• Transactions of Materials Processing
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• v.13 no.7
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• pp.600-607
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• 2004

This paper addresses a viscoplastic constitutive model that allows a consistent way of modeling positive and negative rate sensitivities of flow stress concerned with dynamic strain aging. Based on the concept of continuum mechanics, a phenomenological constitutive model includes the use of a yield surface within the framework of unified viscoplasticity theory. To model negative rate sensitivity, rate-dependent back stress is introduced and flow stress in fully developed inelastic deformation regime is thus decomposed into the plastic contribution of rate independency and the viscous one of rate dependency.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2010.05a
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• pp.193-194
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• 2010

• Korea-Australia Rheology Journal
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• v.18 no.2
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• pp.67-81
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• 2006

Using a strain-controlled rheometer, the dynamic viscoelastic properties of aqueous xanthan gum solutions with different concentrations were measured over a wide range of strain amplitudes and then the linear viscoelastic behavior in small amplitude oscillatory shear flow fields was investigated over a broad range of angular frequencies. In this article, both the strain amplitude and concentration dependencies of dynamic viscoelastic behavior were reported at full length from the experimental data obtained from strain-sweep tests. In addition, the linear viscoelastic behavior was explained in detail and the effects of angular frequency and concentration on this behavior were discussed using the well-known power-law type equations. Finally, a fractional derivative model originally developed by Ma and Barbosa-Canovas (1996) was employed to make a quantitative description of a linear viscoelastic behavior and then the applicability of this model was examined with a brief comment on its limitations. Main findings obtained from this study can be summarized as follows: (1) At strain amplitude range larger than 10%, the storage modulus shows a nonlinear strain-thinning behavior, indicating a decrease in storage modulus as an increase in strain amplitude. (2) At strain amplitude range larger than 80%, the loss modulus exhibits an exceptional nonlinear strain-overshoot behavior, indicating that the loss modulus is first increased up to a certain strain amplitude(${\gamma}_0{\approx}150%$) beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (3) At sufficiently large strain amplitude range (${\gamma}_0>200%$), a viscous behavior becomes superior to an elastic behavior. (4) An ability to flow without fracture at large strain amplitudes is one of the most important differences between typical strong gel systems and concentrated xanthan gum solutions. (5) The linear viscoelastic behavior of concentrated xanthan gum solutions is dominated by an elastic nature rather than a viscous nature and a gel-like structure is present in these systems. (6) As the polymer concentration is increased, xanthan gum solutions become more elastic and can be characterized by a slower relaxation mechanism. (7) Concentrated xanthan gum solutions do not form a chemically cross-linked stable (strong) gel but exhibit a weak gel-like behavior. (8) A fractional derivative model may be an attractive means for predicting a linear viscoelastic behavior of concentrated xanthan gum solutions but classified as a semi-empirical relationship because there exists no real physical meaning for the model parameters.

• Biotechnology and Bioprocess Engineering:BBE
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• v.7 no.1
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• pp.52-55
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• 2002

Flow cytometric techniques were used to investigate cell size, protein content and cell cycle behavior of recombinant Saccharomyces cerevisiae strains producing human lysozyme (HLZ). Two different signal sequences, the native yeast $MF\alpha1$ signal sequence and the rat $\alpha-amylase$ signal sequence, were used for secretion of HLZ. The strain containing the rat $\alpha-amylase$ signal sequence showed a higher level of internal lysozyme and lower specific growth rates. Flow cytometric analysis of the total protein content and cell size showed the strain harboring the native yeast signal sequence had a higher total protein content than the strain containing the rat $\alpha-amylase$ signal sequence. Cell cycle analysis indicated that the two lysozyme producing recombinant strains had an increased number of cells in the $G_2+M$ phase of the yeast cell cycle compared with the host strain SEY2102.

• Advanced Composite Materials
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• v.17 no.3
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• pp.191-214
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• 2008

Polypropylene/layered silicate nanocomposites containing maleic anhydride grafted polypropylene were prepared by melt compounding and their rheological behavior was investigated in shear flow. Transient and steady shear flows were simulated numerically by using the K-BKZ integral constitutive equation along with experimentally determined damping functions under dynamic oscillatory and step strain shear flows. Nonlinear shear responses were predicted with the K-BKZ constitutive equation using two different damping functions such as the Wagner and PSM models. It was observed that PP-g-MAH compatibilized PP/layered silicate nanocomposites have stronger and earlier shear thinning and higher steady shear viscosity than pure PP resin or uncompatibilized nanocomposites at low shear rate regions. Strong damping behavior of the PP/layered silicate nanocomposite was predicted under large step shear strain and considered as a result of the strain-induced orientation of the organoclay in the shear flow. Steady shear viscosity of the pure PP and uncompatibilized nanocomposite predicted by the K-BKZ model was in good agreement with the experimental results at all shear rate regions. However, the model was inadequate to predict the steady shear viscosity of PP-g-MAH compatibilized nanocomposites quantitatively because the K-BKZ model overestimates strain-softening damping behavior for PP/layered silicate nanocomposites.

