• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2010년도 춘계학술발표대회 초록집
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• pp.28-28
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• 2010

The secondary barrier of cargo containment for membrane LNG tank is composed of composite materials such as rigid triplex (rigid secondary barrier, RSB) and flexible triplex (flexible secondary barrier, FSB). RSB and FSB are adhered to each other using an epoxy adherent and the quality of the secondary barrier depends on the bonding strength between them. The bonding strength between RSB and FSB is greatly influenced by the surface condition of RSB prior to joining. In this study, the effect of surface condition prior to joining on the joint strength and the fracture mode occurred between RSB and FSB have been examined in order to establish a proper surface treatment method for improving the bonding strength at the temperature of $-170^{\circ}C$.

• 대한조선학회논문집
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• 제54권5호
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• pp.415-420
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• 2017

Insulation systems in Liquefied Natural Gas Carriers (LNGC) are vulnerable to sloshing impact and fatigue loads because of waves. If gas leaks into the primary barrier, the Flexible Secondary Barrier (FSB) prevents the leakage of gas in this system. Fatigue strength of the FSB largely depends on the behavior of composite materials. In this study, a new system is applied to the FSB using aramid fiber to improve the fatigue strength of the secondary barrier, with the intention of replacing conventional E-glass fibers. The manufacturing method involved varying the ratio of the aramid fiber to the E-glass fiber for optimum design of the FSB. The fatigue tests results of the secondary barrier using aramid fiber were superior to that using E-glass fiber. The statistical analysis is performed to obtain the fatigue test results and estimate the probability of failure as well as the design guideline of LNGC secondary barriers.

• 대한조선학회논문집
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• 제58권3호
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• pp.137-143
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• 2021

In this study, the fracture strength of Flexible Secondary Barrier (FSB) composites was standardized by conducting a distribution analysis of the fracture probability, considering that the fracture strength of FSB composites such as glass fiber reinforced composites is relatively large. As the mechanical performance of FSB composites varies with the fiber direction, 20 replicate uniaxial tensile tests were performed for different temperatures ranging from the ambient to cryogenic conditions, considering the actual operating environment of liquefied natural gas. For the probability statistical analysis, the Weibull distribution analysis derived from the weakest link theory was used, considering the large variance in the fracture strength and brittle fracture behavior. The results of the Weibull distribution analysis were used to calculate the standard fracture strength of the FSB composites for different fiber directions. The findings can help ensure the reliability of the FSB mechanical properties in different fiber directions in the design of the secondary barrier and structural analyses.

• 한국포장학회지
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• 제24권1호
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• pp.13-16
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• 2018

Powdered infant formula is susceptible to oxidation in the presence of oxygen. Even though the product is usually packaged in nitrogen atmosphere, the oxygen ingress through the package layer may occur in case of flexible pouches and affects the oxidation of the product. $O_2$ barrier of the package is thus important variable to protect the product from oxidative deterioration. $O_2$ barrier property was investigated for aluminum-laminated small pillow packs of $3.5{\times}17.5cm$. Storage temperature and combination of primary and secondary packages were evaluated as variables affecting the barrier for conditions of empty pouch flushed with nitrogen. Apparent oxygen transmission rate of the primary package exposed to air was $2.32{\times}10^{-3}mL\;(STP)\;atm^{-1}\;d^{-1}$ at $30^{\circ}C$ and its temperature dependence could be explained by activation energy of $28.5kJ\;mol^{-1}$ in Arrhenius relationship. The additional secondary package of nylon/PE film containing 20 primary packages was ineffective in modulating package $O_2$ transmission and was only marginally helpful when combined with oxygen scavenger. The same was true in suppressing the product oxidation when the primary package was filled with 14 g of the formula.

• 한국산업융합학회 논문집
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• 제27권1호
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• pp.207-212
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• 2024

Recently, with the strengthening of environmental regulations, there has been an increasing interest in eco-friendly energy sources, leading to a trend of the increasing scale of Cargo Containment Systems (CCS) for Liquefied Natural Gas (LNG) carriers. Among these systems, membrane tanks have gained popularity in LNG transport vessels due to their superior spatial utilization and competitiveness. However, due to high initial investment costs and the difficulty in repair in case of damage, a safety layer, the secondary barrier, must be installed without fail. In this study, in order to apply a new secondary barrier to the existing membrane-type LNG CCS, tests were conducted on the fiberglass layer previously used in the Triplex-Flexible Secondary Barrier (FSB), substituting it with basalt fiber. Tensile and vertical tensile tests were performed to assess the newly applied material. Environmental tests were conducted at room temperature (25℃) and extremely low temperatures (-170℃), considering the temperatures to which substances may be exposed during LNG vessel operations. The basalt-FSB produced in this study demonstrated superior results compared to the specifications of the existing product, confirming its potential applicability for implementation.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2017년도 추계학술발표회
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• pp.36-36
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• 2017

