• Title/Summary/Keyword: Flammable gas

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A STUDY ON THE EXPLOSION SAFETY ASSESSMENT OF HYDROCARBON REFRIGERANT REFRIGERATOR

  • Oh, Kyu-Hyung;Kim, Min-Kyu;Chu, Euy-Sung;Lim, Byung-Han;Kim, Man-Hoe;Park, Yoon-Ser
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.289-296
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    • 1997
  • This paper discribes an experimental explosion risk assessment study on refrigerators containing flammable hydrocarbon refrigerant. A refrigerator used in this study is a larder fridge type, 215 liter in volume. The hydrocarbon refrigerant used in the refrigerator is iso-butane(C$_4$H$_{10}$). For the explosion safety assessment of the refrigerator, temperature of compressor, cooling air circulation fan motor, defrost heater and inner lamp were measured during the operation. And to confirm the ignitablity of flammable gas by the electric spark of the switches of the refrigerator, ON-OFF test of all switches were conducted with compulsorily near the stoichiometric concentration atmosphere of iso-butane-air mixture. As the result of experiment above mentioned and another experiment for the explosion safety assessment, we can conclude that explosion hazard in connection with the use of hydrocarbon refrigerant was few.w.

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Prediction of Temperature Dependence of Explosion Limits and Interrelationship of Explosion Characteristics for Akylketones (알킬케톤류의 폭발 특성치 간의 상관관계 및 폭발한계의 온도의존성 예측)

  • Ha Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.10 no.2 s.31
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    • pp.7-13
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    • 2006
  • In order to evaluate the fire and explosion involved and to ensure the safe and optimized operation of chemical processes, it is necessary to know combustion characteristics. The explosion limit, the heat of combustion, flame temperature and temperature dependence of the lower explosive limit are the major combustion characteristics used to determine the fire and explosion hazards of the flammable substances. The aim of this study is to investigate interrelationship of explosion characteristics and the temperature dependence of the lower explosion limit at elevated temperature for akylketones. By using the reference data, the empirical equations which describe the interrelationships of explosion properties of akylketones have been derived. Also, the new equations using the mathematical and statistical methods for predicting the temperature dependence of lower explosion limits of akylketones on the basis of the literature data are proposed. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other flammable substances.

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3D Terrain Model Application for Explosion Assessment

  • Kim, Hyung-Seok;Chang, Eun-Mi;Kim, In-Won
    • 한국지역지리학회:학술대회
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    • 2009.08a
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    • pp.108-115
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    • 2009
  • An increase in oil and gas plants caused by development of process industry have brought into the increase in use of flammable and toxic materials in the complex process under high temperature and pressure. There is always possibility of fire and explosion of dangerous chemicals, which exist as raw materials, intermediates, and finished goods whether used or stored in the industrial plants. Since there is the need of efforts on disaster damage reduction or mitigation process, we have been conducting a research to relate explosion model on the background of real 3D terrain model. By predicting the extent of damage caused by recent disasters, we will be able to improve efficiency of recovery and, sure, to take preventive measure and emergency counterplan in response to unprepared disaster. For disaster damage prediction, it is general to conduct quantitative risk assessment, using engineering model for environmentaldescription of the target area. There are different engineering models, according to type of disaster, to be used for industry disaster such as UVCE (Unconfined Vapor Cloud Explosion), BLEVE (Boiling Liquid Evaporation Vapor Explosion), Fireball and so on, among them.we estimate explosion damage through UVCE model which is used in the event of explosion of high frequency and severe damage. When flammable gas in a tank is released to the air, firing it brings about explosion, then we can assess the effect of explosion. As 3D terrain information data is utilized to predict and estimate the extent of damage for each human and material. 3D terrain data with synthetic environment (SEDRIS) gives us more accurate damage prediction for industrial disaster and this research will show appropriate prediction results.

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APPLICATION OF 3D TERRAIN MODEL FOR INDUSTRY DISASTER ASSESSMENT

  • Kim, Hyung-Seok;Cho, Hyoung-Ki;Chang, Eun-Mi;Kim, In-Hyun;Kim, In-Won
    • Proceedings of the KSRS Conference
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    • 2008.10a
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    • pp.3-5
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    • 2008
  • An increase in oil and gas plants caused by development of process industry have brought into the increase in use of flammable and toxic materials in the complex process under high temperature and pressure. There is always possibility of fire and explosion of dangerous chemicals, which exist as raw materials, intermediates, and finished goods whether used or stored in the industrial plants. Since there is the need of efforts on disaster damage reduction or mitigation process, we have been conducting a research to relate explosion model on the background of real 3D terrain model. By predicting the extent of damage caused by recent disasters, we will be able to improve efficiency of recovery and, sure, to take preventive measure and emergency counterplan in response to unprepared disaster. For disaster damage prediction, it is general to conduct quantitative risk assessment, using engineering model for environmental description of the target area. There are different engineering models, according to type of disaster, to be used for industry disaster such as UVCE (Unconfined Vapour Cloud Explosion), BLEVE (Boiling Liquid Evaporation Vapour Explosion), Fireball and so on, among them, we estimate explosion damage through UVCE model which is used in the event of explosion of high frequency and severe damage. When flammable gas in a tank is released to the air, firing it brings about explosion, then we can assess the effect of explosion. As 3D terrain information data is utilized to predict and estimate the extent of damage for each human and material. 3D terrain data with synthetic environment (SEDRIS) gives us more accurate damage prediction for industrial disaster and this research will show appropriate prediction results.

