• Fire Science and Engineering
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• v.27 no.3
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• pp.47-51
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• 2013

The explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. The explosion limit of organic acids have been shown to be correlated the heat of combustion and the chemical stoichiometric coefficients. In this study, the lower explosion and upper explosion limits of organic acids were predicted by using the heat of combustion and chemical stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other organic acids.

• Fire Science and Engineering
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• v.23 no.5
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• pp.50-56
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• 2009

Explosion limit and autoignition temperature are the major properties used to determine the fire and explosion hazards of the flammable substances. Explosion limit and autoignition temperature for safe handling of ethylene were investigated. By using the literatures data, the lower and upper explosion limits of ethylene recommended 2.6vol% and 36vol%, respectively. Also autoignition temperatures of ethylene with ignition sources recommended $420^{\circ}C$ at the electrically heated crucible furnace (the whole surface heating) and recommended about $800^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosion limits for ethylene are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• Journal of the Korean Institute of Gas
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• v.19 no.2
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• pp.5-11
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• 2015

The explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. The explosion limit of aldehydes have been shown to be correlated the heat of combustion and the chemical stoichiometric coefficients. In this study, the lower explosion and upper explosion limits of aldehydes were predicted by using the heat of combustion and chemical stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data above determination coefficient 0.99. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the aldehydes.

• Journal of the Society of Disaster Information
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• v.20 no.1
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• pp.47-59
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• 2024

Purpose: This study aims to propose measures for the prevention of fire and explosion accidents within manufacturing facilities by improving the existing classification criteria for hazardous locations based on the leakage patterns of flammable liquids. The objective is to suggest ways to safely manage ignition sources and combustible materials. Method: The hazardous locations were calculated using "KS C IEC 60079-10-1," and the calculated explosion hazard distances were visualized in 3D. Additionally, the formula for the atmospheric dispersion of flammable vapors, as outlined in "P-91-2023," was utilized to calculate the dispersion rates within the hazardous locations represented in 3D. Result: Visualization of hazardous locations in 3D enabled the identification of blind spots in the floor plan, facilitating immediate recognition of ignition sources within these areas. Furthermore, when calculating the time taken for the Lower Explosive Limit (LEL) to reach within the volumetric space of the hazardous locations represented in 3D, it was found that the risk level did not correspond identically with the explosion hazard distances. Conclusion: Considering the atmospheric dispersion of flammable liquids, it was concluded that safety management should be conducted. Therefore, a method for calculating the concentration values requiring detection and alert based on realistically achievable ventilation rates within the facility is proposed.

• Journal of ILASS-Korea
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• v.20 no.2
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• pp.107-113
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• 2015

To date, the demand for Combined Cycle Power Plant (CCPP) has been continuously increased to overcome the problem of air pollution and lack of energy. In particular, the underground CCPP is exposed to substantial fire and explosion risks induced by gas leakage. The present study conducted numerical simulations to examine the fire behavior and gas leakage characteristics for a restricted region including gas turbine and other components used in a typical CCPP system. The commercial code of FLUENT V.14 was used for simulation. From the results, it was found that flammable limit distribution of leakage gas affects fire behavior. Especially, the flame is propagated in an instant in restricted region with LNG gas. In addition, consequence analysis factors such as critical temperature and radiation heat flux are introduced. These results would be useful in making the safety guidelines for the underground CCPP.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.1
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• pp.75-81
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• 2006

Lean premixed combustion is a well known method for low $NO_x$ gas turbine combustor. But lean combustion is usually accompanied by flame instability. To overcome this problem, the hydrogen ($H_2$) was added to main fuel methane to increase flammable limit. In this paper, the effects of hydrogen addition on lean premixed combustion of methane ($CH_4$) were investigated numerically. Results showed that the extinction stretch rate increases and the extinction temperature constant with relatively small amount of $H_2$ addition. The flame temperature and NO emission increase with $H_2$ addition at the same stretch rate and equivalence ratio but it could increase the range of lean extinction and extinction equivalence ratio limit. Eventually, the $H_2$ addition case showed almost same or lower NO emission than no addictive $CH_4$ case in the extinction condition.

• Transactions of the Korean Society of Automotive Engineers
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• v.3 no.1
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• pp.65-75
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• 1995

The present study was investigated combustion characteristics of methane-air mixtures at stratified charge in a constant volume combustion chamber. The results indicated that even the vety lean mixture, which is normally not flammable in single chamber type, could be burned within. a comparatively short time by using sub-chamber with stratified charge method. And the lean inflammability limit of mixture in a main chamber was about ($\phi_m$cr=O.46, when the equivalence ratio of a sub-chamber was $\phi_s$= 1.0. Initial time of pressure increase and total burning times were decreased and maximum combustion pressure. was increased as the equivalence ratio of both sub and main chamber approached unity. Specifically, initial time of pressure increase and total burning times were greatly affected rather by. the equivalence ratio of sub-chamber than that of main chamber. The maximum combustion pressure was little affected if the total equivalence ratio lies in the same range.

• Journal of the Korean Society of Safety
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• v.22 no.5
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• pp.84-89
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• 2007

The lower explosion limit(LEL) is one of the major combustion properties used to determine the fire and explosion hazards of the combustible substances. In this study, the lower explosion limits of the ester compounds were predicted by using the normal boiling points and the flash points based on the liquid thermodynamic theory. As a results, the A.A.P.E.(average absolute percent error) and the A.A.D.(average absolute deviation) of the reported and the calculated the LEL for the ester are 8.80 vol% and 0.18 vol%, respectively and the coefficient of correlation was 0.965. From a given results, by the use of the proposed methodology, it is possible to predict the lower explosion limits of the other flammable materials.

• Journal of the Korean Society of Safety
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• v.27 no.5
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• pp.35-41
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• 2012

The Numerical simulation was performed on the flow field around the two-dimensional rectangular bluff body in order to complement the previous experimental results of the bluff body stabilized flames [1]. For both fuel ejection configurations against an oxidizer stream, the flame stability was affected mainly by vortex structure and mixing field near bluff body. FDS(Fire Dynamic Simulator) based on the LES(Large Eddy Simulation) was employed to clarify the isothermal mixing characteristic and wake flow pattern around bluff body. The air used atmosphere and the fuel used methane. The result of counter flow configuration shows that the flow field depends on air velocity but the mixing field is influenced on the fuel velocity. At low fuel velocity the fuel mole fraction is below the flammable limit and hence the mixing is insufficient to react. Therefore, as the result, the flame formed at low fuel velocity is characterized by non-premixed flames. For the flow field of co-flow configuration, flame stability was affected by fuel velocity as well as air velocity. the vortex generated by fuel stream has counter rotating direction against the air stream. Therefore, the momentum ratio between air and fuel stream was important to decide the flame blow out limit, which is result in the characteristic of the partially premixed reacting wake near extinction.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.465-469
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• 2016

The usage of the correct combustion characteristic of the treated substance for the safety of the process is critical. For the safe handling of cumene being used in various ways in the chemical industry, the flash point and the autoignition temperature (AIT) of cumene was experimented. And, the lower explosion limit of cumene was calculated by using the lower flash point obtained in the experiment. The flash points of cumene by using the Setaflash and Pensky-Martens closed-cup testers measured $31^{\circ}C$ and $33^{\circ}C$, respectively. The flash points of cumene by using the Tag and Cleveland open cup testers are measured $43^{\circ}C$ and $45^{\circ}C$. The AIT of cumene by ASTM 659E tester was measured as $419^{\circ}C$. The lower explosion limit by the measured flash point $31^{\circ}C$ was calculated as 0.87 vol%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.