• 한국산학기술학회논문지
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• 제11권10호
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• pp.4041-4046
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• 2010

유연한 알콕시 곁사슬을 갖는 전방향족 폴리에스터가 direct polycondensation에 의하여 합성되었으며, 합성된 중합체들은 $^1H$-NMR, FT-IR, DSC, TGA, 편광현미경 및 X-ray 분석기에 의하여 조사되었다. 1,1,2,2-테트라클로로에탄(TCE)을 용매로 사용하여 측정된 중합체의 고유점성도(${\eta}_{inh}$)는 0.46~2.41 dL/g의 값을 나타내었다. 곁사슬을 갖는 중합체들은 두 개의 용융전이 즉, 고체상-sanidic 액정상으로의 전이 ($T_{m1}$)와 sanidic 액정상-nematic 액정상으로의 전이 ($T_{m2}$)를 나타내었으며, 알콕시 곁사슬의 길이가 증가함에 따라 상전이온도들은 감소하고, 유기용매에 의한 용해도는 증가하는 경향을 나타내었다. X-ray 분석에서, $2{\theta}\;{\simeq}5$와 $2{\theta}\;{\simeq}20$ 피이크는 각각 중합체 주사슬과 긴 곁사슬의 결정화에 의한 것으로 나타났다.

• Korea-Australia Rheology Journal
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• 제20권3호
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• pp.109-116
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• 2008

The effect of intermolecular aggregation induced by hydrophobic and electrostatic interactions on shear and elongational flow properties of aqueous acrylic thickener solutions is discussed. Complex shear modulus is determined at frequencies up to $10^4$ rad/s employing oscillatory squeeze flow. Extensional flow behavior is characterized using Capillary Break-up Extensional Rheometry. Aqueous solutions of poly(acrylic acid)(PAA)/poly(vinylpyrrolidone-co-vinylimidazole) (PVP-VI) mixtures exhibit unusual rheological properties described here for the first time. Zero-shear viscosity of the mixtures increases with decreasing pH and can exceed that of the pure polymers in solution by more than two orders of magnitude. This is attributed to the formation of complexes induced by electrostatic interactions in the pH range, where both polymers are oppositely charged. PAA/PVP-VI mixtures are compared to the commercial thickener Sterocoll FD (BASF SE), which is a statistical co-polymer including (meth) acrylic acid and ethylacrylate (EA) forming aggregates in solution due to "sticky" contacts among hydrophobic EA-sequences. PAA/PVP-VI complexes are less compact and more deformable than the hydrophobic Sterocoll FD aggregates. Solutions of PAA/PVP-VI exhibit a higher zero-shear viscosity even at lower molecular weight of the aggregates, but are strongly shear-thinning in contrast to the weakly shear-thinning solutions of Sterocoll FD. The higher ratio of characteristic relaxation times in shear and elongation determined for PAA/PVP-VI compared to Sterocoll FD solutions reflects, that the charge-induced complexes provide a much stronger resistance to extensional flow than the aggregates formed by hydrophobic interactions. This is most likely due to a break-up of the latter in extensional flow, while there is no evidence for a break-up of complexes for PAA/PVP-VI mixtures. These flexible aggregates are more suitable for the stabilization of thin filaments in extensional flows.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.335-335
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• 2011

Instability of a thin film attached to a compliant substrate often leads to emergence of exquisite wrinkle patterns with length scales that depend on the system geometry and applied stresses. However, the patterns that are created using the current techniques in polymer surface engineering, generally have low aspect ratio of undulation amplitude to wavelength, thus, limiting their application. Here, we present a novel and effective method that enables us to create wrinkles with a desired wavelength and high aspect ratio of amplitude over wavelength as large as to 2.5:1. First, we create buckle patterns with high aspect ratio of amplitude to wavelength by deposition of an amorphous carbon film on a surface of a soft polymer poly(dimethylsiloxane) (PDMS). Amorphous carbon films are used as a protective layer in structural systems and biomedical components, due to their low friction coefficient, strong wear resistance against, and high elastic modulus and hardness. The deposited carbon layer is generally under high residual compressive stresses (~1 GPa), making it susceptible to buckle delamination on a hard substrate (e.g. silicon or glass) and to wrinkle on a flexible or soft substrate. Then, we employ glancing angle deposition (GLAD) for deposition of a high aspect ratio patterns with amorphous carbon coating on a PDMS surface. Using this method, pattern amplitudes of several nm to submicron size can be achieved by varying the carbon deposition time, allowing us to harness patterned polymers substrates for variety of application. Specifically, we demonstrate a potential application of the high aspect wrinkles for changing the surface structures with low surface energy materials of amorphous carbon coatings, increasing the water wettability.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.108-109
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• 2012

