• Proceedings of the Korean Environmental Health Society Conference
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• 2005.06a
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• pp.399-405
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• 2005

In this study, we investigated the gas chromatography (GC) and pulsed flame photometric detection (PFPD) system for the analysis of four major reduced S compounds including hydrogen sulfide ($H_2S)$; methyl mercaptan ($CH_3SH$); dimethyl sulfide (DMS); and dimethyl disulfide(DMDS) contained in environmental samples. To analyze these compounds in high concentration range (above ppb level), we developed a high mode analytical setting with the loop-injection system. By contrast, we also established a low mode setting for the analysis of low concentration samples (ppt-level samples from ambient air) by the combination with thermal desorption unit(TDU). Comparative analysis of both settings revealed that relative detection properties of four S compounds are systematic enough. The results of high mode analysis indicated that the patterns were systematic among compounds: H2S exhibited the lowest sensitivity, while DMBS showed the strongest one. The results were also compared in terms of sensitivity reductions for all compounds by dividing slope ratios between low and high mode system. Although low mode system exhibited significant reductions on the order of a few tens times, their detection characteristics were highly consistent as it was shown in the high mode setting. To learn more about absolute and relative relations between two different modes of S analysis, future studies may have to be directed to cover more complicated nature of GC/PFPD performance. Hydrogen sulfide($H_2S$) was over in summer about low level of olfactory sense 410 ppt, Methyl mercaptan(C$H_3SH$) was over in apring and summer about low level of olfactory sense 70, Dimethyl sulfide(DMS) was not over in four season about low level of olfactory sense 2,200 ppt. Carbon disulfide($CS_2$) was not over in four deason about Tow level of olfactory sense 210,000, Dimethyl disulfide(DMDS) was not over in summer about low level of olfactory sense2,000.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.30 no.2
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• pp.91-97
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• 2002

Dynamic extinction of solid propellants subjected to rapid pressure drop was studied with the aid of energy equation of condensed phase and flame model in gas phase. It is found that the total residence time($\tau_\gamma$) which measures the residing time of fuel in the reaction zone may play a crucial role in determining the dynamic response of the combustuion to extinction. Residence time was modeled by various combinations of diffusion and chemocal kinetic time scale. Effect of pressure history coupled with chamber volume on the extinction response was also performed and was found that dynamic extinction is more susceptible in a confined chamber than in open geometry. And, dynamic extinction was revealed to be affected profoundly by diffysion time scale rather than chemical kinetic time scale.

• Journal of the Korean Ceramic Society
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• v.29 no.12
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• pp.926-934
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• 1992

Uniform diamond films in a few $\textrm{mm}^2$ size and locally isolated diamond single crystals in size of 60 $\mu\textrm{m}$ were synthesized on Si-wafer and Al2O3 substrate by the method of acetylene flame. The effects of substrate temperature and flow ratio of oxygen to acetylene on the morphology of deposited diamond were investigated. According to the observations of growth behavior of diamond on Si substrate with respect to substrate surface pretreatment and flow ratio, it was shown that well faceted diamonds could grow uniformly when flow ratio was above 0.9 and substrates were densely scratched. With increasing substrates temperature, the crystal morphology changes from octahedron bounded by only {111} plane below 850$^{\circ}C$ to cubo-octahedron with almost equal development of {111} and {100} plane in the temperature range of 850∼950$^{\circ}C$. Between 950∼1050$^{\circ}C$, the {111} faces become rough and concave. Above 1050$^{\circ}C$, new crystallites begin to grow on concave {111} surface and overall morphology looks like cubo-octahedron with degenerated {111} faces. These changes of morphology can be understood in terms of the different growth mode of each crystallographic plane with respect to the substrate temperature and supersaturation. And the observed phenomena on {111} planes can be related to the face instability and twin generation.

• Journal of the Korean Society of Combustion
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• v.20 no.1
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• pp.32-42
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• 2015

The combustion instability was experimentally investigated in model gas turbine combustor with dual swirl burner. When such instability occurs, a strong coupling between pressure oscillation and unsteady heat release excites a self-sustained acoustic wave which results in a loud sound, and can even cause fatal damage to the combustor and entire system. In present study, to understand the combustion instability with a premixed mixture, the detailed periods of pressure and heat release data in unstable flame mode were investigated by various measurement methods at relatively rich condition and lean condition near flammable limits. Also, to prepare the utilization of synthetic natural gas (SNG) fuel in gas turbine system, an investigation was conducted using a simulated SNG including methane as a reference fuel to examine the effects of $H_2$ content on flame stability. These results provide that the instability due to flash-back behaviour like CIVB phenomenon occurred at rich condition, while the repetition of relighting and extinction caused the oscillation of lean condition near flammable limit. From the analysis of $H_2$ content effects, it is also confirmed that the instability frequency is proportional to the laminar burning velocity at both rich and lean condition.