• Korea-Australia Rheology Journal
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• v.14 no.2
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• pp.49-55
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• 2002

To understand the large amplitude oscillatory shear (LAOS) behavior of complex fluids, we have investigated the flow behavior of a network model in the LAOS environment. We applied the LAOS flow to the model proposed by Vaccaro and Marrucci (2000), which was originally developed to describe the system of associating telechelic polymers. The model was found to predict at least three different types of LAOS behavior; strain thinning (G' and G" decreasing), strong strain overshoot (G' and G" increasing followed by decreasing), and weak strain overshoot (G' decreasing, G" increasing followed by decreasing). The overshoot behavior in the strain sweep test, which il often observed in some complex fluid systems with little explanation, could be explained in terms of the model parameters, or in terms of the overall balance between the creation and loss rates of the network junctions, which are continually created and destroyed due to thermal and flow energy. This model does not predict strain hardening behavior because of the finitely extensible nonlinear elastic (FENE) type nonlinear effect of loss rate. However, the model predicts the LAOS behavior of most of the complex fluids observed in the experiments.he experiments.

• Transactions of Materials Processing
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• v.3 no.4
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• pp.427-439
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• 1994

The high temperature deformation behavior of $SiC_p/Al-Si$ composites and Al-Si matrix was studied by hot torsion test in a range of temperature from $270^{\circ}C$ to $520^{\circ}C$ and at strain rate range of $1.2{\times}10_{-3}~2.16{\times}10_{-1}/sec$. The hot restoration mechanisms for both matrix and composites were found to be dynamic recrystallization(DRX) from the investigation of flow curves and microstructural evolutions. The Si precipitates and SiC particles promoted DRX, and the peak strain$({\varepsilon}_p)$ of the composites was smaller than that of the matrix. Flow stresses of $SiC_p/Al-Si$ composites were found to be generally higher than the matrix, but the difference was quite small at higher temperature due to the decrease of capability of load transfer by SiC particles. With increasing temperature, failure strain of matrix and composites are inclined to increase, the increasing value of failure strain for the $SiC_p/Al-Si$ composites was small compared to that of matrix. The stress dependence of both materials on strain rate() and temperature(T) was examined by hyperbolic sine law, $\.{\varepsilon}=A_1[sinh({\alpha}{\cdot}{\sigma})]_n$exp(-Q/RT)

• Geomechanics and Engineering
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• v.29 no.6
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• pp.615-626
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• 2022

The soft clays are widely distributed, and one of the prominent engineering problems is the creep behavior. In order to predict the creep deformation of soft clays in an easier and more acceptable way, a simple creep constitutive model has been proposed in this paper. Firstly, the triaxial creep test data indicated that, the strain-time (𝜀-t) curve showing in the 𝜀-lgt space can be divided into two lines with different slopes, and the time referring to the demarcation point is named as t_EOP. Thereafter, the strain increments occurred after the time t_EOP are totally assumed to be the creep components, and the elastic and plastic strains had occurred before t_EOP. A hyperbolic equation expressing the relationship between creep volumetric strain, stress and time is proposed, with several triaxial creep test data of soft clays verifying the applicability. Additionally, the creep flow law is suggested to be similar with the plastic flow law of the modified Cam-Clay model, and the proposed volumetric strain equation is used to deduced the scaling factor for creep strains. Therefore, a creep constitutive model is thereby established, and verified by successfully predicting the creep principal strains of triaxial specimens.

• Transactions of Materials Processing
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• v.6 no.5
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• pp.395-399
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• 1997

There exists a certain functional relation between Vickers hardness and flow stress in the strain-hardened material. Using this relation, the Vickers hardness values in the strain-hardened material can be converted into the flow stress values in good approximation. Therefore, the information about the flow stress distribution in the material can be easily acquired through a forming experiment. That makes it possible to simulate the process state for a critical moment of cold forging under the given boundary conditions very quickly without calculating the foregoing history of the actual deformation from the beginning.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1997.03a
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• pp.65-68
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• 1997

Vickers hardness is defined as indenting force per unit area indented by a pyramid-shaped diamond at the hardness test. It is well known that Vickers hardness has a direct relation with the flow stress of the strain-hardened material. This relation was theoretically investigated and the result was summerized in a form of algebraic equation in the last paper. In the present paper and experimental validation of this theoretical relation is given along with mathematical formulas for conversion of Vickers hardness into the flow stress in the strain-hardened material for practical use.