• Archives of Pharmacal Research
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• 제6권2호
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• pp.103-108
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• 1983

Such sulfur-containing drugs as chlorpromazine, sulfonamides and thiazides were determined by gas chromatography with flame photometric detector (FPD) and flame ionization detector (FID). 0.6% QF-1 or 3% SE-30 on Chromosorb WAWDMCS were found suitable for drugs listed above. In the experimental conditions given maximum response the FPD response and the response ratio of FPD increased with the number of sulfur atom per molecule. It was possible to obtain a linear calibration curve from $10^{-9}$ / mole to $2{\times}10^{-8}$ / mole and to analyze variety of sulfur drugs by the calibration curve of one sulfur standard.

• 약학회지
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• 제22권3호
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• pp.157-162
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• 1978

Total organic carbon(TOC) can be determined by means of combustion and flame ionization detector. The principle of string method is that a sample acidified to pH2 and transferred into combustion tube by string is oxidized with air. Another combustion tube method is that organic compounds are oxidized in the combustion tube charged with CuO and cobalt asbestos after the acidified sample is injected directly by microsyringe. Carbon dioxide evolved was reduced under specially treated nickel catalyst and hydrogen, the methane produced was detected by flame ionization detector. Linear relationship was found between concentration and the peak height by the string method. The peak area in the case of combustion tube method is in the range of 1-200ppm. The coefficient of variation by string method was 2.3% and that by combustion tube method was 1.8%. The lower detectable limit was about 10mol. Advantages of the latter are simplicity, sensitivity and reproducibility. TOC in contineous stream can also be determined automatically by means of the string method.

• 조명전기설비학회논문지
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• 제28권1호
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• pp.88-95
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• 2014

The infrared, flame detector uses to detect fire situation from the characteristics of fire sources radiant energy. But it is able to malfunction on account of susceptible to interference of various surrounding waves. This paper is designed 6 independent PCB-boards to minimize the closed loops of siginal circuit. Also considering the interaction of electric and magnetic fields, this paper is designed protecting circuit of current and voltage output to reduced electromagnetic interference. And this paper is improving electromagnetic susceptibility by ferrite bid, capacitor filter and grounding circuits.

• Journal of Mechanical Science and Technology
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• 제19권12호
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• pp.2197-2204
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• 2005

The combination of Gas chromatography (GC) for separation and Flame Ionization Detection (FID) for detection and identification of the components of a mixture of compounds is a fast and strongly proved method of analytic chemistry. The objective of this research was to design a combined High-speed miniature screening Gas chromatograph along with a Flame Ionization Detector for quick, quantitative and qualitative analysis of gas components. This combined GC-FID system is suitable to detect the volatile and semi-volatile hydrocarbons present in a gas mixture. The construction made it less expensive, easy to use and movable. The complete gas path was developed. On/off valves, temperature and flow sensors and their interface electronics were used for controlling purpose. A Microcontroller was programmed to measure the temperature and gas flow using the sensors and to control and regulate them using the electronics and valves. A pocket PC with its touch screen served as a user interface for the system. Software was developed for the pocket PC, which makes the communication possible with the Microcontroller. The system parameters can be indicated in the Pocket PC as simple text and also the analysis result can be displayed.

• 한국식품과학회지
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• 제37권5호
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• pp.695-701
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• 2005

각각의 황 함유 화합물의 표준곡선을 그렸을 때, linear range의 범위는 $10^2$부터 $10^4$까지의 범위를 보였다. Dimethyl trisulfide가 가장 작은 limit of detection(LOD) 값과 가장 넓은 linear range $(10^4)$를 보이는 반면, methional은 가장 큰 LOD 값과 가장 좁은 linear range$(10^2)$를 가졌다. 각 황 함유 화학물의 분자구조와 PFPD의 황 함유 화합물 분석 원칙에 영향을 받는 것으로 사료된다. 서로 다른 세 종류의 fiber를 사용시, 미세 고체상 추출법(SPME)을 사용했을 때, CAR/PDMS fiber는 가장 좋은 추출 효율을 보였고, 반대로 PDMS/DVB fiber는 가장 낮은 효율을 나타내었다. SPME 방법을 사용하면, 시료에 포함되어 있는 6개의 황 함유 화합물들 중, 최대 5개까지 분석이 가능하였다. 그러나 본 실험에서 사용하지 않은 황 함유 화합물들도 다수 동정 되었는데, 이렇게 추출과정 중 artifacts로 생성된 황 함유 화합물들은 분석 시 오차를 작용할 수 있다. 고정상 기체추출법(SH)은 SPME와 비교했을 때 더 적은 수의 황 함유 화합물을 감지해냈다. SPME와 비교 시 SH의 추출 효율은 낮았지만, artifact로 생성되는 화합물의 수는 적었다.