• Journal of the Korean Society of Safety
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• v.26 no.5
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• pp.1-6
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• 2011

Flame extinction and the chemistry of stoichiometric methane/air mixture were investigated numerically in the PSR(perfectly stirred reactor). For the study, PSR code was modified to be possible to unsteady calculation, and the sinusoidal fluctuation was subjected to the residence time. In the region of residence time far from the extinction limit, combustion mode was strongly dependent on the frequency. The low frequency excitation provided the quasi-steady behavior on the temperature and the concentrations of related species, but small variation of temperature was observed under high frequency. In the region of residence time near the extinction limit, the mixture subjected above 1 KHz was still reacting even though extinction had to be occurred under quasi-steady concept. The attenuation of extinction limit resulted from that chemical time was comparable to the flow time. The mean mole fractions of both NO and CO were almost same regardless of imposed frequency. However, the average mole fraction of $C_2H_2$ was decreased as increasing frequency, which implies that soot yield might be reduced at the higher frequency of flow excitation. The result provides the basic concept for flame stabilization, and it will be used to design a mild combustor.

• Journal of the Korean Society of Safety
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• v.24 no.4
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• pp.28-33
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• 2009

This study examined the mounting status of cigar lighter receptacles for vehicles and analyzed the tracking phenomenon that occurs when foreign material entered a cigar lighter receptacle to obtain data for the analysis of accident investigation. Regardless of the vehicle's output, cigar lighter receptacles are mounted in a vehicle horizontally, vertically, or at tilting or inclined angle. The tilting type cigar lighter receptacle is much easier to use but current leakage resulting from foreign materials (coffee, beverages, water, etc.) falling into the cigar lighter receptacle may cause a fire to start. This study used a vehicle battery (DC 12V) as a power supply for the tracking test and configured its circuit in the same way as that of an electrical device in a vehicle. The tracking phenomenon that occurred in the standby mode of the vehicle exhibited a fine flame and an irregular occurrence of smoke. While this tracking phenomenon was occurring, the leakage current and the reaching distance of the flame were measured to be approximately 930mA and $20{\sim}50cm$, respectively. It is thought that the resultant flame may ignite toluene, dust, cigarettes, etc. It was observed that as the tracking progressed, the internal metal socket melted and a hole was created, the surface of which was also severely carbonized. In addition, the electrical resistance of the carbonized conductive path was measured to be approximately $30{\Omega}$. It is thought that this much resistance may cause local heating when leakage current flows and could ignite any nearby flammable material.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.231-235
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• 2009

The mainly objectives of this study was a combustion dynamics and instability characteristics in a model dump type combustor which is scale down of GE 7FA+e DLN 2.6 gas turbine combustor with running at Seo-Inchon combined cycle power plant. Model gas turbine injector has 2-stage swirl vane and it's reduced 1/3 size of the original one. The shape of plenum and combustor were designed for similar acoustic characteristics. As the result, this research have been shows the peak frequency of model combustor was changed quarter-wave mode to Helmholtz resonator mode in plenum and longitudinal mode in dump combustor at unstable flame conditions caused by the different of combustor temperature and fuel-air mixture distributions.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2005.11a
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• pp.445-449
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• 2005

The mixed acoustic-convective mode combustion instability and the possibility of combustion control using a loudspeaker to these instabilities were studied. By changing inlet velocity, combustor length and equivalence ratio, the dynamic pressure signals and the flame structures were simultaneously taken. The results showed that as the combustor length increased and the inlet velocity decreased, the instability frequency decreased and the maximum power spectral densities of the dynamic pressures generally decreased. The instability frequency could be affected by an equivalence ratio over the operating conditions. From the data of close-loop control, as the loudspeaker may work out-of-phase with the natural instability, the optimum time-delay controller was confirmed to be able to reduce the vortex shedding from the mixed acoustic-convective mode combustion instability.

• Journal of the Korean Society of Propulsion Engineers
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• v.10 no.2
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• pp.115-128
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• 2006

A technical analysis of current scramjet and combined-cycle engine is presented. Substantial research has been pursued to characterize the operation mechanism of scramjet propulsion, especially in the areas of flame stabilization and system integration, dramatically over the years in support of both military and space access application. Major technology that had significant impact on the maturation of scramjet propulsion technology are dual combustion ramjet, dual mode ramjet, and combined cycle engine to cover a typical wide rage of flight, up to flight Mach number 10. Notable are the fundamental and practical techniques, for instance, scram propulsion itself, thermal relaxation and protection using endothermic fuel and/or CSiC composit materials, and design/manufacture of movable intake and nozzle, to realize high speed propulsion system in near future.

• Fire Science and Engineering
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• v.26 no.6
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• pp.92-98
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• 2012

In this sturdy, large experimental (ISO 13785-2) was performed to analyze the building materials used in fire retardant materials for aluminum composite panel and in general properties. As a results, maximum temperature in the case of the general materials was measured in 210 seconds $1,021^{\circ}C$, the retardant materials was measured in 1,200 seconds early $1,190^{\circ}C$. The retardant material of aluminum composite panel, Fire behavior if the ignition is slow and the general materials in aluminum composite panel, fire ignition and combustion at the same time was growing rapidly. The general materials and flame-retardant material of aluminum composite panel was an obvious difference to the combustion ignition but after ignition combustion mode showed a similar pattern of the rapidly vertical spread of flame. The results of this study, in order to reduce the risk of aluminum composite panels for fire and the retardant materials used for ignition the slow should be actively encouraging. Also after the ignition, there is an urgent need to put out a fire in exterior materials for extinguishing facilities.