• Archives of Pharmacal Research
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• v.9 no.2
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• pp.111-114
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• 1986

Bretylium tosylate is a quaternary ammonium compound used for the treatment of ventricular fibrilation in humans. It is advantageous to other cationic compound in the study of biliary excretion in that negligible amount is bound to plasma protein and metabolite is not likely is to be formed. Some researchers reported that the formation of ion-pair complex caused to increase the lipothilicity of cationic compound. The partition of bretylium between water and organic phase was increased with the addition of sodium taurodeoxycholate. Also sensitive gas chromatographical assay procedure using flame ionization detector was studied. This procedure can detect as low as 0.1 mg/ml using 0.1 ml biological sample, but contamination by previous injection is the major problem of this method.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2010.04a
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• pp.319-321
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• 2010

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.3
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• pp.265-275
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• 2000

By using thermal desorption/gas chromatograph/flame ionization detector(TD/GC/FID), this study was carried out to evalute an accuracy and a precision on Benzene(B), Toluene(T), o-Xylene(X) analysis in an industrial hygiene laboratory. Limits of detection of TD/GC/FID on B, T, X were showed 13.75ng/sample or less. For the accuracy of the method by concentration levels, overall bias was showed 7.7% as an absolute value, and the pooled coefficient of variation showed 3.51%. For the precision on repeatability of peak area and retention time between within-run and between-run of analytical system, it is showed the results of within-run gave better than those of between-run. Also the accuracy by sorbents(Tenax TA and Chromosorb 106)was evaluated, and the precision on reproducibility between MDHS72 and this study was compared. It is showed it is possible for TD/GC/FID to evaluate accurately B, T, X concentration levels of less than 1ppm at indoor or outdoor of workplaces in Korea.

• Korean Journal of Food Science and Technology
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• v.29 no.6
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• pp.1101-1104
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• 1997

The volatile compounds in sesame oil were collected by a dynamic headspace technique and analyzed using a gas chromatograph with a flame ionization detector and an olfactory detector. Twenty compounds such as methylpyrazine, acetic acid, 2-furan carboxaldehyde and 2-furanmethanol were separated and identified with a mass spectrometric detector. The result of sniffing test showed that pyrazine compounds and 2-furan-carboxaldehyde had a sweet and roasted flavor whereas acetic acid and 2-furanmethanol stinked.

• Analytical Science and Technology
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• v.11 no.2
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• pp.139-144
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• 1998

For the ambient monitoring of acrylamide, the adequate condition of sampling and analysis was checked. The adequate adsorbents and desorption solvents were tested. The combination of charcoal tube as a adsorbent and acetone as a desorption solvent showed 87% desorption efficiency. Flame ionization detector was used to detect acrylamide. The detection limit was 0.814 mg acrylamide in 1 L acetone. It is the equivalent concentration of 0.0203 mg acrylamide in $1m^3$ air if the volume of air collected was 40L. The permissible exposure level (PEL) of acrylamide in the workplace air recommended by Occupational Safety and Health Administration (OSHA, USA) is 0.3 mg acrylamide in $1m^3$ air. So, it is very simple and economic analytical method for acrylamide to be set in the industrial hygiene laboratories.

• YAKHAK HOEJI
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• v.25 no.4
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• pp.181-186
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• 1981

Compositions of neutral lipid of the hazel nut (Corylus heterophylla Fischer var. thumbergii Blume, Betulaceae) produced in Korea were analyzed by thinchrography (Iatrosoan TH-10 type), which was equipped with a flame ionization detector. The neutral lipid components were nearly separated of the basis of their degree of unsaturation by employing the chromatography on silica gel sintered rod impregnated with 12.5% silver nitrate and it was noted that triglyceride was the major lipid components of Korean hazel nut. The triglyceride compositions were trilinolenin 10.63, trilinolein 18.01, triolein 42.24, tripalmitin 17.57 and tristearin 11.55% by thinchrographic analysis.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.2
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• pp.212-219
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• 1998

Unburned hydrocarbon is a key contributor to both the fuel economy and emissions of automotive engine. Cyclic variation of HC emission is of importance, especially during throttle transients. The real time measurement of hydrocarbon is particularly important to obtain a better understanding of the mechanisms for combustion and emissions, especially during cold start and throttle transient condition. This paper reports the cycle resolved measurement technique of unburned hydrocarbons to quantify rapid changes of in-cylinder concentration in the vicinity of spark plug by using the Fast Response Flame Ionization Detector(FRFID). While this instrument actually measures fuel concentration, its results can be indicative of the AFR behaviour. In order to understand the rapid change of hydrocarbons with cylinder pressure, it is necessary to study the response time delay of the system, including the time associated with gas transportation to FID. And signal from FRFID is correlated with cylinder pressure data to relate changes in mixture preparation to the classic analysis, such as indicated mean effective(IMEF) and ignition delay, etc.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.1
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• pp.77-87
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• 2014

In this study, an experimental approach to measure a suite of low weight hydrocarbons was investigated with an emphasis on ethylene (EL) along with many others (ethane (EA), propane (PA), propylene (PL), n-butane (BA), acetylene (AL), methyl acetylene (ML)). Their concentrations were quantified using GC-FID system equipped with thermal desorption (TD) system. The TD-based analysis was conducted using both Link Tube/Thermal Desorber (LT/TD) method and Modified Injection through a Thermal Desorption (MITD) method. The results of these analyses were evaluated in a number of respects. The system allowed the detection of all compounds except methane with the mean response factor (RF) of 10.28 (EA) to 11.94 (PL). The method detection limits of target compounds were seen in the range of 0.027 (ML) to 0.146 ng (BA). The emission flux of some environmental samples (fruits), when measured using a small flux chamber system, fell in the range of 0.14 (AL: Kiwi) to $181ng{\cdot}g^{-1}{\cdot}hr^{-1}$ (EL: Apple Peel). The results of this study confirm that the experimental approach developed in this study allows to accurately measure emissions of low weight hydrocarbons (LWHC) like ethylene from various natural and man-made source processes.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.5
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• pp.23-28
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• 2002

As the interest on the air pollution is gradually rising up at home and abroad, automotive industries have been working on the exhaust emission reduction from vehicles through a lot of approaches, which consist of new engine design, innovative aftertreatment systems, and using clean fuels. Methanol, ethanol, LNG, LPG, H2, reformulated gasoline are generally recognized as the clean fuel. Since the low price policy of government on LPG has expanded its vehicle market recently, there is concern of the exhaust emission of LPG vehicle. In this paper, we studied the value of LPG fuel as a clean fuel by comparing the results of the exhaust emission from LPG and Gasoline fueled vehicles, and discussed its limitation of LPG vehicle with mixer type as a fuel supply system. FTIR was used to understand the difference of exhaust emission components of LPG and Gasoline fueled vehicles.

• YAKHAK HOEJI
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• v.32 no.1
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• pp.6-13
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• 1988

A gas chromatographic method is described for the determination of volatile free acids(VFAs) in body fluids. VFAs were trace enriched from body fluids by liquid-solid extraction using Chromosorb P as the solid sorbent and ether as the eluant. The enriched VFAs were injected in splitless injection mode onto a HP-20M fused silica capillary column. The flame ionization detector was used as the detector. The present method was applied to the profiling of VFAs in body fluids from patients suffering from the infectious disease, hepatitis. The VFAs concentrations were high in saliva of hepatitis patients and isobutyric acid detected in sera of hepatitis patients compared to healthy subjects.