a hydrate in sea-water and is to stick to electrolyte as a side reaction. This phenomena make the distance between the electrolytes narrow to decrease the flow rate, which induces the local vortex flow which erodes the pole plate. Moreover, this increases the resistance of the electrolyte as well as voltage to decrease the electrolytic efficiency, which has curtailed a chlorine yield and caused a pole plate cut. We are able to overcome these problems by chemical cleaning and intend to extend the life-time of electrolyte and to increase output of the sea-water electrolysis facilities by studying optimal policy regarding chemical cleaning of electrolytic cell. Cleaning time of electrolytic facilities is determined when both increase in electrolytic efficiency and decrease in pole-plate voltage are 10%. At this time as operating current of electrolytic facilities is high, operating time is diminished. Whereas, parameter of end point determination according to cleaning is Mg ionic concentration in solution. When we use Cleaner as a 7wt% HCl, cleaning time is about 80min proper. We are able to maintain pole plate performance by protecting against pole plate cut by means of electrolytic by-product, improve operating rate of facilities, and cut down on maintenance expenditure after acidic cleaning.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2004.04a
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• pp.227-232
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• 2004

Ballast water from ship harmful microorganism sterilized use of electrolytic sterilization system. The experimental methods were use of peristaltic flow pump upward on electrode pole. Due to reaction time, HRT were unlike microorganism on flow rate. In electrolysis, dioxide iridium coated titanium(Ti／IrO$_2$) and stainless steel plate were used for anode and cathode respectively. Current density controls make use of D.C Power supply on 250V 100Amper. Experimental use of current density between 0.1 and 0.5A was able to disinfect microorganism at 5 seconds by the reaction time. This study shows that the electrolyzed water has a potential for the sterilization of ballast water.

• Journal of Environmental Health Sciences
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• v.34 no.2
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• pp.175-182
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• 2008

This study investigates the optimal conditions for electrogenerated hydrogen peroxide production and the application of the electro-Fenton process using DSA electrodes. The influences of parameters for the hydrogen peroxide generation such as electrode materials, electrolyte concentration, current, pH, air flow rate and electrode distance were investigated using a laboratory scale batch reactor. The relative performance for hydrogen peroxide generation of each of the six electrodes is : Ru-Sn-Ti > Ru-Sn-Sb > Ru > Ir > Pt > Sn-Sb. Optimum NaCl dosage, current and air flow rate were 2.0 g/l, 12.5 A and 2 l/min, respectively. When the pH is low, hydrogen peroxide concentration was high. Electrode distance dos not effect to a hydrogen peroxide generation. A complete color removal was obtained for RhB (200 mg/l) at the 8 min mark of the electro-Fenton process under optimum operation conditions of $Fe^{2+}$ 0.105 g/l and 5.0 A. The electro-Fenton process increased initial reaction and decreased final reaction time. However the effect was not high.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.810-815
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• 2011

Concentrated water discharged from seawater desalination process contains a high concentration of $Na^+$ ion. Electrolysis was applied to synthesize NaOH solution from the highly concentrated NaCl solution. The effect of various operating parameters of composited laboratory-scale chlor-alkali (CA) membrane cell was investigated. The operating parameters such as membrane types (CIMS and Nafion membranes), pretreatment of the membrane, flow rate (73 mL/min~200 mL/min), initial $Na^+$ ion concentration (1.5 M, 3M and 5 M) and current (1.5A and 2A) were evaluated. It was observed that synthesis efficiency of NaOH solution with CIMS membrane was higher than that with Nafion membrane, but the durability of CIMS membrane on $Cl_2$ gas was poor. The synthesis efficiency of NaOH solution increased with increasing initial $Na^+$ ion concentration and current, while the efficiency decreased with increasing flow rate using Nafion membrane.

• Resources Recycling
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• v.26 no.3
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• pp.61-68
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• 2017

Cyclone electrowinning method was used to recover tin to metal in hydrochloric acid solution. The effects of flow rate, current density, tin concentration, and hydrochloric acid concentration on the electrowinning of tin were investigated. As the flow rate increased and the concentration of tin and hydrochloric acid decreased, the tin recovery and current efficiency increased. As the current density increased, the recovery rate increased but the current efficiency decreased. Tin can be effectively recovered at flow rates of 18 L/min., $3A/dm^2$, 2.5 g/L Sn, and 5 wt.% HCl.

• Resources Recycling
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• v.26 no.4
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• pp.62-70
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• 2017

A cyclone type electrolytic method was used to recover silver from thiourea-hydrochloric acid mixed solutions. The electrowinning behavior of silver was investigated in different systems, such as the flow rate, current density, silver concentration, thiourea concentration and hydrochloric acid concentration. As the increase of the flow rate, current density and hydrochloric acid concentration, the recovery rate of silver was increased. Whereas, as the increase of silver concentration, the recovery rate of silver was decreased. The thiourea concentration did not affect the Ag recovery and current efficiency. Above 99% of Ag was recovered at the flow rate of 12 L/min., current density of $0.75A/dm^2$, silver concentration of 1.0 g/L, 0.5 M thiourea and 0.1 M hydrochloric acid. In most experimental conditions, silver was recovered as a powder form.

• Journal of the Korean institute of surface engineering
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• v.20 no.3
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• pp.118-126
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• 1987

The Zn-Al composite electroplating was studied by using chloride zinc bath containing metal hydroxides $(Zn(OH)_2,\;Al(OH)_3))$ and aluminium powder. The size of Al powder codeposited in the beaker bath with Al powder of-400 mesh was under 10${\mu}m$. The Zn-Al composite was electro-deposited at 40$^{\circ}C$ in the ranges of current density of 5-50 A/$dm^2$ in the flowing electrolyte. The content of aluminium particles codeposited increased slightly with increasing flow rate of electrolyte from 0.5 m/sec to 1.0 m/sec, and decreased with increasing current density from 5 A/$dm^2$ to 50 A/$dm^2$. The content of aluminium particles codeposited by using the electrolyte containing zinc hydroxide(0.1M) was 2~4 wt%. The Al powder was codeposited mainly near the surface layer of the electrodeposits. The dissolution rate of aluminium particles in the electrolyte containing 0.1M $Zn(OH)_2$ and Boric acid was 0.41 g/l. day in comparison with 1.5 g/l. day dissolution rate in pure chloride bath.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.6
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• pp.835-841
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• 2011

The humidification is essential for performance enhancement of the electrolysis of PEMFC because proton conductivity depends on hydration of the proton exchange membrane. In this study, the humidification experiment did about On/Off control the humidification and dew condensation for PEMFC by using of the membrane humidifiers. As the results, it was possible to approximation control of the humidity by using of the solenoid valve On/Off control on the membrane humidifier. Also the problem on the dew condensation was resolved by approximation humidity control through solenoid valve On/Off control and the removal of the dew condensation in the flow channel was verified through visualization experiment.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.20 no.3
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• pp.257-262
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• 2011

A low capacity generator converted to high capacity of 40m3 is designed and developed in order to use the hydroxy gas in the steel manufacturing process. For efficient design, it is increased from 8 electrode tubes to 10 electrode tubes as well as expanding the diameter of cell integument up to two times bigger, which can increase the amount of hydrogen occurrence per a cell significantly. In addition, circulating pump and pipe, heat exchanger of affiliated SUS material have been used in the circulation of electrolysis catalyst, and circulating cooling section and piping design are also developed. The flame trap is designed into all-in-one suitable check valve in the flow rate of 28-35m3/h and its application is possibly applied in work operation. It is found that the efficiency of generator developed is enhanced substantially up to 84%. It is expected that the application in this field can be expanded significantly by this study.