• 한국안전학회지
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• 제32권2호
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• pp.38-45
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• 2017

This paper is an experimental study to find an optimal detection method for detecting fire early in a rack-type warehouse stored with goods. In this study, we constructed rack-type structure with the fourth floor of 13.5 m high and conducted fire experiments which were to measure flow of heat/smoke in rack-type structure and response time of fire detectors. The detectors used at experiments were fixed temperature type detectors, rate of rise detectors, photoelectric smoke detectors, air sampling smoke detectors and flame detectors. The used ignition sources are n-heptane fire for response of heat detection and cotton fire for response of smoke detection. The fixed temperature type detectors, rate of rise detectors and photoelectric detectors were installed to every rack level respectively. The results show that the rate of rise detector should be installed every 2 levels and photoelectric smoke detector should be installed every 4 levels for the early stage fire detection. Air sampling smoke detectors can detect fire early in response to control of sensitivity, but there is a problem in false alarm. The fixed temperature detector is not suitable for early stage fire detection in warehouse and flame detector not worked if flame is not visible, so it need to install combination with other detector.

• 방재기술
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• 통권13호
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• pp.18-26
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• 1992

This report is explained about operating principles, characteristices of flame detectors. Flame detector is designed to detect the UV (Ultraviolet) and IR (Infrared) rediation produced by flaming involving carbonaceous materials.

• 약학회지
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• 제28권1호
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• pp.25-27
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• 1984

Some $\betha$-lactam antibiotics-penicillins and cephalosporins-were determined by gas chromatography (GC) with flame photometric detector (FPD) which was selective and sensitive to sulfur-containing compounds. Methyl ester derivatives of carboxyl group in $\betha$-lactam antibiotics were prepared using 0.5Mmethyl iodide in methylene chloride and were taken for gas chromatography with 0.9% or 0.6% QF-1 on Chromosorb WAW-DMCS. We have found that it is possible to determine methyl esters of $\betha$-lactam antibiotics by GC/FPD.

• Journal of Microbiology and Biotechnology
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• 제25권5호
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• pp.704-708
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• 2015

For the analysis of multiple-reaction intermediates for long-chain dicarboxylic acid biotransformation, simple and reproducible methods of extraction and derivatization were developed on the basis of gas chromatography with flame ionization detector (GC-FID) instead of mass spectrometry. In the derivatization step, change of the ratio of pyridine to MSTFA from 1:3 to 9:1 resulted in higher peak intensity (p = 0.021) and reproducibility (0.6%CV) when analyzing 32 g/l ricinoleic acid (RA). Extraction of RA and ω-hydroxyundec-9-enoic acid with water containing 100 mM Tween 80 showed 90.4-99.9% relative extraction efficiency and 2-7%CV compared with those with hydrophobic ethyl acetate. In conclusion, reduction of the pyridine content and change of the extraction solvent to water with Tween 80 provided compatible derivatization and extraction methods to GC-FID-based analysis of longchain carboxylic acids.

• 한국화재소방학회논문지
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• 제23권3호
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• pp.67-72
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• 2009

본 논문은 주택 실물화재실험에 의한 화재감지기 응답특성에 관한 연구로서 철거가 예정된 연립주택을 화재실험대상으로 선정하여 현재 가장 많이 사용되고 있는 감지기 종류인 열감지기(차동식, 정온식, 아날로그식)와 연기감지기(광전식, 아날로그식, 단독경보형)를 주택내부에 설치여 화재감지기의 응답특성을 분석하고, 추가적으로 건물내부로의 화염전파 및 화재확대를 관찰하기 위해 열전대를 설치하여 온도변화를 측정하였다. 실험결과 주택에서 효과적인 화재감지시스템을 구축하기 위해서는 연기감지기가 열감지기보다 주택용 감지기로 적합한 것으로 나타났다.