This talk will begin with the demonstration of facile synthesis of silicon nanostructures using the magnesiothermic reduction on silica nanostructures prepared via self-assembly, which will be followed by the characterization results of their performance for energy storage. This talk will also report the fabrication and characterization of highly porous, stretchable, and conductive polymer nanocomposites embedded with carbon nanotubes (CNTs) for application in flexible lithium-ion batteries. It will be presented that the porous CNT-embedded PDMS nanocomposites are capable of good electrochemical performance with mechanical flexibility, suggesting these nanocomposites could be outstanding anode candidates for use in flexible lithium-ion batteries. Directed self-assembly (DSA) of block copolymers (BCPs) can generate uniform and periodic patterns within guiding templates, and has been one of the promising nanofabrication methodologies for resolving the resolution limit of optical lithography. BCP self-assembly processing is scalable and of low cost, and is well-suited for integration with existing semiconductor manufacturing techniques. This talk will introduce recent research results (of my research group) on the self-assembly of Si-containing block copolymers for the achievement of sub-10 nm resolution, fast pattern generation, transfer-printing capability onto nonplanar substrates, and device applications for nonvolatile memories. An extraordinarily facile nanofabrication approach that enables sub-10 nm resolutions through the synergic combination of nanotransfer printing (nTP) and DSA of block copolymers is also introduced. This simple printing method can be applied on oxides, metals, polymers, and non-planar substrates without pretreatments. This talk will also report the direct formation of ordered memristor nanostructures on metal and graphene electrodes by the self-assembly of Si-containing BCPs. This approach offers a practical pathway to fabricate high-density resistive memory devices without using high-cost lithography and pattern-transfer processes. Finally, this talk will present a novel approach that can relieve the power consumption issue of phase-change memories by incorporating a thin $SiO_x$ layer formed by BCP self-assembly, which locally blocks the contact between a heater electrode and a phase-change material and reduces the phase-change volume. The writing current decreases by 5 times (corresponding to a power reduction of 1/20) as the occupying area fraction of $SiO_x$ nanostructures varies.

• 한국도로학회논문집
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• 제6권4호
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• pp.91-100
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• 2004

본 연구는 차도용 칼라 역청 콘크리트의 적용성을 평가하기 위하여 수행되었다. 칼라 역청 포장은 차도가 아닌 보행자 도로나 자전거 도로에 사용되어 왔다 본 연구에서 바인더 개질 및 혼합물 강성의 증진을 위하여 두 가지폴리머가 사용되었다. 또한 갭입도 혼합물에서 나타나는 침강현상을 방지하기 위하여 폐신문지를 사용하였다 마샬안정도, 간접인장강도, 동결-융해 및 인공노화 처리 전 후의 인장강도비, 소성변형 저항성, 피로수명을 측정하였다. LDPE 개질된 칼라 역청 콘크리트는 일반 아스팔트 혼합물에 비해 높은 안정도와 인장강도를 나타냈으며, 특히 소성변형 저항성에서 많은 향상을 가져왔다. Rosin 개질된 칼라 역청 콘크리트는 일반 아스팔트 혼합물보다 높은 안정도와 동결융해저항성을 보였으며, 특히 간접인장강도에서 많은 향상을 보였다. LDPE +Rosin의 개질은 거의 대부분의 역학적 특성의 증가를 가져왔다. 따라서 본 연구에서 사용된 칼라 역청 콘크리트 혼합물은 기존 AP-3를 사용한 아스팔트 콘크리트 혼합물과 비교해 역학적 특성이 비슷하였으며, 모든 혼합물은 차도용 시방 규정을 만족하였다. 그리고, 이를 LDPE와 Rosin으로 개질할 경우 포장의 공용성능이 더욱 향상될 것으로 보여 차도용으로 충분히 사용 가능함을 확인하였다.

• 대한기계학회논문집B
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• 제36권5호
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• pp.539-543
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• 2012

셀룰로오스 EAPap 작동기는 생체 모방형 작동기의 하나로 생체적합하고 가볍고 비교적 낮은 전압에서도 큰 변위를 발생시킨다는 장점을 가지고 있다. 셀룰로오스를 재생하면서 셀룰로오스 파이버를 배열함으로써 압전 종이를 만들었다. 한편 셀룰로오스에 탄소나노튜브, 산화금속 나노분말, 전도성 고분자, 이온성 유체등을 물리적, 화학적으로 결합시켜 다양한 하이브리드 나노복합재를 만들었다. 본 논문에서는 셀룰로오스 EAPap 의 제조공정 및 이를 응용한 바이오센서, 화학센서, 유연트랜지스터, 그리고 작동기의 응용 디바이스에 대해 소개한다. 또한 셀룰로오스 EAPap 을 무선으로 구동하는 기술에 대해 소개한다. 이는 생체모방로봇, 정찰 등에 활용될 수 있다.