• 대한조선학회논문집
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• 제58권4호
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• pp.206-213
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• 2021

Recently, although the size of the LNG Cargo Containment System (CCS) has been increasing, the secondary barrier is reported to remain unchanged, and the conventional Flexible Secondary Barrier (FSB) used in Mark-III type has been pointed out to be vulnerable to failure owing to thermal and cyclic loads. In this respect, a tensile test was carried out to verify the reinforcing effect of FSB using aramid fiber on weft compared to the conventional FSB. In order to consider the LNG leakage situation, a series of tensile tests were conducted from ambient to cryogenic temperature, and mechanical properties were evaluated for each fiber direction on account of anisotropy. Tensile behavior and fracture analyses were performed to confirm the mechanical properties of each material according to temperature. Tensile test results proved that replacing the aramid fiber instead of E-glass fiber used on weft is effective in enhancing the mechanical properties.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.100-101
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• 2012

The plasma damage free and room temperature processedthin film deposition technology is essential for realization of various next generation organic microelectronic devices such as flexible AMOLED display, flexible OLED lighting, and organic photovoltaic cells because characteristics of fragile organic materials in the plasma process and low glass transition temperatures (Tg) of polymer substrate. In case of directly deposition of metal oxide thin films (including transparent conductive oxide (TCO) and amorphous oxide semiconductor (AOS)) on the organic layers, plasma damages against to the organic materials is fatal. This damage is believed to be originated mainly from high energy energetic particles during the sputtering process such as negative oxygen ions, reflected neutrals by reflection of plasma background gas at the target surface, sputtered atoms, bulk plasma ions, and secondary electrons. To solve this problem, we developed the NBAS (Neutral Beam Assisted Sputtering) process as a plasma damage free and room temperature processed sputtering technology. As a result, electro-optical properties of NBAS processed ITO thin film showed resistivity of $4.0{\times}10^{-4}{\Omega}{\cdot}m$ and high transmittance (>90% at 550 nm) with nano- crystalline structure at room temperature process. Furthermore, in the experiment result of directly deposition of TCO top anode on the inverted structure OLED cell, it is verified that NBAS TCO deposition process does not damages to the underlying organic layers. In case of deposition of transparent conductive oxide (TCO) thin film on the plastic polymer substrate, the room temperature processed sputtering coating of high quality TCO thin film is required. During the sputtering process with higher density plasma, the energetic particles contribute self supplying of activation & crystallization energy without any additional heating and post-annealing and forminga high quality TCO thin film. However, negative oxygen ions which generated from sputteringtarget surface by electron attachment are accelerated to high energy by induced cathode self-bias. Thus the high energy negative oxygen ions can lead to critical physical bombardment damages to forming oxide thin film and this effect does not recover in room temperature process without post thermal annealing. To salve the inherent limitation of plasma sputtering, we have been developed the Magnetic Field Shielded Sputtering (MFSS) process as the high quality oxide thin film deposition process at room temperature. The MFSS process is effectively eliminate or suppress the negative oxygen ions bombardment damage by the plasma limiter which composed permanent magnet array. As a result, electro-optical properties of MFSS processed ITO thin film (resistivity $3.9{\times}10^{-4}{\Omega}{\cdot}cm$, transmittance 95% at 550 nm) have approachedthose of a high temperature DC magnetron sputtering (DMS) ITO thin film were. Also, AOS (a-IGZO) TFTs fabricated by MFSS process without higher temperature post annealing showed very comparable electrical performance with those by DMS process with $400^{\circ}C$ post annealing. They are important to note that the bombardment of a negative oxygen ion which is accelerated by dc self-bias during rf sputtering could degrade the electrical performance of ITO electrodes and a-IGZO TFTs. Finally, we found that reduction of damage from the high energy negative oxygen ions bombardment drives improvement of crystalline structure in the ITO thin film and suppression of the sub-gab states in a-IGZO semiconductor thin film. For realization of organic flexible electronic devices based on plastic substrates, gas barrier coatings are required to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency flexible AMOLEDs needs an extremely low water vapor transition rate (WVTR) of $1{\times}10^{-6}gm^{-2}day^{-1}$. The key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required (under ${\sim}10^{-6}gm^{-2}day^{-1}$) is the suppression of nano-sized defect sites and gas diffusion pathways among the grain boundaries. For formation of high quality single inorganic gas barrier layer, we developed high density nano-structured Al2O3 single gas barrier layer usinga NBAS process. The NBAS process can continuously change crystalline structures from an amorphous phase to a nano- crystalline phase with various grain sizes in a single inorganic thin film. As a result, the water vapor transmission rates (WVTR) of the NBAS processed $Al_2O_3$ gas barrier film have improved order of magnitude compared with that of conventional $Al_2O_3$ layers made by the RF magnetron sputteringprocess under the same sputtering conditions; the WVTR of the NBAS processed $Al_2O_3$ gas barrier film was about $5{\times}10^{-6}g/m^2/day$ by just single layer.