• Journal of Energy Engineering
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• v.23 no.4
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• pp.169-175
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• 2014

For the safe handling of ethylbenzene, this study was investigated the explosion limits of ethylbenzene in the reference data. And the lower flash points, upper flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of ethylbenzene by using Setaflash closed-cup and Pensky-Martens closed-cup testers were experimented $20^{\circ}C$ and $22^{\circ}C$, respectively. The lower flash points ethylbenzene by using Tag and Cleveland open cup testers were experimented $25^{\circ}C$ and $28^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for ethylbnezene. The experimental AIT of ethylbenzene was $430^{\circ}C$. The calculated LEL and UEL by using the measured lower flash point and upper flash point were 0.93 Vol.% and 7.96 Vol.%, respectively.

• Journal of the Korean Society of Safety
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• v.29 no.3
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• pp.114-120
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• 2014

The purpose of this study is to conduct the study of the combustion and thermal characteristics through transportation oil for the analysis of fire hazard. Transportation oil breaks down into fuels such as diesel for civilian demands, gasoline, DF1(diesel for military), high sulfur diesel(for marine), kerosene and JP1(for aviation), and lubricants like brake fluid, power steering oil, engine oil, and automatic and manual transmission oil. The experiments of flash point, ignition point, flame duration time, heat release rate were carried out using TAG closed cup flash point tester(AFP761), Cleveland open cup auto flash point analyzer(AFP762), KRS-RG-9000 and Dual cone calorimeter. As a result, the fuel's ignition points were lower than lubricants, especially that of gasoline was not conducted as it has below zero one. Gasoline has the highest ignition point of about $600^{\circ}C$, while the other fuels showed $400{\sim}465^{\circ}C$. For flame duration time, lubricants had over 300 seconds, but fuels had less than 300 seconds except high sulfur diesel(350 seconds). Total heat release rate ranged $287{\sim}462kW/m^2$ for lubricants and gasoline showed the highest total heat release rate, $652kW/m^2$.

• Journal of the Korean Institute of Gas
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• v.18 no.3
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• pp.75-81
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• 2014

For the safe handling of isobutylalcohol(IBA), this study was investigated the explosion limits of isobutylalcohol in the reference data. And the lower flash points, upper flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. By using the literatures data, the lower and upper explosion limits of isobutylalcohol recommended 1.7 Vol% and 10.9 Vol.%, respectively. The lower flash point of isobutylalcohol by using Setaflash and Penski-Martens closed-cup testers were experimented $25^{\circ}C$ and $30^{\circ}C$, respectively. The lower flash point isobutylalcohol by using Tag and Cleveland open cup testers were experimented $36^{\circ}C$ and $39^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for isobutylalcohol. The experimental AIT of isobutylalcohol was $400^{\circ}C$.

• Journal of the Korean Institute of Gas
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• v.11 no.4
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• pp.7-11
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• 2007

There has been a report of fire and explosion accident in regenerated thermal oxidizer (RTO). This paper was to investigate accident causes of RTO in the resin re-treatment process. The experiments carried out physicochemical properties and thermal stability analyses by using flash point tester, flammable range apparatus, autoignition tester, GC/MSD and thermal screening unit. We inferred causes of fire and explosion from the regenerated thermal oxidizer to prevent an accident of its process.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.17-24
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• 2019

The combustion properties of the flammable substance used in industrial fields include lower/upper flash point, lower/upper explosion limit, autoignition temperature(AIT), fire point, and minimum oxygen concentration(MOC) etc.. The accurate assessment of these characteristics should be made for process and worker safety. In this study, tert-amylalcohol(TAA), which is widely used as a solvent for epoxy resins, oxidizers of olefins, fuel oils and biomass, was selected. The reason is that there are few researches on the reliability of combustion characteristics compared to other flammable materials. The flash point of the TAA was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of the TAA was measured by ASTM 659E. The lower/upper explosion limits of the TAA was estimated using the measured lower/upper flash points by Setaflash tester. The flash point of the TAA by using Setaflash and Pensky-Martens closed-cup testers were experimented at 19 ℃ and 21 ℃, respectively. The flash points of the TAA by Tag and Cleveland open cup testers were experimented at 28 ℃ and 34 ℃, respectively. The AIT of the TAA was experimented at 437 ℃. The LEL and UEL calculated by using lower and upper flash point of Setaflash were calculated at 1.10 vol% and 11.95 vol%, respectively.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.237-242
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• 2009

Various type of alternative fuel have been developed due to exhaustion of fossil fuel reserves and high oil price. Biodiesel is produced from the reaction of triglyceride, which is main component of animal fat and vegetable oil, and methanol by methanolysis as it is known for eco- friendly fuel for alternative petrodiesel. In this work, it was analyzed for the characteristics of the blended biodiesel with domestic petrodiesel according to blending ratio. Density, kinematic viscosity and flash point were increased with increasing the content of biodiesel. But the characteristic of blended biodiesel fuel were changed to aggravate in low temperature. Also, the derived cetane number(DCN) from IQT was increased by added biodiesel. Especially, the DCN of biodiesel from palm oil showed 71.26.