• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2013.04a
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• pp.41-41
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• 2013

화학산업이 발달함에 따라 화학 산업 현장에서 사용되고 있는 가연성물질들의 여러 가지 화재 및 폭발 위험이 증가되고 있으며, 화재 및 폭발의 예방 안전을 위한 화학공정설계 및 대처에 있어, 물질의 연소특성치 데이터를 필요로 한다. 인화점은 가연성 액체를 다루는 공정에서 안전한 취급과 사고방지를 위해 중요한 자료가 되며, 화재의 위험을 나타내는 지표로서 가연성액체의 액면 가까이서 인화할 때 필요한 증기를 발산하는 액체의 최저온도, 그리고 가연성증기의 포화증기압이 공기와 혼합기체의 폭발한계 하한농도와 같게 되는 온도로 정의한다. 본 연구에서는 2성분계 혼합물에 대해 인화점을 측정하였고, 측정값을 Raoult의 법칙과 다중회귀분석(Multiple Regression)을 도입하여 이론값과 비교 하였다. 따라서 본 연구에서 제시된 방법론에 의해 아직까지 밝혀지지 않은 순수가연성액체와 가연성혼합물의 인화점을 예측하는 방법을 전개하고자 하며, 실험에서 찾고자하는 자료에 도움을 주고자 한다. 본 연구를 바탕으로 혼합물의 인화점 예측 방법과 실험에서 측정한 자료를 화재 및 폭발을 방지하는 기초 자료로 제공하고자하며, 산업현장에서 취급되고 있고 위험성 평가가 되지 않은 보다 많은 물질에 대한 이론 및 실험 연구에 활용 되도록 하는데 그 목적이 있다.

• Journal of Korea Water Resources Association
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• v.50 no.1
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• pp.17-28
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• 2017

A recent increase in extreme weather events and flash floods associated with the enhanced climate variability results in an increase in climate-related disasters. For these reasons, various studies based on a high resolution weather radar system have been carried out. The weather radar can provide estimates of precipitation in real-time over a wide area, while ground-based rain gauges only provides a point estimate in space. Weather radar is thus capable of identifying changes in rainfall structure as it moves through an ungauged basin. However, the advantage of the weather radar rainfall estimates has been limited by a variety of sources of uncertainty in the radar reflectivity process, including systematic and random errors. In this study, we developed an ensemble radar rainfall estimation scheme using the multivariate copula method. The results presented in this study confirmed that the proposed ensemble technique can effectively reproduce the rainfall statistics such as mean, variance and skewness (more importantly the extremes) as well as the spatio-temporal structure of rainfall fields.

• 한국지구과학회:학술대회논문집
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• 2005.09a
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• pp.304-314
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• 2005

The present study aims to develop animation module-based teaching-learning materials for a unit of middle school 3rd grade science, which contains the movement of the solar system, through the utilization of various forms of multimedia elements. The developed materials consist of 12 in total flash animation modules covering ‘movement of the Earth,’ ‘movement of the Moon,’ movement of the Planets,‘ etc. To analyze the student responses to the science classes to which the developed animation modules were to be applied, the researcher selected for subjects two third-grade classes that were made up of 60 students and later divided for an experimental group and a control group in a middle school located in Jeonju. The experimental group was treated with the animation module-based lessons developed in the present study while the control group was taught in the traditional teacher-centered ways. Tests for the science-related attitudes of the two groups were administered and the results showed that the mean score of the experimental group was significantly higher than the mean score of the control group (p<0.05) in the categories of ‘interest’ and ‘scientific attitude’. It was thus believed that the animation module-based teaching has a positive effect on the categories of ‘interest’ and ‘scientific attitude’. To assess the qualitative dimension of the developed materials, the researcher subjected them to the utilization of the 30 local science teachers and afterwards a survey was done with the 8 crucial items taken from the WBI evaluation test developed by Multimedia Education Support Center in 1998. The result was broadly positive in terms of lesson design and from a technological point of view.

• Journal of the Korean Institute of Gas
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• v.10 no.2 s.31
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• pp.33-39
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• 2006

For the safety design and operation of many gas process, it is necessary to know certain explosion limit, flash point, auto ignition temperature and minimum oxygen concentration of handling substances. Also it is necessary to know explosion limit at high temperature and pressure. For the safe handling of propane, explosion limit and autoignition temperature of combustion characteristics for propane were investigated. By using the literatures data, the lower and upper explosion limits of propane recommended 2.0 vol% and 10.0 vol%, respectively. Also autoignition temperatures of propane with ignition sources recommended $450^{\circ}C$ at the electrically heated cruicible fumace(the whole surface heating) and recommended about $960^{\circ}C$ at the local hot surface. The new equations for predicting the temperature and the pressure dependence of the explosion limits of propane are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.3
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• pp.268-277
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• 2016