• 공업화학
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• 제3권4호
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• pp.694-700
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• 1992

Palladium 촉매에 의한 CO Insertion Heck reaction을 고분자 중합에 응용하여 가공성이 좋은 고강도 엔지니어링 플라스틱으로 응용 가능한 flexible spacer를 가진 aromatic polyamide와 Polyester를 합성할 수 있었다. 촉매로서 dichlorobis(triphenyl phosphine) palladium(II) $(PdCl_2(PPh_3)_2)$와 Palladium chloride($PdCl_2$)를 사용하였고, 이 중합 시스템은 똑같은 조건에서 polyamide와 polyester를 합성 할 수 있는 장점이 있으므로 그 중합체의 열적성질을 DSC, TGA 등으로 조사하였는데 곁사슬이 있지 않은 aromatic polyamide와 Polyester는 amide와 ester 결합의 차이에도 불구하고 전이온도등이 거의 같았다. Hexyl부터 hexadecyl까지 alkyl 곁사슬을 2,5 위치에 이중으로 가진 phenylene dibromide와 Phenylene diamine으로부터 중합체를 합성하였는데 치환기가 없는 경우에 비하여 전이온도가 감소하였고, alkyl side chain이 hexadecyl인 경우는 뚜렷한 융점을 확인할 수 있었다.

• Composites Research
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• 제37권3호
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• pp.190-196
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• 2024

분리판은 바나듐 레독스 흐름전지(VRFB) 스택 내 셀의 전기적 통로 및 구조적 지지 역할 수행하는 매우 중요한 부품 중 하나이다. 흑연 소재는 전기 전도성이 뛰어나 분리판에 주로 사용되지만, 셀 스택에서 전극과 분리판 사이에 높은 계면 접촉 저항(ICR)이 발생하여 VRFB의 성능에 심각한 제한이 존재한다. 본 연구에서는 ICR의 한계를 해결할 수 있는 일체형 전극-분리판 조립체를 개발하는 것을 목표로 하였다. 일체형 조립체는 핫 프레스 방법을 활용하여 열가소성 및 열경화성 폴리머와 단일 탄소 펠트를 사용하여 제작하였다. 실험 결과, 일체형 조립체가 연속적인 전기 경로로 인해 감소된 전체 저항을 나타냄을 확인하였다. 또한, 충/방전 셀 테스트 결과에서 일체형 조립체는 향상된 셀 성능을 보여주었다. 따라서 개발된 일체형 전극-분리판 조립체는 기존의 분리판 및 전극 조립체를 대체할 수 있을 것으로 판단된다.

• International Journal of Control, Automation, and Systems
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• 제5권4호
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• pp.429-435
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• 2007

A number of different alternative actuation methods have been under active development for some specific applications where the traditional electromechanical actuators are difficult to apply. Recently, many of these substitutes are trying to employ new smart materials like electroactive polymers. However most of the polymeric materials are flexible and vulnerable so that they normally can not sustain external forces. Although the materials have shown a good potential to be used for alternative actuation mechanisms, no tangible industrial application is yet presented because of the reason. A conceptual design for a rectilinear motion actuator using dielectric elastomer is presented in this article. The introduced design concept might enable to produce fairly controllable rectilinear motions for various applications and the presented prototype actuator system is fully packaged in a small unit and controlled by a standard communication interface.

• Advances in materials Research
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• 제3권4호
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• pp.233-242
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• 2014

Magnetic and conducting aniline sulfide resin cross-linked (ASC-Fe3O4) nanocomposite has been prepared in the presence of aniline sulfide resin (ASR), aniline, $Fe_3O_4$ coated by polyethylene glycol (PEG) and initiator. The magnetic properties of the resulting composites showed ferromagnetic behavior, such as high-saturated magnetization (Ms= 41 emu/g), and coercive force (Hc=1.5 Oe). The saturated magnetization was increased by increasing of $Fe_3O_4$ content and decreased by increasing aniline ratio. The transmission electron micrograph (TEM) and X-ray diffraction proved that nanometer-sized about 20-30 nm $Fe_3O_4$ in the composite. The average size of ASC-$Fe_3O_4$ nanocomposite with core-shell structure was about 50-60 nm, and polydisperse. This approach may also be extended to the synthesis and modification of other polymers. Electrical conductivity of aniline sulfide resin cross-linked (ASC) nanocomposite has been studied by four-point probe method and produced $3.3{\times}10^{-4}S/cm$ conductivity for it. The conductivity of the composites at room temperature depended on the $Fe_3O_4$, aniline ratio and doping degree. The thermogravimetry analysis (TGA) results showed that this resin is thermal resistance near of $500^{\circ}C$. So, It can be used for resistance thermal coating for military applications. $Fe_3O_4$-PASC nanocomposite has been flexible structure with electrical and magnetic properties.