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Risk Assessment of Fire and Explosion of Methane (메탄의 화재 및 폭발 위험성 평가)

  • Ha Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.1-7
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    • 2005
  • The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosive limit, flash point, autoignition temperature, minimum oxygen concentration, heat of combustion etc.. Explosive limit and autoignition temperature are the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limit and autoignition temperature of methane fur LNG process safety were investigated. By using the literatures data, the lower and upper explosive limits of methane recommended 4.8 vol$\%$ and 16 vol$\%$, respectively. Also autoignition temperatures of methane with ignition sources recommended $540^{\circ}C$ at the electrically heated cruicible furnace (the whole surface heating) and recommended about $1000^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosive limits for methane are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

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Measurement and Prediction of Autoignition Temperature(AIT) of n-Decane+Ethylbenzene System (노말데칸과 에틸벤젠 계의 최소자연발화온도 측정 및 예측)

  • Lee, Jae-Hwa;Kim, Gui-Ju;Hong, Soon-Kang;Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.19 no.5
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    • pp.54-60
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    • 2015
  • The autoignition temperature (AIT) of a material is the lowest temperature at which the material will spontaneously ignite. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs of n-decane+ethylbenzene system by using ASTM E659 apparatus. The AITs of n-decane and ethylbenzene which constituted binary system were $210^{\circ}C$ and $430^{\circ}C$, respectively. The experimental AITs of n-decane+ethylbenzene mixture were a good agreement with the calculated AITs by the proposed equations with about $11^{\circ}C$ A.A.D.(average absolute deviation).

A Study on Flow Analysis according to the Cause of Gas Leakage in the Specialty Gas Supply Device for Semiconductors (반도체용 특수가스 공급장치 내부에서의 가스누출 원인에 따른 유동해석에 관한 연구)

  • Kim, Jung-Duck;Kwon, Ki-sun;Rhim, Jong-Guk;Yang, Won-Baek
    • Journal of the Korean Institute of Gas
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    • v.25 no.2
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    • pp.42-51
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    • 2021
  • Facilities that supply specialty gases used in semiconductor manufacturing mainly handles with hazardous and dangerous substances with flammable, toxic, and corrosive properties, and gas cabinets are mainly used as such supply facilities. The effects of the supply facilities were analyzed for each leak through the rupture disk in the gas cabinet and a leak where the leak hole. In this case, gas leaked to the outside depending on the leak area. It is a factor that creates a risk depending on the concentration of the leaked gas. Depending on the risk of leakage, all measures such as safe operation procedures should be reviewed again.

Estimating the Area of Damage Caused by Gas Pipeline Leakage in Subway Construction Zones (지하철역 공사지역 도시가스 배관 누출로 인한 피해면적 산정)

  • Yang, Yong-Ho;Lee, Jae-Wook;Kong, Ha-Sung
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.2
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    • pp.419-427
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    • 2024
  • This study assessed the potential impact of gas leakage resulting from accidental damage to buried urban gas pipelines during perforating operation near subway construction sites. The risk of explosions due to ignition sources such as static electricity, arising from gas infiltrating the subway construction site through storm sewers and sewage pipes, was evaluated using the ALOHA program. The results of the threat zone calculation, which input various parameters of urban gas pipelines such as length, diameter, and pressure, indicated that the flammable area within the vapor cloud extended from 1.2 to 1.4 km (red zone), the blast area ranged from 0.8 to 1.0 km (yellow zone), and the jet fire extended from 45 to 61 m (red zone). This study demonstrates that within the flammable area of the vapor cloud, a specific combination of concentration and conditions can increase flammability. The blast area may experience explosions with a pressure of 1.0 psi, sufficient to break glass windows. In the event of a jet fire, high temperatures and intense radiant heat exposure lead to rapid fire propagation in densely populated areas, posing a high risk of casualties. The findings are presented in terms of the sphere of influence and threat zone ranges.

Experimental Study on Ignition of Flammable Gas by Spark of Dry Battery (건전지의 방전에 의한 폭발성 가스의 점화에 관한 실험적 연구)

  • Lee, Chun-Ha;Song, Hyun-Jig;Lee, Kwang-Sik;Lee, Dong-In
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1543-1546
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    • 1994
  • Ignitabilility of explosive gas mixture by spark of dry cell in case of short circuit by accident was studied for the purpose of evaluation of intrinsically safe characteristics of dry cell that manufactured in Korea. IEC type spark test apparatus, $21{\pm}2$ Vol% of hydrogen - air mixture, and dry cell that produced in Korea was used for the experiment. The result of this research could be used for design, manufacturing, and using the intrinsically safe electrical apparatus.

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A Study on Fire and Explosion Accident Cause in Regenerated Thermal Oxidizer (축열식 소각로의 화재.폭발 사고원인 규명 연구)

  • Lee, Keun-Won;Ma, Byung-Chol;Hwang, Soon-Yong
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.7-11
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    • 2007
  • There has been a report of fire and explosion accident in regenerated thermal oxidizer (RTO). This paper was to investigate accident causes of RTO in the resin re-treatment process. The experiments carried out physicochemical properties and thermal stability analyses by using flash point tester, flammable range apparatus, autoignition tester, GC/MSD and thermal screening unit. We inferred causes of fire and explosion from the regenerated thermal oxidizer to prevent an accident of its process.

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