This paper aims at presenting bunkering educational programs for LNG fueled ship taking into consideration existing similar education programs and safety systems at the international level in order to enhance both seafarers' and vessels' safety. Heavy fuel oil has typically been used as fuel of ship propulsion. The competitiveness of the fuel oil is recently getting weak in terms of cost and environmental aspects. Liquefied natural gas is introduced for ship propulsion in the maritime field as a new energy source replacing heavy fuel oil. In order to prepare for installation and operation of LNG fueled propulsion ship on board, International Maritime Organization has discussed this subject for about 10 years. As a result of the discussion on such ships in IMO, the International Code of Safety for Ships Using Gases or Other Low-Flash-Point Fuels entered into force on the year 2015. International organizations and several countries therefore drives actively entire researches and other businesses with a view to providing equipment and system of LNG bunkering. The systems are divided into ship-to-ship transfer, terminal / pipeline-to-ship transfer and truck-to-ship transfer. By adopting transfer system of LNG bunkering, many human resources will be needed in these areas on scene as well as on managing, operating, trading, finance, design of LNG bunkering industries. LNG bunkering is just in the beginning stage. Hence, this paper reviews and proposes professional educational programs of LNG bunkering in consideration of technical aspects of the safety system of LNG bunkering based on the types of bunkering systems.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.237-242
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• 2009

Various type of alternative fuel have been developed due to exhaustion of fossil fuel reserves and high oil price. Biodiesel is produced from the reaction of triglyceride, which is main component of animal fat and vegetable oil, and methanol by methanolysis as it is known for eco- friendly fuel for alternative petrodiesel. In this work, it was analyzed for the characteristics of the blended biodiesel with domestic petrodiesel according to blending ratio. Density, kinematic viscosity and flash point were increased with increasing the content of biodiesel. But the characteristic of blended biodiesel fuel were changed to aggravate in low temperature. Also, the derived cetane number(DCN) from IQT was increased by added biodiesel. Especially, the DCN of biodiesel from palm oil showed 71.26.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.5
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• pp.447-452
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• 2016

The use of gas as fuel, particularly liquefied natural gas (LNG), has increased in recent years owing to its lower sulfur and particulate emissions compared to fuel oil or marine diesel oil. LNG is a low temperature, volatile fuel with very low flash point. The major challenges of using LNG are related to fuel bunkering, storing, and handling during ship operation. The main components of an LNG fuel system are the bunkering equipment, fuel tanks, vaporizers/heaters, pressure build-up units (PBUs), and gas controlling units. Low-pressure dual-fuel (DF) engines are predominant in small LNG-powered vessels and have been operating in many small- and medium-sized ferries or LNG-fueled generators.(Tamura, K., 2010; Esoy, V., 2011[1][2]) Small ships sailing at coast or offshore rarely have continuous operation at constant engine load in contrast to large ships sailing in the ocean. This is because ship operators need to change the engine load frequently due to various obstacles and narrow channels. Therefore, controlling the overall system performance of a gas supply system during transient operations and decision of bunkering time under a very poor infrastructure condition is crucial. In this study, we analyzed the fuel consumption, the system stability, and the dynamic characteristics in supplying fuel gas for operating conditions with frequent engine load changes using a commercial analysis program. For the model ship, we selected the 'Econuri', Asia's first LNG-powered vessel, which is now in operation at Incheon Port of South Korea.

• Journal of ILASS-Korea
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• v.19 no.1
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• pp.1-8
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• 2014

Liquefied petroleum gas (LPG) is regarded as an alternative fuel for spark ignition engine due to similar or even higher octane number. In addition, LPG has better fuel characteristics including high vaporization characteristic and low carbon/hydrogen ratio leading to a reduction in carbon dioxide emission. Recently, development of LPG direct injection system started to improve performance of vehicles fuelled with LPG. However, spray characteristics of LPG were not well understood, which is should be known to develop injector for LPG direct injection engines. In this study, effects of operation condition including ambient pressure, temperature, and injection pressure on spray properties of n-butane were evaluated and compared to gasoline in a multi-hole injector. As general characteristics of both fuels, spray penetration becomes smaller with an increase of ambient pressure as well as a reduction in the injection pressure. However, it is found that evaporation of n-butane was faster compared to gasoline under all experimental condition. As a result, spray penetration of n-butane was shorter than that of gasoline. This result was due to higher vapor pressure and lower boiling point of n-butane. On the other hand, spray angle of both fuels do not vary much except under high ambient temperature conditions. Furthermore, spray shape of n-butane spray becomes completely different from that of gasoline at high ambient temperature conditions due to flash boiling of n-butane.

• Applied Chemistry for Engineering
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• v.19 no.6
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• pp.617-623
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• 2008

GTL (gas-to-liquid) fuel produced by the Fischer-Tropsch reaction of carbon monoxide (CO) and hydrogen ($H_2$) is expected to be one of the environmental friendly biomass based alternatives and blended to petrodiesel. In this study, the characteristic of the fuel was analyzed by its concentration differences after blending petrodiesel in domestic market with different amounts of GTL fuel which produced from Shell. Gas chromatography shows that GTL fuel consists of longer paraffin chain than common diesel. GTL fuel showed a high flash point, distillation, kinematic viscosity, and derived cetane number. In addition, GTL fuel showed lower lubricity due to low sulfur content.

• Applied Chemistry for Engineering
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• v.8 no.2
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• pp.220-229
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• 1997

Extraction of valuable light hydrocarbon from atmospheric residue using pentane as a solvent has been carried out. The SIMDIS was used to calculate the true boiling point of atmospheric residue containing complex components before the modeling of the extraction process could by performed. In order to simplify the procedure, modeling was adopted and a lumping method was used, such that a large number of compounds were divided into similar component classes called pseudocomponents. The modeling of the extraction process of the atmospheric residue-pentane system was based on the isothermal flash calculation, and the Peng-Robinson equation of state was used to calculate the fugacity coefficient of vapor and liquid phase during calculation steps of modeling. The agreement between the experiments and the calculations was reasonable considering the uncertainties involved in modeling such complex processes.